EBK CHEMICAL PRINCIPLES
8th Edition
ISBN: 9781305856745
Author: DECOSTE
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Textbook Question
Chapter 4, Problem 130CP
Three students were asked to find the identity of themetal in a particular sulfate salt. They dissolved a0.1472-g sample of the salt in water and treated it withexcess barium chloride, resulting in the precipitation ofbarium sulfate. After the precipitate had been filteredand dried, it weighed 0.2327 g.
Each student analyzed the data independently andcame to different conclusions. Pat decided that the metalwas titanium. Chris thought it was sodium. Randy reportedthat it was gallium. What formula did each studentassign to the sulfate salt?
Look for information on the sulfates of gallium, sodium,and titanium in this text and reference books suchas the CRC Handbook of Chemistry and Physics. Whatfurther tests would you suggest to determine which studentis most likely correct?
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ
Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions
about this system:
?
rise
Under these conditions, will the pressure of NOCI tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO?
In other words, if you said the pressure of NOCI will tend to rise, can that
be changed to a tendency to fall by adding NO? Similarly, if you said the
pressure of NOCI will tend to fall, can that be changed to a tendency to
rise by adding NO?
yes
no
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO needed to reverse it.
Round your answer to 2 significant digits.
0.035 atm
✓
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00.
18
Ar
Highlight each glycosidic bond in the molecule below. Then answer the questions in the table under the drawing area.
HO-
HO-
-0
OH
OH
HO
NG
HO-
HO-
OH
OH
OH
OH
NG
OH
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+
Suppose the molecule in the drawing area below were reacted with H₂ over a platinum catalyst. Edit the molecule to show what would happen to it. That is, turn
it into the product of the reaction.
Also, write the name of the product molecule under the drawing area.
Name: ☐
H
C=0
X
H-
OH
HO-
H
HO-
-H
CH₂OH
×
Chapter 4 Solutions
EBK CHEMICAL PRINCIPLES
Ch. 4 - Prob. 1DQCh. 4 - Prob. 2DQCh. 4 - Prob. 3DQCh. 4 - Prob. 4DQCh. 4 - Prob. 5DQCh. 4 - The exposed electrodes of a light bulb are placed...Ch. 4 - Prob. 7DQCh. 4 - Prob. 8DQCh. 4 - Consider separate aqueous solutions of HCland...Ch. 4 - Prob. 10DQ
Ch. 4 - Prob. 11DQCh. 4 - Characterize strong electrolytes versus weak...Ch. 4 - The figures below are molecular-level...Ch. 4 - Prob. 14ECh. 4 - Differentiate between what happens when the...Ch. 4 - Commercial cold packs and hot packs are available...Ch. 4 - Prob. 17ECh. 4 - Prob. 18ECh. 4 - Prob. 19ECh. 4 - Prob. 20ECh. 4 - Prob. 21ECh. 4 - Prob. 22ECh. 4 - Prob. 23ECh. 4 - Prob. 24ECh. 4 - Prob. 25ECh. 4 - Prob. 26ECh. 4 - Prob. 27ECh. 4 - Prob. 28ECh. 4 - Prob. 29ECh. 4 - A stock solution containing Mn2+ ions is prepared...Ch. 4 - Prob. 31ECh. 4 - Prob. 32ECh. 4 - List the formulas of three soluble bromide salts...Ch. 4 - Prob. 34ECh. 4 - Prob. 35ECh. 4 - Prob. 36ECh. 4 - Prob. 37ECh. 4 - Prob. 38ECh. 4 - Write the balanced molecular, complete, and net...Ch. 4 - How would you separate the