EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
3rd Edition
ISBN: 9781259298424
Author: SMITH
Publisher: VST
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Chapter 3.3, Problem 3.12P
Interpretation Introduction
Interpretation:
The pair of elements that will form the ionic compound should be selected from the given pairs.
Concept Introduction:
The ionic compound is defined as elements that are bonded by the ionic bond. In this, the ion of the elements is bonded together by the electrostatic force of attraction known as an ionic bond.
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32. Consider a two-state system in which the low energy level is 300 J mol 1 and the higher energy
level is 800 J mol 1, and the temperature is 300 K. Find the population of each level. Hint: Pay attention
to your units.
A. What is the partition function for this system?
B. What are the populations of each level?
Now instead, consider a system with energy levels of 0 J mol
C. Now what is the partition function?
D. And what are the populations of the two levels?
E. Finally, repeat the second calculation at 500 K.
and 500 J mol 1 at 300 K.
F. What do you notice about the populations as you increase the temperature? At what temperature
would you expect the states to have equal populations?
30. We will derive the forms of the molecular partition functions for atoms and molecules shortly in
class, but the partition function that describes the translational and rotational motion of a homonuclear
diatomic molecule is given by
Itrans (V,T) =
=
2πmkBT
h²
V
grot (T)
4π²IKBT
h²
Where h is Planck's constant and I is molecular moment of inertia.
The overall partition function is qmolec Qtrans qrot.
Find the energy, enthalpy, entropy, and Helmholtz free energy for the translational and rotational
modes of 1 mole of oxygen molecules and 1 mole of iodine molecules at 50 K and at 300 K and with a
volume of 1 m³. Here is some useful data:
Moment of inertia:
I2 I 7.46 x 10-
45
kg m²
2
O2 I 1.91 x 101
-46
kg m²
K
for each reaction step.
Be sure to account for all bond-breaking and bond-making
steps.
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Chapter 3 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
Ch. 3.1 - Predict whether the bonds in the following species...Ch. 3.1 - (a) Classify each example of molecular art as a...Ch. 3.1 - Label each of the following as a compound,...Ch. 3.1 - Vitamin C has the chemical formula C6H8O6. Even if...Ch. 3.2 - Prob. 3.5PCh. 3.2 - Write the ion symbol for an atom with the given...Ch. 3.2 - How many protons and electrons are present in each...Ch. 3.2 - Prob. 3.8PCh. 3.2 - Prob. 3.9PCh. 3.2 - How many electrons and protons are contained in...
Ch. 3.2 - Mn2+ is an essential nutrient needed for blood...Ch. 3.3 - Prob. 3.12PCh. 3.3 - Prob. 3.13PCh. 3.3 - Prob. 3.14PCh. 3.3 - Prob. 3.15PCh. 3.4 - Prob. 3.16PCh. 3.4 - Prob. 3.17PCh. 3.4 - Prob. 3.18PCh. 3.4 - Prob. 3.19PCh. 3.4 - Prob. 3.20PCh. 3.4 - Prob. 3.21PCh. 3.4 - Prob. 3.22PCh. 3.5 - List four physical properties of ionic compounds.Ch. 3.6 - Prob. 3.24PCh. 3.6 - Prob. 3.25PCh. 3.6 - Prob. 3.26PCh. 3.6 - Prob. 3.27PCh. 3.6 - Using the charges on the ions that compose...Ch. 3 - Which formulas represent ionic compounds and which...Ch. 3 - Which formulas represent ionic compound and which...Ch. 3 - Which pairs of elements are likely to form ionic...Ch. 3 - Which pairs of elements are likely to form ionic...Ch. 3 - Prob. 3.33PCh. 3 - Prob. 3.34PCh. 3 - Write the ion symbol for an atom with the given...Ch. 3 - How many protons and electrons are present in each...Ch. 3 - What species fits each description?
a. a period 2...Ch. 3 - Prob. 3.38PCh. 3 - Prob. 3.39PCh. 3 - Prob. 3.40PCh. 3 - Prob. 3.41PCh. 3 - Prob. 3.42PCh. 3 - Prob. 3.43PCh. 3 - How many electrons must be gained or lost by each...Ch. 3 - For each of the general electron-dot formulas for...Ch. 3 - Label each of the following elements or regions in...Ch. 3 - Prob. 3.47PCh. 3 - Prob. 3.48PCh. 3 - Prob. 3.49PCh. 3 - Prob. 3.50PCh. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - Prob. 3.53PCh. 3 - Prob. 3.54PCh. 3 - How many protons and electrons are contained in...Ch. 3 - How many protons and electrons are contained in...Ch. 3 - Identify the polyatomic anion (including its...Ch. 3 - Prob. 3.58PCh. 3 - Prob. 3.59PCh. 3 - Prob. 3.60PCh. 3 - Prob. 3.61PCh. 3 - Prob. 3.62PCh. 3 - Prob. 3.63PCh. 3 - Prob. 3.64PCh. 3 - What is the charge on the cation M in each of the...Ch. 3 - What is the charge on the anion Z in each of the...Ch. 3 - Prob. 3.67PCh. 3 - Prob. 3.68PCh. 3 - Write the formula for the ionic compound formed...Ch. 3 - Prob. 3.70PCh. 3 - Write the formula for the ionic compound formed...Ch. 3 - Write the formula for the ionic compound formed...Ch. 3 - Prob. 3.73PCh. 3 - Prob. 3.74PCh. 3 - Prob. 3.75PCh. 3 - Prob. 3.76PCh. 3 - Prob. 3.77PCh. 3 - Prob. 3.78PCh. 3 - Prob. 3.79PCh. 3 - Prob. 3.80PCh. 3 - Prob. 3.81PCh. 3 - Prob. 3.82PCh. 3 - Prob. 3.83PCh. 3 - Prob. 3.84PCh. 3 - Prob. 3.85PCh. 3 - Prob. 3.86PCh. 3 - Prob. 3.87PCh. 3 - Prob. 3.88PCh. 3 - Prob. 3.89PCh. 3 - Prob. 3.90PCh. 3 - Prob. 3.91PCh. 3 - Prob. 3.92PCh. 3 - Prob. 3.93PCh. 3 - Prob. 3.94PCh. 3 - Prob. 3.95PCh. 3 - Prob. 3.96PCh. 3 - Prob. 3.97PCh. 3 - Prob. 3.98PCh. 3 - Energy bars contain ionic compounds that serve as...Ch. 3 - Prob. 3.100CP
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