Physics (5th Edition)
5th Edition
ISBN: 9780321976444
Author: James S. Walker
Publisher: PEARSON
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Question
Chapter 31, Problem 8CQ
(a)
To determine
The value of
n
angular momentum of the electron must be zero.
(b)
To determine
Whether the angular momentum of the electron can be zero or not with other values of
n
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The electron in a hydrogen atom with anenergy of -0.544 eV is in a subshell with 18 states. (a) What is theprincipal quantum number, n, for this atom? (b) What is the maximum possible orbital angular momentum this atom can have?(c) Is the number of states in the subshell with the next lowestvalue of / equal to 16, 14, or 12? Explain.
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We want to look at the angular momentum structure of one electronic level of an atom.
a. The atom has orbital angular momentum L, electron spin angular momentum S and nuclear angular momentum I. For very large magnetic fields B, what are the quantum numbers and energies?
b. In addition to the static B field along the z axis, we add a transverse oscillating magnetic field. Which states are now coupled by the oscillating field, i.e. between which states are transitions induced?
Chapter 31 Solutions
Physics (5th Edition)
Ch. 31.1 - Prob. 1EYUCh. 31.2 - Prob. 2EYUCh. 31.3 - Prob. 3EYUCh. 31.4 - Prob. 4EYUCh. 31.5 - Prob. 5EYUCh. 31.6 - Prob. 6EYUCh. 31.7 - Prob. 7EYUCh. 31 - Prob. 1CQCh. 31 - Prob. 2CQCh. 31 - Prob. 3CQ
Ch. 31 - Prob. 4CQCh. 31 - Prob. 5CQCh. 31 - Prob. 6CQCh. 31 - Prob. 7CQCh. 31 - Prob. 8CQCh. 31 - Prob. 9CQCh. 31 - Prob. 1PCECh. 31 - Prob. 2PCECh. 31 - Prob. 3PCECh. 31 - Prob. 4PCECh. 31 - Prob. 5PCECh. 31 - Prob. 6PCECh. 31 - Prob. 7PCECh. 31 - Prob. 8PCECh. 31 - Prob. 9PCECh. 31 - Prob. 10PCECh. 31 - Prob. 11PCECh. 31 - Prob. 12PCECh. 31 - Prob. 13PCECh. 31 - Prob. 14PCECh. 31 - Prob. 15PCECh. 31 - Prob. 16PCECh. 31 - Prob. 17PCECh. 31 - Prob. 18PCECh. 31 - Prob. 19PCECh. 31 - Prob. 20PCECh. 31 - Prob. 21PCECh. 31 - Prob. 22PCECh. 31 - Prob. 23PCECh. 31 - Prob. 24PCECh. 31 - Prob. 25PCECh. 31 - Prob. 26PCECh. 31 - Prob. 27PCECh. 31 - Prob. 28PCECh. 31 - Prob. 29PCECh. 31 - Prob. 30PCECh. 31 - Prob. 31PCECh. 31 - Prob. 32PCECh. 31 - Prob. 33PCECh. 31 - Prob. 34PCECh. 31 - Prob. 35PCECh. 31 - Prob. 36PCECh. 31 - Prob. 37PCECh. 31 - Prob. 38PCECh. 31 - Prob. 39PCECh. 31 - Prob. 40PCECh. 31 - Prob. 41PCECh. 31 - Prob. 42PCECh. 31 - Prob. 43PCECh. 31 - Prob. 44PCECh. 31 - Prob. 45PCECh. 31 - Prob. 46PCECh. 31 - Prob. 47PCECh. 31 - Prob. 48PCECh. 31 - Prob. 49PCECh. 31 - Prob. 50PCECh. 31 - Prob. 51PCECh. 31 - Prob. 52PCECh. 31 - Give the electronic configuration for the ground...Ch. 31 - Prob. 54PCECh. 31 - Prob. 55PCECh. 31 - Prob. 56PCECh. 31 - The configuration of the outer electrons in Ni is...Ch. 31 - Prob. 58PCECh. 31 - Prob. 59PCECh. 31 - Prob. 60PCECh. 31 - Prob. 61PCECh. 31 - Prob. 62PCECh. 31 - Prob. 63PCECh. 31 - Prob. 64PCECh. 31 - Prob. 65PCECh. 31 - Prob. 66PCECh. 31 - Prob. 67PCECh. 31 - Prob. 68GPCh. 31 - Prob. 69GPCh. 31 - Prob. 70GPCh. 31 - Prob. 71GPCh. 31 - Prob. 72GPCh. 31 - Prob. 73GPCh. 31 - Prob. 74GPCh. 31 - Prob. 75GPCh. 31 - Prob. 76GPCh. 31 - Prob. 77GPCh. 31 - Prob. 78GPCh. 31 - Prob. 79GPCh. 31 - Prob. 80GPCh. 31 - Prob. 81GPCh. 31 - Prob. 82GPCh. 31 - Prob. 83GPCh. 31 - Prob. 84PPCh. 31 - Prob. 85PPCh. 31 - Prob. 86PPCh. 31 - Prob. 87PPCh. 31 - Prob. 88PPCh. 31 - Prob. 89PP
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- For an electron in a hydrogen atom in the n=2 state, compute: (a) the angular momentum; (b) the kinetic energy; (c) the potential energy; and (d) the total energy.arrow_forwardWhat are the possible values of m for an electron in the n = 4 state?arrow_forwardFor a hydrogen atom in an excited state with principal quantum number n, show that the smallest angle that the orbital angular momentum vector can make with respect to the z-axis is =cos1( n1n) .arrow_forward
