(a)
Interpretation: The name of the acid HCl is to be given.
Concept Introduction: The acid is a binary hydrogen acid. Its name starts with ‘hydro’ and ends in ‘ic’ replacing the suffix ‘ide’ of the anion.
(a)
Answer to Problem 25A
The name of the acid is Hydrochloric acid.
Explanation of Solution
The anion is chloride. Starting with Hydrogen and replacing ‘ide’ of the chloride to ‘ic’ the name becomes Hydrochloric acid.
(b)
Interpretation: The name of the acid H2SO4 is to be given.
Concept Introduction: The acid is an oxo-acid of sulfur in which along with sulfur and hydrogen, oxygen is present. Identify the anion present in the acid. If it ends in ‘ate’, change it to ‘ic’ acid and if it ends in ‘ide’ change it to ‘ous’ acid.
(b)
Answer to Problem 25A
The name of the acid is Sulfuric acid.
Explanation of Solution
Anion present here is a sulfate. Changing its suffix to ‘ic’ acid, the name becomes sulfuric acid.
(c)
Interpretation: The name of the acid HNO3 is to be given.
Concept Introduction: The acid is an oxo-acid of nitrogen in which along with nitrogen and hydrogen, oxygen is present. Identify the anion present in the acid. If it ends in ‘ate’, change it to ‘ic’ acid and if it ends in ‘ide’ change it to ‘ous’ acid.
(c)
Answer to Problem 25A
The name of the acid is Nitric acid.
Explanation of Solution
Anion present here is Nitrate. Changing its suffix to ‘ic’ acid, the name becomes Nitric acid.
(d)
Interpretation: The name of the acid HI is to be given.
Concept Introduction: The acid is a binary hydrogen acid. Its name starts with ‘hydro’ and ends in ‘ic’ replacing the suffix ‘ide’ of the anion.
(d)
Answer to Problem 25A
The name of the acid is Hydroiodic acid.
Explanation of Solution
The anion is iodide. Starting with Hydrogen and replacing ‘ide’ of the chloride to ‘ic’ the name becomes Hydroiodic acid.
(e)
Interpretation: The name of the acid HNO2 is to be given.
Concept Introduction: The acid is an oxo-acid of nitrogen in which along with nitrogen and hydrogen, oxygen is present. Identify the anion present in the acid. If it ends in ‘ate’, change it to ‘ic’ acid and if it ends in ‘ide’ change it to ‘ous’ acid.
(e)
Answer to Problem 25A
The name of the acid is Nitrous acid.
Explanation of Solution
Anion present here is Nitrate. Changing its suffix to ‘ous’ acid, the name becomes Nitrous acid.
(f)
Interpretation: The name of the acid HClO3 is to be given.
Concept Introduction: The acid is an oxo-acid of Chlorine in which along with Chlorine and hydrogen, oxygen is present. Identify the anion present in the acid. If it ends in ‘ate’, change it to ‘ic’ acid and if it ends in ‘ide’ change it to ‘ous’ acid.
(f)
Answer to Problem 25A
The name of the acid is Chloric acid.
Explanation of Solution
Anion present here is Chloride. Changing its suffix to ‘ic’ acid, the name becomes Chloric acid.
(g)
Interpretation: The name of the acid HBr is to be given.
Concept Introduction: The acid is a binary hydrogen acid. Its name starts with ‘hydro’ and ends in ‘ic’ replacing the suffix ‘ide’ of the anion.
(g)
Answer to Problem 25A
The name of the acid is Hydrobromic acid.
Explanation of Solution
The anion is bromide. Starting with Hydrogen and replacing ‘ide’ of the chloride to ‘ic’ the name becomes Hydrobromic acid.
(h)
Interpretation: The name of the acid HF is to be given.
Concept Introduction: The acid is a binary hydrogen acid. Its name starts with ‘hydro’ and ends in ‘ic’ replacing the suffix ‘ide’ of the anion.
