OWLV2 FOR MOORE/STANITSKI'S CHEMISTRY:
5th Edition
ISBN: 9781285460369
Author: STANITSKI
Publisher: Cengage Learning
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Question
Chapter 3.12, Problem 3.25PSP
Interpretation Introduction
Interpretation:
The molarity of the
Concept introduction:
Molar mass of a substance is the mass in grams of one mole of a substance.
Molarity can be calculated by using following formula
The Molarity of the solution can be calculated by using following formula
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 3 Solutions
OWLV2 FOR MOORE/STANITSKI'S CHEMISTRY:
Ch. 3.1 - When washing soda, Na2CO3, reacts with sulfuric...Ch. 3.2 - When sprayed into the flame of a torch, powdered...Ch. 3.2 - Prob. 3.1PSPCh. 3.2 - Prob. 3.2PSPCh. 3.3 - Prob. 3.3PSPCh. 3.3 - Prob. 3.4PSPCh. 3.3 - Prob. 3.5PSPCh. 3.3 - Prob. 3.6PSPCh. 3.3 - Prob. 3.3CECh. 3.4 - Phosphoric acid, H3PO4, has three protons that can...
Ch. 3.4 - Prob. 3.5CECh. 3.4 - Look back through the discussion of electrolytes...Ch. 3.4 - Prob. 3.8PSPCh. 3.4 - Prob. 3.9PSPCh. 3.4 - Write a balanced equation for the reaction of...Ch. 3.4 - Prob. 3.6ECh. 3.4 - Prob. 3.7ECh. 3.4 - Prob. 3.8ECh. 3.4 - Prob. 3.9CECh. 3.4 - Prob. 3.10CECh. 3.5 - Prob. 3.11CECh. 3.5 - Prob. 3.12CECh. 3.5 - Prob. 3.13ECh. 3.5 - Prob. 3.11PSPCh. 3.5 - Prob. 3.12PSPCh. 3.5 - Prob. 3.14CECh. 3.6 - Prob. 3.15CECh. 3.6 - Prob. 3.16ECh. 3.6 - Prob. 3.13PSPCh. 3.6 - Prob. 3.17ECh. 3.6 - Prob. 3.14PSPCh. 3.7 - Prob. 3.15PSPCh. 3.7 - Using the same reaction, calculate the mass of...Ch. 3.7 - At high temperatures, silicon dioxide reacts with...Ch. 3.7 - Urea is used as a fertilizer because it can react...Ch. 3.8 - Assume the methanol synthesis has an 85.0% yield...Ch. 3.8 - Prob. 3.19PSPCh. 3.8 - Prob. 3.19ECh. 3.8 - Prob. 3.20ECh. 3.9 - Phenol is a compound of carbon, hydrogen, and...Ch. 3.9 - Calcium carbonate forms carbon dioxide and calcium...Ch. 3.10 - Prob. 3.20PSPCh. 3.10 - Prob. 3.23ECh. 3.10 - Prob. 3.24ECh. 3.10 - Prob. 3.25CECh. 3.10 - Describe how you would prepare each solution.
1.00...Ch. 3.10 - Prob. 3.26ECh. 3.10 - Prob. 3.22PSPCh. 3.10 - Prob. 3.27CECh. 3.11 - Prob. 3.23PSPCh. 3.11 - Prob. 3.24PSPCh. 3.11 - Sodium chloride is used in intravenous solutions...Ch. 3.12 - Show that the reaction of KMnO4 with H2O2 is a...Ch. 3.12 - Prob. 3.25PSPCh. 3 - Aqueous solutions of ammonium sulfide and...Ch. 3 - In a blast furnace at high temperature, iron(III)...Ch. 3 - What information does a balanced chemical equation...Ch. 3 - Prob. 2QRTCh. 3 - Prob. 3QRTCh. 3 - Prob. 4QRTCh. 3 - Prob. 5QRTCh. 3 - Prob. 6QRTCh. 3 - When asked, “What is the limiting reactant?” you...Ch. 3 - Prob. 8QRTCh. 3 - Prob. 9QRTCh. 3 - For this reaction, fill in the table with the...Ch. 3 - Prob. 11QRTCh. 3 - Prob. 12QRTCh. 3 - This diagram shows A (blue spheres) reacting with...Ch. 3 - Prob. 14QRTCh. 3 - Prob. 15QRTCh. 3 - Prob. 16QRTCh. 3 - Prob. 17QRTCh. 3 - Prob. 18QRTCh. 3 - Prob. 19QRTCh. 3 - Balance these equations. (a) UO2(s) + HF() UF4(s)...Ch. 3 - Prob. 21QRTCh. 3 - Prob. 22QRTCh. 3 - Prob. 23QRTCh. 3 - Balance these combustion reactions. (a) C6H12O6 +...Ch. 3 - Prob. 25QRTCh. 3 - Prob. 26QRTCh. 3 - Prob. 27QRTCh. 3 - Which substance conducts electricity when...Ch. 3 - Prob. 29QRTCh. 3 - Predict whether each compound is soluble in water....Ch. 3 - Prob. 31QRTCh. 3 - Which drawing is the best nanoscale representation...Ch. 3 - If aqueous solutions of potassium carbonate and...Ch. 3 - If aqueous solutions of potassium sulfide and...Ch. 3 - Prob. 35QRTCh. 3 - Prob. 36QRTCh. 3 - Prob. 37QRTCh. 3 - Prob. 38QRTCh. 3 - Prob. 39QRTCh. 3 - Prob. 40QRTCh. 