a) Interpretation: The functional groups in the following molecules are to be identified. Concept introduction: It is evident from the following molecules that - a) This structure contains a benzene ring, a primary alcoholic group and a secondary amine group.

Question

Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below. Find the following: (a) The no. of protons corresponding to each signal in the spectra (6) Give the structure of the compound and assign the signals to each proton in the compound. a 70.2 Integration Values C5H10O2 b 47.7 C 46.5 d 69.5 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 Chemical Shift (ppm) 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8

Answer 1

Question

Chapter 3.SE, Problem 22AP

Interpretation Introduction

a)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

a) This structure contains a benzene ring, a primary alcoholic group and a secondary amine group.

Interpretation Introduction

b)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

b) This structure contains a double bond and a ketonic group.

Interpretation Introduction

c)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

c) This structure contains a cyclohexene ring, a secondary amine group attached to the ketonic group that is amide group.

Interpretation Introduction

d)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

d) This structure contains a ketonic group attached to the hydroxyl group that is it contains carboxylic acid group.

Interpretation Introduction

e)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

e) This structure contains two double bond and a ketonic group.

Interpretation Introduction

f)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

f) This structure contains a triple bond, a ketonic and a halide group.

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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below. Find the following: (a) The no. of protons corresponding to each signal in the spectra (6) Give the structure of the compound and assign the signals to each proton in the compound. a 70.2 Integration Values C5H10O2 b 47.7 C 46.5 d 69.5 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 Chemical Shift (ppm) 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8

Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below. Answer the following: (a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure of the molecule below. (b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible. complex splitting patterns assuming J values are not similar. там Br 22 2 3 6 4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0 Chemical Shift (ppm) ra. Br 2 3 6 6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 Chemical Shift (ppm) 2 2 Br 7.3 7.2 7.1 7.0 6.9 6.7 6.6 6.5 6.4 6.3 6.2 6.1 6.0 Chemical Shift (ppm) 5.9 5.8 5.7 5.5 5.4 5.3 5.2 5.0 4.9

1600° 1538°C 1493°C In the diagram, the letter L indicates that it is a liquid. Indicate its components in the upper region where only L is indicated. The iron-iron carbide phase diagram. Temperature (°C) 1400 8 1394°C y+L 1200 2.14 y, Austenite 10000 912°C 800a 0.76 0.022 600 400 (Fe) a, Ferrite Composition (at% C) 15 1147°C a + Fe3C 2 3 Composition (wt% C) L 2500 4.30 2000 y + Fe3C 727°C 1500 Cementite (Fe3C) 1000 4 5 6 6.70 Temperature (°F)

Answer 2

Question

Chapter 3.SE, Problem 22AP

Interpretation Introduction

a)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

a) This structure contains a benzene ring, a primary alcoholic group and a secondary amine group.

Interpretation Introduction

b)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

b) This structure contains a double bond and a ketonic group.

Interpretation Introduction

c)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

c) This structure contains a cyclohexene ring, a secondary amine group attached to the ketonic group that is amide group.

Interpretation Introduction

d)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

d) This structure contains a ketonic group attached to the hydroxyl group that is it contains carboxylic acid group.

Interpretation Introduction

e)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

e) This structure contains two double bond and a ketonic group.

Interpretation Introduction

f)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

f) This structure contains a triple bond, a ketonic and a halide group.

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Answer 3

Question

Chapter 3.SE, Problem 22AP

Interpretation Introduction

a)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

a) This structure contains a benzene ring, a primary alcoholic group and a secondary amine group.

Interpretation Introduction

b)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

b) This structure contains a double bond and a ketonic group.

Interpretation Introduction

c)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

c) This structure contains a cyclohexene ring, a secondary amine group attached to the ketonic group that is amide group.

Interpretation Introduction

d)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

d) This structure contains a ketonic group attached to the hydroxyl group that is it contains carboxylic acid group.

Interpretation Introduction

e)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

e) This structure contains two double bond and a ketonic group.

Interpretation Introduction

f)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

f) This structure contains a triple bond, a ketonic and a halide group.

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Answer 4

Question

Chapter 3.SE, Problem 22AP

Interpretation Introduction

a)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

a) This structure contains a benzene ring, a primary alcoholic group and a secondary amine group.

Interpretation Introduction

b)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

b) This structure contains a double bond and a ketonic group.

Interpretation Introduction

c)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

c) This structure contains a cyclohexene ring, a secondary amine group attached to the ketonic group that is amide group.

Interpretation Introduction

d)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

d) This structure contains a ketonic group attached to the hydroxyl group that is it contains carboxylic acid group.

Interpretation Introduction

e)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

e) This structure contains two double bond and a ketonic group.

Interpretation Introduction

f)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

f) This structure contains a triple bond, a ketonic and a halide group.

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Answer 5

Chapter 3.SE, Problem 22AP

Interpretation Introduction

a)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

a) This structure contains a benzene ring, a primary alcoholic group and a secondary amine group.

Interpretation Introduction

b)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

b) This structure contains a double bond and a ketonic group.

Interpretation Introduction

c)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

c) This structure contains a cyclohexene ring, a secondary amine group attached to the ketonic group that is amide group.