- Consider hydrogen in the ground state, 100 . (a) Use the derivative to determine the radial position for which the probability density, P(r), is a maximum. (b) Use the integral concept to determine the average radial position. (This is called the expectation value of the electrons radial position.) Express your answers into terms of the Bohr radius, a0. Hint: The expectation value is the just average value, (c) Why are these values different?arrow_forwardQuantum Physicsarrow_forwardUsing the information from the hydrogen atom diagram provided, what energy level would the electron in the hydrogen atom jump to if it is initially in the n = 2 energy level and collides with a free electron that has a kinetic energy of 2 eV?arrow_forward
- Angular momentum and Spin. An electron in an H-atom has orbital angular momentum magnitude and z-component given by L² = 1(1+1)ħ², 1 = 0,1,2,..., n-1 Lz = m₂ħ, m₁ = 0, ±1, ±2,..., ±l 3 S² = s(s+1)h² = h², 4 Consider an excited electron (n > 1) on an H-atom. Sz = msh 1 =+=ħ Show that the minimum angle that the I can have with the z-axis is given by n-1 n L.min = cos Clue: the angle a vector with magnitude V from the z-axis can be computed from cos 0 = V²/Varrow_forwardThe allowed energies of a simple atom are 0.0 eV, 4.0 eV, and 6.0 eV. An electron traveling at a speed of 1.5x106 m/s collisionally excites the atom. Part A) What is the minimum speed the electron could have after the collision? Part B) What is the maximum speed the electron could have after the collision?arrow_forwardQuantum numbers arise naturally from the mathematics used to describe the possible states of an electron in an atom. The four quantum numbers, the principal quantum number (?),(n), the angular momentum quantum number (?),(?), the magnetic quantum number (??),(m?), and the spin quantum number (?s)(ms) have strict rules which govern the possible values. Identify all allowable combinations of quantum numbers for an electron. A. ?=4,n=4, ?=1,?=1, ??=2,m?=2, ?s=−1/2ms B.?=3,n=3, ?=−1,?=−1, ??=1,m?=1, ?s=−1/2ms C.?=5,n=5, ?=2,?=2, ??=2,m?=2, ?s=+1/2ms D.?=3,n=3, ?=3,?=3, ??=1,m?=1, ?s=−1/2ms E.?=2,n=2, ?=1,?=1, ??=1,m?=1, ?s=0ms F. ?=3,n=3, ?=1,?=1, ??=1,m?=1, ?s=+1/2arrow_forward
- 8. An electron in H atom occupies the state (√eve + R21 a) What is the energy of the electron? b) If you measure the total angular momentum squared (L²), what value(s) you will get and with what probability? c) If you measure the z-component of orbital angular momentum (L₂), what value(s) you might get and with what probability?arrow_forwardAngular momentum and Spin. An electron in an H-atom has orbital angular momentum magnitude and z-component given by L² = 1(1+1)ħ², Lz = m₁h, 1 = 0,1,2,..., n 1 - m₁ = 0, ±1, ±2, ..., ±l 3 S² = s(s+1) h² = =h²₁ 4 Consider an excited electron (n > 1) on an H-atom. The total angular momentum ] = L + Š, whose magnitude and z-component follow a similar dependence to some quantum numbers j and m; as J² = j(j + 1)ħ², Jz = mjħ 1 S₂ = m₂h = ± = h Where j and m; are quantum numbers which assume values that jumps in steps of one such that j is non-negative and −j ≤ m¡ ≤ j. For a given quantum number 1, what are the (two) possible values for j? Clue: we can use the vector sum relation of angular momenta, then consider the z-component only.arrow_forwardAn electron is in the nth Bohr orbit of the hydrogen atom. n3 (a) Show that the period of the electron is T = to n³ and determine the numerical value of to. 153 as (b) On average, an electron remains in the n = 2 orbit for approximately 8 us before it jumps down to the n = 1 (ground-state)orbit. How many revolutions does the electron make in the excited state? 8.26e+09 × (c) Define the period of one revolution as an electron year, analogous to an Earth year being the period of the Earth's motion around the Sun. Explain whether we should think of the electron in the n = 2 orbit as "living for a long time."arrow_forward
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