3 - Prob. 41QRTCh. 3 - Prob. 42QRTCh. 3 - Prob. 43QRTCh. 3 - Prob. 44QRTCh. 3 - Prob. 45QRTCh. 3 - Prob. 46QRTCh. 3 - Prob. 47QRTCh. 3 - Prob. 48QRTCh. 3 - Prob. 49QRTCh. 3 - Prob. 50QRTCh. 3 - Prob. 51QRTCh. 3 - Prob. 52QRTCh. 3 - Prob. 53QRTCh. 3 - Prob. 54QRTCh. 3 - Prob. 55QRTCh. 3 - Prob. 56QRTCh. 3 - Prob. 57QRTCh. 3 - Prob. 58QRTCh. 3 - Nitrogen monoxide is oxidized in air to give brown...Ch. 3 - Prob. 60QRTCh. 3 - The final step in the manufacture of platinum...Ch. 3 - Disulfur dichloride, S2Cl2, is used to vulcanize...Ch. 3 - Prob. 63QRTCh. 3 - Prob. 64QRTCh. 3 - Prob. 65QRTCh. 3 - Prob. 66QRTCh. 3 - Prob. 67QRTCh. 3 - Cisplatin, Pt(NH3)2Cl2, a drug used in the...Ch. 3 - Aluminum chloride, Al2Cl6, is an inexpensive...Ch. 3 - Prob. 70QRTCh. 3 - Prob. 71QRTCh. 3 - Prob. 72QRTCh. 3 - Prob. 73QRTCh. 3 - Quicklime, CaO, is formed when calcium hydroxide...Ch. 3 - Prob. 75QRTCh. 3 - Disulfur dichloride, which has a revolting smell,...Ch. 3 - Prob. 77QRTCh. 3 - Prob. 78QRTCh. 3 - Quinone, which is used in the dye industry and in...Ch. 3 - l-Dopa is a drug used for the treatment of...Ch. 3 - Write the balanced chemical equation for the...Ch. 3 - Prob. 82QRTCh. 3 - Prob. 83QRTCh. 3 - Prob. 84QRTCh. 3 - Prob. 85QRTCh. 3 - Prob. 86QRTCh. 3 - You need 300. mL of 0.500-M K2Cr2O7. Which method...Ch. 3 - You need to make a 0.300-M solution of NiSO4(aq)....Ch. 3 - You wish to make a 0.200-M solution of CuSO4(aq)....Ch. 3 - Prob. 90QRTCh. 3 - Prob. 91QRTCh. 3 - You mix 25.0 mL of 0.234-M FeCl3 solution with...Ch. 3 - A soft drink contains an unknown mass of citric...Ch. 3 - Prob. 94QRTCh. 3 - Prob. 95QRTCh. 3 - Potassium hydrogen phthalate, KHC8H4O4, is used to...Ch. 3 - Prob. 97QRTCh. 3 - Prob. 98QRTCh. 3 - Prob. 99QRTCh. 3 - Prob. 100QRTCh. 3 - Boron forms an extensive series of compounds with...Ch. 3 - Prob. 102QRTCh. 3 - Prob. 103QRTCh. 3 - Prob. 104QRTCh. 3 - Prob. 105QRTCh. 3 - Azurite is a copper-containing mineral that often...Ch. 3 - Prob. 107QRTCh. 3 - Prob. 108QRTCh. 3 - Vitamin C is ascorbic acid, HC6H7O6, which can be...Ch. 3 - Prob. 110QRTCh. 3 - Prob. 111QRTCh. 3 - Prob. 112QRTCh. 3 - Prob. 113QRTCh. 3 - Prob. 114QRTCh. 3 - Prob. 115QRTCh. 3 - Prob. 116QRTCh. 3 - Prob. 117QRTCh. 3 - Prob. 118QRTCh. 3 - Prob. 119QRTCh. 3 - Prob. 120QRTCh. 3 - Ammonia can be formed by a direct reaction of...Ch. 3 - Carbon monoxide burns readily in oxygen to form...Ch. 3 - Prob. 123QRTCh. 3 - Write a balanced chemical equation that represents...Ch. 3 - A student set up an experiment for six different...Ch. 3 - A weighed sample of a metal is added to liquid...Ch. 3 - Prob. 127QRTCh. 3 - Prob. 128QRTCh. 3 - Each box represents a tiny volume in an aqueous...Ch. 3 - Consider the chemical reaction 2 S + 3 O2 → 2 SO3....Ch. 3 - Prob. 131QRTCh. 3 - Prob. 132QRTCh. 3 - Prob. 133QRTCh. 3 - Prob. 134QRTCh. 3 - Prob. 135QRTCh. 3 - Prob. 136QRTCh. 3 - Prob. 137QRTCh. 3 - Prob. 138QRTCh. 3 - Prob. 139QRTCh. 3 - Prob. 140QRTCh. 3 - Prob. 141QRTCh. 3 - Prob. 142QRTCh. 3 - In a reaction, 1.2 g element A reacts with exactly...Ch. 3 - Prob. 144QRTCh. 3 - When solutions of silver nitrate and sodium...Ch. 3 - Nickel metal reacts with aqueous silver nitrate in...Ch. 3 - Prob. 147QRTCh. 3 - Prob. 148QRTCh. 3 - Prob. 149QRTCh. 3 - Prob. 150QRTCh. 3 - A mountain lake that is 4.0 km × 6.0 km with an...Ch. 3 - Prob. 152QRTCh. 3 - Prob. 153QRTCh. 3 - Prob. 154QRTCh. 3 - Prob. 155QRTCh. 3 - Ethanol, C2H5OH, is a gasoline additive that can...Ch. 3 - Prob. 157QRTCh. 3 - Prob. 3.ACPCh. 3 - Prob. 3.BCPCh. 3 - Prob. 3.DCPCh. 3 - Prob. 3.ECPCh. 3 - Prob. 3.FCPCh. 3 - Prob. 3.GCP
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