a) Two tertiary carbons Interpretation: The structures of the alkanes containing the following groups are to be drawn. Concept introduction: Primary carbons are carbons attached to one carbon. Secondary carbons are attached to two other carbons. Tertiary carbons are attached to three other carbons. Finally, quaternary carbons are attached to four other carbons.

Question

For the photochemical halogenation reaction below, draw both propagation steps and include the mechanism arrows for each step. H CH ot CH3 CI-CI MM hv of CH H-CI CH3 2nd attempt See Periodic Table See Hint Draw only radical electrons; do not add lone pair electrons. Note that arrows cannot meet in "space," and must end at either bonds or at atoms. 1 i Add the missing curved arrow notation to this propagation step. 20 H ن S F P H CI Br 品

Answer 1

Question

Chapter 3.3, Problem 10P

Interpretation Introduction

a) Two tertiary carbons

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

Interpretation Introduction

b) Isopropyl group

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

Interpretation Introduction

c) One quaternary and one secondary carbons

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

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For the photochemical halogenation reaction below, draw both propagation steps and include the mechanism arrows for each step. H CH ot CH3 CI-CI MM hv of CH H-CI CH3 2nd attempt See Periodic Table See Hint Draw only radical electrons; do not add lone pair electrons. Note that arrows cannot meet in "space," and must end at either bonds or at atoms. 1 i Add the missing curved arrow notation to this propagation step. 20 H ن S F P H CI Br 品

The radical below can be stabilized by resonance. 4th attempt Draw the resulting resonance structure. DOCE

Use curved arrows to generate a second resonance form for the allylic radical formed from 2-methyl-2-pentene. 1 Draw the curved arrows that would generate a second resonance form for this radical. D 2 H S F A Бг I

Answer 2

Question

Chapter 3.3, Problem 10P

Interpretation Introduction

a) Two tertiary carbons

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

Interpretation Introduction

b) Isopropyl group

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

Interpretation Introduction

c) One quaternary and one secondary carbons

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

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Answer 3

Question

Chapter 3.3, Problem 10P

Interpretation Introduction

a) Two tertiary carbons

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

Interpretation Introduction

b) Isopropyl group

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

Interpretation Introduction

c) One quaternary and one secondary carbons

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

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Answer 4

Question

Chapter 3.3, Problem 10P

Interpretation Introduction

a) Two tertiary carbons

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

Interpretation Introduction

b) Isopropyl group

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

Interpretation Introduction

c) One quaternary and one secondary carbons

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

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Answer 5

Chapter 3.3, Problem 10P

Interpretation Introduction

a) Two tertiary carbons

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

Interpretation Introduction

b) Isopropyl group

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

Interpretation Introduction

c) One quaternary and one secondary carbons

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

Answer 6

Chapter 3.3, Problem 10P

Interpretation Introduction

a) Two tertiary carbons

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

Answer 7

Chapter 3.3, Problem 10P

Interpretation Introduction

a) Two tertiary carbons

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

Answer 8

Interpretation Introduction

b) Isopropyl group

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

Answer 9

Interpretation Introduction

b) Isopropyl group

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

Answer 10

Interpretation Introduction

c) One quaternary and one secondary carbons

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

Answer 11

Interpretation Introduction

c) One quaternary and one secondary carbons

Interpretation:

The structures of the alkanes containing the following groups are to be drawn.

Concept introduction:

Primary carbons are carbons attached to one carbon.

Secondary carbons are attached to two other carbons.

Tertiary carbons are attached to three other carbons.

Finally, quaternary carbons are attached to four other carbons.

Answer 12

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Answer 23

Ch. 3.1 - Prob. 1P Ch. 3.1 - Prob. 2P Ch. 3.1 - Identify the functional groups in the following...Ch. 3.2 - Draw structures of the five isomers of C6H14.Ch. 3.2 - Propose structures that meet the following...Ch. 3.2 - Prob. 6P Ch. 3.3 - Draw the eight 5-carbon alkyl groups (pentyl...Ch. 3.3 - Identify the carbon atoms in the following...Ch. 3.3 - Prob. 9P Ch. 3.3 - Prob. 10P

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