(a) Interpretation: The lone pairs needed to complete the octet should be filled in the main group elements in the acrylonitrile. Concept Introduction: The octet rule is, tendency of an atom to have eight electrons in its valence shell. In a molecular structure, each single bond indicates two electrons.

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Answer 1

Question

Chapter 4, Problem 19P

Interpretation Introduction

(a)

Interpretation:

The lone pairs needed to complete the octet should be filled in the main group elements in the acrylonitrile.

Concept Introduction:

The octet rule is, tendency of an atom to have eight electrons in its valence shell. In a molecular structure, each single bond indicates two electrons.

Interpretation Introduction

(b)

Interpretation:

The lone pairs needed to complete the octet should be filled in the main group elements in the cysteine.

Concept Introduction:

The octet rule is, tendency of an atom to have eight electrons in its valence shell. In a molecular structure, each single bond indicates two electrons.

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. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. < cleavage Bond A • CH3 + 26. t cleavage 2°C• +3°C• Bond C Cleavage CH3 ZC '2°C. 26. E Strongest 3°C. 2C. Gund Largest BDE weakest bond In that molecule a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest C bond Produces A Weakest Bond Most Strongest Bond Stable radical Strongest Gund produces least stable radicals b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 人 8°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. methyl radical •CH3 formed in bund A Cleavage

Which carbocation is more stable?

Are the products of the given reaction correct? Why or why not?

Answer 2

Question

Chapter 4, Problem 19P

Interpretation Introduction

(a)

Interpretation:

The lone pairs needed to complete the octet should be filled in the main group elements in the acrylonitrile.

Concept Introduction:

The octet rule is, tendency of an atom to have eight electrons in its valence shell. In a molecular structure, each single bond indicates two electrons.

Interpretation Introduction

(b)

Interpretation:

The lone pairs needed to complete the octet should be filled in the main group elements in the cysteine.

Concept Introduction:

The octet rule is, tendency of an atom to have eight electrons in its valence shell. In a molecular structure, each single bond indicates two electrons.

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Answer 3

Question

Chapter 4, Problem 19P

Interpretation Introduction

(a)

Interpretation:

The lone pairs needed to complete the octet should be filled in the main group elements in the acrylonitrile.

Concept Introduction:

The octet rule is, tendency of an atom to have eight electrons in its valence shell. In a molecular structure, each single bond indicates two electrons.

Interpretation Introduction

(b)

Interpretation:

The lone pairs needed to complete the octet should be filled in the main group elements in the cysteine.

Concept Introduction:

The octet rule is, tendency of an atom to have eight electrons in its valence shell. In a molecular structure, each single bond indicates two electrons.

Expert Solution & Answer

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Answer 4

Question

Chapter 4, Problem 19P

Interpretation Introduction

(a)

Interpretation:

The lone pairs needed to complete the octet should be filled in the main group elements in the acrylonitrile.

Concept Introduction:

The octet rule is, tendency of an atom to have eight electrons in its valence shell. In a molecular structure, each single bond indicates two electrons.

Interpretation Introduction

(b)

Interpretation:

The lone pairs needed to complete the octet should be filled in the main group elements in the cysteine.

Concept Introduction:

The octet rule is, tendency of an atom to have eight electrons in its valence shell. In a molecular structure, each single bond indicates two electrons.

Expert Solution & Answer

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Answer 5

Chapter 4, Problem 19P

Interpretation Introduction

(a)

Interpretation:

The lone pairs needed to complete the octet should be filled in the main group elements in the acrylonitrile.

Concept Introduction:

The octet rule is, tendency of an atom to have eight electrons in its valence shell. In a molecular structure, each single bond indicates two electrons.

Interpretation Introduction

(b)

Interpretation:

The lone pairs needed to complete the octet should be filled in the main group elements in the cysteine.

Concept Introduction:

The octet rule is, tendency of an atom to have eight electrons in its valence shell. In a molecular structure, each single bond indicates two electrons.

Answer 6

Chapter 4, Problem 19P

Interpretation Introduction

(a)

Interpretation:

The lone pairs needed to complete the octet should be filled in the main group elements in the acrylonitrile.

Concept Introduction:

The octet rule is, tendency of an atom to have eight electrons in its valence shell. In a molecular structure, each single bond indicates two electrons.

Answer 7

Chapter 4, Problem 19P

Interpretation Introduction

(a)

Interpretation:

The lone pairs needed to complete the octet should be filled in the main group elements in the acrylonitrile.

Concept Introduction:

The octet rule is, tendency of an atom to have eight electrons in its valence shell. In a molecular structure, each single bond indicates two electrons.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The lone pairs needed to complete the octet should be filled in the main group elements in the cysteine.

Concept Introduction:

The octet rule is, tendency of an atom to have eight electrons in its valence shell. In a molecular structure, each single bond indicates two electrons.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The lone pairs needed to complete the octet should be filled in the main group elements in the cysteine.

Concept Introduction:

The octet rule is, tendency of an atom to have eight electrons in its valence shell. In a molecular structure, each single bond indicates two electrons.

Answer 10

Expert Solution & Answer

Answer 11

Expert Solution & Answer

Answer 12

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Answer 13

Ch. 4.1 - Use electron-dot symbols to show how a hydrogen...Ch. 4.1 - Use electron-dot symbols to show how two chlorine...Ch. 4.1 - How many covalent bonds are predicted for each...Ch. 4.1 - Fill in the lone pairs on each atom to give every...Ch. 4.1 - Prob. 4.4P Ch. 4.2 - Draw a Lewis structure for each covalent molecule....Ch. 4.2 - Draw a Lewis structure for dimethyl ether (C2H6O)...Ch. 4.2 - Prob. 4.4PP Ch. 4.2 - Prob. 4.5P Ch. 4.2 - Prob. 4.6P

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(b) Interpretation: The lone pairs needed to complete the octet should be filled in the main group elements in the cysteine. Concept Introduction: The octet rule is, tendency of an atom to have eight electrons in its valence shell. In a molecular structure, each single bond indicates two electrons.

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Chapter 4 Solutions