following ions in...Ch. 4 - Prob. 41ECh. 4 - Prob. 42ECh. 4 - Prob. 43ECh. 4 - What volume of 0.100 M Na3PO4 is required to...Ch. 4 - Prob. 45ECh. 4 - Prob. 46ECh. 4 - Prob. 47ECh. 4 - The following drawings represent aqueous...Ch. 4 - Prob. 49ECh. 4 - Prob. 50ECh. 4 - Prob. 51ECh. 4 - Prob. 52ECh. 4 - Saccharin (C7H5NO3S) is sometimes dispensed in...Ch. 4 - Prob. 54ECh. 4 - A 1.42-g sample of a pure compound with formula...Ch. 4 - Prob. 56ECh. 4 - Prob. 57ECh. 4 - Prob. 58ECh. 4 - Prob. 59ECh. 4 - Prob. 60ECh. 4 - Prob. 61ECh. 4 - Prob. 62ECh. 4 - Prob. 63ECh. 4 - Sodium hydroxide solution is usually standardized...Ch. 4 - Prob. 65ECh. 4 - Prob. 66ECh. 4 - Prob. 67ECh. 4 - A student titrates an unknown amount of...Ch. 4 - Prob. 69ECh. 4 - Prob. 70ECh. 4 - Hydrochloric acid (75.0 mL of 0.250 M) is added...Ch. 4 - Prob. 72ECh. 4 - Prob. 73ECh. 4 - Prob. 74ECh. 4 - Prob. 75ECh. 4 - Prob. 76ECh. 4 - Prob. 77ECh. 4 - Prob. 78ECh. 4 - Prob. 79ECh. 4 - Balance each of the following oxidationreduction...Ch. 4 - Prob. 81ECh. 4 - Prob. 82ECh. 4 - Prob. 83ECh. 4 - Prob. 84ECh. 4 - Prob. 85ECh. 4 - Prob. 86ECh. 4 - Prob. 87ECh. 4 - Prob. 88ECh. 4 - Prob. 89ECh. 4 - Prob. 90ECh. 4 - Prob. 91AECh. 4 - Prob. 92AECh. 4 - Consider a 1.50-g mixture of magnesium nitrate...Ch. 4 - Suppose 50.0 mL of 0.250 M CoCl2 solution is added...Ch. 4 - Prob. 95AECh. 4 - A mixture contains only NaCland Fe(NO3)3 . A...Ch. 4 - A mixture contains only sodium chloride and...Ch. 4 - Prob. 98AECh. 4 - A student added 50.0 mL of an NaOH solution...Ch. 4 - In a 1-L beaker, 203 mL of 0.307 M ammonium...Ch. 4 - It took 25.060.05 mL of a sodium hydroxide...Ch. 4 - You wish to prepare 1 L of a 0.02 M potassium...Ch. 4 - Citric acid, which can be obtained from lemon...Ch. 4 - Acetylsalicylic acid is the active ingredient in...Ch. 4 - A 6.50-g sample of a diprotic acid requires 137.5...Ch. 4 - Prob. 106AECh. 4 - Chlorisondamine chloride (C14H20Cl6N2) is a drug...Ch. 4 - Calculate the concentration of all ions present...Ch. 4 - A solution is prepared by dissolving 0.6706 g...Ch. 4 - For the following chemical reactions, determine...Ch. 4 - What volume of 0.100 M NaOH is required to...Ch. 4 - Prob. 112AECh. 4 - A 450.0-mL sample of a 0.257-M solution of silver...Ch. 4 - Prob. 114AECh. 4 - A 50.00-mL sample of aqueous Ca(OH)2 requires34.66...Ch. 4 - When organic compounds containing sulfur are...Ch. 4 - Assign the oxidation state for the element listed...Ch. 4 - The blood alcohol (C2H5OH) level can be determined...Ch. 4 - Zinc and magnesium metal each react with...Ch. 4 - A 10.00-g sample consisting of a mixture of...Ch. 4 - Consider the reaction of 19.0 g of zinc with...Ch. 4 - Consider an experiment in which two burets, Y and...Ch. 4 - A sample is a mixture of KCl and KBr. When 0.1024...Ch. 4 - You made 100.0 mL of a lead(II) nitrate solution...Ch. 4 - Polychlorinated biphenyls (PCBs) have been used...Ch. 4 - Prob. 126CPCh. 4 - Prob. 127CPCh. 4 - Chromium has been investigated as a coating for...Ch. 4 - Prob. 129CPCh. 4 - Three students were asked to find the identity of...Ch. 4 - A sample is a mixture of AgNO3,CuCl2,andFeCl3...Ch. 4 - Prob. 132MPCh. 4 - You have two 500.0-mL aqueous solutions. Solution...
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