Interpretation Introduction

d)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

d) This structure contains a ketonic group attached to the hydroxyl group that is it contains carboxylic acid group.

Interpretation Introduction

e)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

e) This structure contains two double bond and a ketonic group.

Interpretation Introduction

f)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

f) This structure contains a triple bond, a ketonic and a halide group.

Answer 6

Chapter 3.SE, Problem 22AP

Interpretation Introduction

a)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

a) This structure contains a benzene ring, a primary alcoholic group and a secondary amine group.

Answer 7

Chapter 3.SE, Problem 22AP

Interpretation Introduction

a)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

a) This structure contains a benzene ring, a primary alcoholic group and a secondary amine group.

Answer 8

Interpretation Introduction

b)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

b) This structure contains a double bond and a ketonic group.

Answer 9

Interpretation Introduction

b)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

b) This structure contains a double bond and a ketonic group.

Answer 10

Interpretation Introduction

c)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

c) This structure contains a cyclohexene ring, a secondary amine group attached to the ketonic group that is amide group.

Answer 11

Interpretation Introduction

c)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

c) This structure contains a cyclohexene ring, a secondary amine group attached to the ketonic group that is amide group.

Answer 12

Interpretation Introduction

d)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

d) This structure contains a ketonic group attached to the hydroxyl group that is it contains carboxylic acid group.

Answer 13

Interpretation Introduction

d)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

d) This structure contains a ketonic group attached to the hydroxyl group that is it contains carboxylic acid group.

Answer 14

Interpretation Introduction

e)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

e) This structure contains two double bond and a ketonic group.

Answer 15

Interpretation Introduction

e)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

e) This structure contains two double bond and a ketonic group.

Answer 16

Interpretation Introduction

f)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

f) This structure contains a triple bond, a ketonic and a halide group.

Answer 17

Interpretation Introduction

f)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

f) This structure contains a triple bond, a ketonic and a halide group.

Answer 18

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Answer 29

Ch. 3.1 - Prob. 1P Ch. 3.1 - Prob. 2P Ch. 3.1 - Identify the functional groups in the following...Ch. 3.2 - Draw structures of the five isomers of C6H14.Ch. 3.2 - Propose structures that meet the following...Ch. 3.2 - Prob. 6P Ch. 3.3 - Draw the eight 5-carbon alkyl groups (pentyl...Ch. 3.3 - Identify the carbon atoms in the following...Ch. 3.3 - Prob. 9P Ch. 3.3 - Prob. 10P

a) Interpretation: The functional groups in the following molecules are to be identified. Concept introduction: It is evident from the following molecules that - a) This structure contains a benzene ring, a primary alcoholic group and a secondary amine group.

Concept explainers

a)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

a) This structure contains a benzene ring, a primary alcoholic group and a secondary amine group.

b)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

b) This structure contains a double bond and a ketonic group.

c)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

c) This structure contains a cyclohexene ring, a secondary amine group attached to the ketonic group that is amide group.

d)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

d) This structure contains a ketonic group attached to the hydroxyl group that is it contains carboxylic acid group.

e)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

e) This structure contains two double bond and a ketonic group.

f)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

f) This structure contains a triple bond, a ketonic and a halide group.

Chapter 3 Solutions

a) Interpretation: The functional groups in the following molecules are to be identified. Concept introduction: It is evident from the following molecules that - a) This structure contains a benzene ring, a primary alcoholic group and a secondary amine group.

Concept explainers

a) Interpretation: The functional groups in the following molecules are to be identified. Concept introduction: It is evident from the following molecules that - a) This structure contains a benzene ring, a primary alcoholic group and a secondary amine group.

b) Interpretation: The functional groups in the following molecules are to be identified. Concept introduction: It is evident from the following molecules that - b) This structure contains a double bond and a ketonic group.

c) Interpretation: The functional groups in the following molecules are to be identified. Concept introduction: It is evident from the following molecules that - c) This structure contains a cyclohexene ring, a secondary amine group attached to the ketonic group that is amide group.

d) Interpretation: The functional groups in the following molecules are to be identified. Concept introduction: It is evident from the following molecules that - d) This structure contains a ketonic group attached to the hydroxyl group that is it contains carboxylic acid group.

e) Interpretation: The functional groups in the following molecules are to be identified. Concept introduction: It is evident from the following molecules that - e) This structure contains two double bond and a ketonic group.

f) Interpretation: The functional groups in the following molecules are to be identified. Concept introduction: It is evident from the following molecules that - f) This structure contains a triple bond, a ketonic and a halide group.

Chapter 3 Solutions

a)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

a) This structure contains a benzene ring, a primary alcoholic group and a secondary amine group.

b)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

b) This structure contains a double bond and a ketonic group.

c)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

c) This structure contains a cyclohexene ring, a secondary amine group attached to the ketonic group that is amide group.

d)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

d) This structure contains a ketonic group attached to the hydroxyl group that is it contains carboxylic acid group.

e)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

e) This structure contains two double bond and a ketonic group.

f)

Interpretation:

The functional groups in the following molecules are to be identified.

Concept introduction:

It is evident from the following molecules that -

f) This structure contains a triple bond, a ketonic and a halide group.