(h)
Answer to Problem 25A
The name of the acid is Hydrofluoric acid.
Explanation of Solution
The anion is fluoride. Starting with Hydrogen and replacing ‘ide’ of the chloride to ‘ic’ the name becomes Hydrofluoric acid.
(i)
Interpretation: The name of the acid CH3CH2OH is to be given.
Concept Introduction: The acid is a
(i)
Answer to Problem 25A
The name of the acid is Ethanoic acid.
Explanation of Solution
There are two carbons in its chemical formula. So the parent chain is Ethane. Replacing ‘e’ with ‘oic’ acid name becomes ethanoic acid.
Chapter 4 Solutions
World of Chemistry, 3rd edition
- Please draw the structure in the box that is consistent with all the spectral data and alphabetically label all of the equivalent protons in the structure (Ha, Hb, Hc....) in order to assign all the proton NMR peaks. The integrations are computer generated and approximate the number of equivalent protons. Molecular formula: C13H1802 14 13 12 11 10 11 (ppm) Structure with assigned H peaks 2.08 3.13arrow_forwardA 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 10.0 mL of the base solution, what is the pH of the resulting solution?arrow_forwardFirefly luciferin exhibits three rings. Identify which of the rings are aromatic. Identify which lone pairs are involved in establishing aromaticity. The lone pairs are labeled A-D below.arrow_forward
- A 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 10.0 mL of the base solution, what is the pH of the resulting solution?arrow_forwardGiven a complex reaction with rate equation v = k1[A] + k2[A]2, what is the overall reaction order?arrow_forwardPlease draw the structure in the box that is consistent with all the spectral data and alphabetically label all of the equivalent protons in the structure (Ha, Hb, Hc....) in order to assign all the proton NMR peaks. The integrations are computer generated and approximate the number of equivalent protons. Molecular formula: C13H1802 14 13 12 11 10 11 (ppm) Structure with assigned H peaks 2.08 3.13arrow_forward
- CHEMICAL KINETICS. One of the approximation methods for solving the rate equation is the steady-state approximation method. Explain what it consists of.arrow_forwardCHEMICAL KINETICS. One of the approximation methods for solving the rate equation is the limiting or determining step approximation method. Explain what it consists of.arrow_forwardCHEMICAL KINETICS. Indicate the approximation methods for solving the rate equation.arrow_forward
- TRANSMITTANCE เบบ Please identify the one structure below that is consistent with the 'H NMR and IR spectra shown and draw its complete structure in the box below with the protons alphabetically labeled as shown in the NMR spectrum and label the IR bands, including sp³C-H and sp2C-H stretch, indicated by the arrows. D 4000 OH LOH H₂C CH3 OH H₂C OCH3 CH3 OH 3000 2000 1500 HAVENUMBERI-11 1000 LOCH3 Draw your structure below and label its equivalent protons according to the peak labeling that is used in the NMR spectrum in order to assign the peaks. Integrals indicate number of equivalent protons. Splitting patterns are: s=singlet, d=doublet, m-multiplet 8 3Hb s m 1Hd s 3Hf m 2Hcd 2Had 1He 鄙视 m 7 7 6 5 4 3 22 500 T 1 0arrow_forwardRelative Transmittance 0.995 0.99 0.985 0.98 Please draw the structure that is consistent with all the spectral data below in the box and alphabetically label the equivalent protons in the structure (Ha, Hb, Hc ....) in order to assign all the proton NMR peaks. Label the absorption bands in the IR spectrum indicated by the arrows. INFRARED SPECTRUM 1 0.975 3000 2000 Wavenumber (cm-1) 1000 Structure with assigned H peaks 1 3 180 160 140 120 100 f1 (ppm) 80 60 40 20 0 C-13 NMR note that there are 4 peaks between 120-140ppm Integral values equal the number of equivalent protons 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 fl (ppm)arrow_forwardCalculate the pH of 0.0025 M phenol.arrow_forward
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY