Physics (5th Edition)
Physics (5th Edition)
5th Edition
ISBN: 9780321976444
Author: James S. Walker
Publisher: PEARSON
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Chapter 31, Problem 44PCE

(a)

To determine

The value of quantum number l , if one exists, for a hydrogen atom whose orbital angular momentum has a magnitude of 6h2π .

(b)

To determine

The value of quantum number l , if one exists, for a hydrogen atom whose orbital angular momentum has a magnitude of 15h2π .

(c)

To determine

The value of quantum number l , if one exists, for a hydrogen atom whose orbital angular momentum has a magnitude of 30h2π .

(d)

To determine

The value of quantum number l , if one exists, for a hydrogen atom whose orbital angular momentum has a magnitude of 36h2π .

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Angular momentum and Spin. An electron in an H-atom has orbital angular momentum magnitude and z-component given by L² = 1(1+1)ħ², Lz = m₁h, 1 = 0,1,2,..., n 1 - m₁ = 0, ±1, ±2, ..., ±l 3 S² = s(s+1) h² = =h²₁ 4 Consider an excited electron (n > 1) on an H-atom. The total angular momentum ] = L + Š, whose magnitude and z-component follow a similar dependence to some quantum numbers j and m; as J² = j(j + 1)ħ², Jz = mjħ 1 S₂ = m₂h = ± = h Where j and m; are quantum numbers which assume values that jumps in steps of one such that j is non-negative and −j ≤ m¡ ≤ j. For a given quantum number 1, what are the (two) possible values for j? Clue: we can use the vector sum relation of angular momenta, then consider the z-component only.
Angular momentum and Spin. An electron in an H-atom has orbital angular momentum magnitude and z-component given by L² = 1(1+1)ħ², 1 = 0,1,2,..., n-1 Lz = m₂ħ, m₁ = 0, ±1, ±2,..., ±l 3 S² = s(s+1)h² = h², 4 Consider an excited electron (n > 1) on an H-atom. Sz = msh 1 =+=ħ Show that the minimum angle that the I can have with the z-axis is given by n-1 n L.min = cos Clue: the angle a vector with magnitude V from the z-axis can be computed from cos 0 = V²/V
Which of the following is a permissable set of quantum numbers for an electron in a hydrogen atom? The atom may be in an excited state (ie. the electron need not be in its ground state). a) n = 6, l = -5, ml = +4, ms = +1/2 b) n = 4, l = -2, ml = +2, ms = -1/2 c) n = 2, l = 2, ml = +1, ms = -1/2 d) n = 5, l = 1, ml = -1, ms = +1/2 e) n = 3, l = 2, ml = -2, ms = -1

Chapter 31 Solutions

Physics (5th Edition)

Ch. 31 - Prob. 4CQCh. 31 - Prob. 5CQCh. 31 - Prob. 6CQCh. 31 - Prob. 7CQCh. 31 - Prob. 8CQCh. 31 - Prob. 9CQCh. 31 - Prob. 1PCECh. 31 - Prob. 2PCECh. 31 - Prob. 3PCECh. 31 - Prob. 4PCECh. 31 - Prob. 5PCECh. 31 - Prob. 6PCECh. 31 - Prob. 7PCECh. 31 - Prob. 8PCECh. 31 - Prob. 9PCECh. 31 - Prob. 10PCECh. 31 - Prob. 11PCECh. 31 - Prob. 12PCECh. 31 - Prob. 13PCECh. 31 - Prob. 14PCECh. 31 - Prob. 15PCECh. 31 - Prob. 16PCECh. 31 - Prob. 17PCECh. 31 - Prob. 18PCECh. 31 - Prob. 19PCECh. 31 - Prob. 20PCECh. 31 - Prob. 21PCECh. 31 - Prob. 22PCECh. 31 - Prob. 23PCECh. 31 - Prob. 24PCECh. 31 - Prob. 25PCECh. 31 - Prob. 26PCECh. 31 - Prob. 27PCECh. 31 - Prob. 28PCECh. 31 - Prob. 29PCECh. 31 - Prob. 30PCECh. 31 - Prob. 31PCECh. 31 - Prob. 32PCECh. 31 - Prob. 33PCECh. 31 - Prob. 34PCECh. 31 - Prob. 35PCECh. 31 - Prob. 36PCECh. 31 - Prob. 37PCECh. 31 - Prob. 38PCECh. 31 - Prob. 39PCECh. 31 - Prob. 40PCECh. 31 - Prob. 41PCECh. 31 - Prob. 42PCECh. 31 - Prob. 43PCECh. 31 - Prob. 44PCECh. 31 - Prob. 45PCECh. 31 - Prob. 46PCECh. 31 - Prob. 47PCECh. 31 - Prob. 48PCECh. 31 - Prob. 49PCECh. 31 - Prob. 50PCECh. 31 - Prob. 51PCECh. 31 - Prob. 52PCECh. 31 - Give the electronic configuration for the ground...Ch. 31 - Prob. 54PCECh. 31 - Prob. 55PCECh. 31 - Prob. 56PCECh. 31 - The configuration of the outer electrons in Ni is...Ch. 31 - Prob. 58PCECh. 31 - Prob. 59PCECh. 31 - Prob. 60PCECh. 31 - Prob. 61PCECh. 31 - Prob. 62PCECh. 31 - Prob. 63PCECh. 31 - Prob. 64PCECh. 31 - Prob. 65PCECh. 31 - Prob. 66PCECh. 31 - Prob. 67PCECh. 31 - Prob. 68GPCh. 31 - Prob. 69GPCh. 31 - Prob. 70GPCh. 31 - Prob. 71GPCh. 31 - Prob. 72GPCh. 31 - Prob. 73GPCh. 31 - Prob. 74GPCh. 31 - Prob. 75GPCh. 31 - Prob. 76GPCh. 31 - Prob. 77GPCh. 31 - Prob. 78GPCh. 31 - Prob. 79GPCh. 31 - Prob. 80GPCh. 31 - Prob. 81GPCh. 31 - Prob. 82GPCh. 31 - Prob. 83GPCh. 31 - Prob. 84PPCh. 31 - Prob. 85PPCh. 31 - Prob. 86PPCh. 31 - Prob. 87PPCh. 31 - Prob. 88PPCh. 31 - Prob. 89PP
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