
General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Chapter 3, Problem 69E
Interpretation Introduction
Interpretation:
Among the given hydrates, the hydrate with greatest
Concept introduction:
An ionic compound which is neutral in nature is known as salt.
The inorganic salt which contains particular number of water molecules crystallized with salt is known as hydrates.
The mass percent water in a hydrate complex is equal to the ratio of mass of water molecules to the total mass of the complex or salt and multiplies by 100. The mathematical expression is given by:
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 3 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
Ch. 3 - Refer to the color scheme given Figure 3-3, and...Ch. 3 - Give the molecular formulas for the molecules...Ch. 3 - Give the structure formulas of the molecules shown...Ch. 3 - Give the structure formulas of the molecules shown...Ch. 3 - Calculate the total number of (a) atoms one...Ch. 3 - Determine the mass, in grams, of a. 7.34molNO2 b....Ch. 3 - The amino acid methionine, which is essential in...Ch. 3 - Determine the number of moles of Br2 in a sample...Ch. 3 - Without doing detailed calculations, explain which...Ch. 3 - Without doing detailed calculations, determine...
Ch. 3 - Determine the number of moles of a. N2O4 in a 115...Ch. 3 - Determine the mass, in grams, of a. 2.10102 molS2...Ch. 3 - The content of is 15.5g/100 mLblood. The molar...Ch. 3 - In white phosphorus, P atoms are joined into P,...Ch. 3 - Prob. 15ECh. 3 - Prob. 16ECh. 3 - For the mineral torbernite, Cu( UO2)2( PO4)2,8H2O...Ch. 3 - For the compound Ge[S( CH 2 )4CH2]4 determine a....Ch. 3 - Determine the mass percent H in the hydrocarbon...Ch. 3 - Determine the mass percent O in the mineral...Ch. 3 - Determine the mass percent H in the hydrocarbon...Ch. 3 - Prob. 22ECh. 3 - Determine the mass percent of each of the elements...Ch. 3 - Prob. 24ECh. 3 - Determine the percent, by mass,of the indicated...Ch. 3 - All of the following minerals are semiprecious or...Ch. 3 - Without doing calculations, arrange the following...Ch. 3 - Prob. 28ECh. 3 - Two oxides of sulfur have nearly identical...Ch. 3 - An oxide of chromium used in chrome plating has a...Ch. 3 - Diethylene glycol, used to de-ice aircraft, is a...Ch. 3 - Prob. 32ECh. 3 - Determine the empirical formula of (a) the...Ch. 3 - Prob. 34ECh. 3 - A compound of carbon and hydrogen consists of...Ch. 3 - Selenium, an element used in the manufacture of...Ch. 3 - Indigo, the dye for blue jeans, has a percent...Ch. 3 - Prob. 38ECh. 3 - Prob. 39ECh. 3 - The element X forms the compound XOCI2 containing...Ch. 3 - Prob. 41ECh. 3 - Two compounds of CI and X are found to have...Ch. 3 - A 0.1888 g sample of a hydrocarbon produces 0.6260...Ch. 3 - Para-cresol (p-cresol) is used as a disinfectant...Ch. 3 - Dimethylhydrazine is a carbon-hydrogen-nitrogen...Ch. 3 - Prob. 46ECh. 3 - Without doing detailed calculations, explain which...Ch. 3 - Prob. 48ECh. 3 - A 1.562 g sample of the alcohol CH2CHOHCH2CH2 is...Ch. 3 - Prob. 50ECh. 3 - Indicate the oxidation state of the underlined...Ch. 3 - Indicate the oxidation state of S in (a) SO42 (b)...Ch. 3 - Prob. 53ECh. 3 - Prob. 54ECh. 3 - Prob. 55ECh. 3 - Hydrogen and oxygen usually have oxidation states...Ch. 3 - Prob. 57ECh. 3 - Name these compounds: (a)Ba(...Ch. 3 - Prob. 59ECh. 3 - Prob. 60ECh. 3 - Prob. 61ECh. 3 - Prob. 62ECh. 3 - Write a formula for (a) the chloride of titanium...Ch. 3 - Write formula for (a) an oxide of nitrogen with N...Ch. 3 - Prob. 65ECh. 3 - Supply the formula for the acids: (a) hydrofluoric...Ch. 3 - Name the following compounds and specify which...Ch. 3 - Prob. 68ECh. 3 - Prob. 69ECh. 3 - Prob. 70ECh. 3 - Anhydrous CuSO4 can be used to dry liquids in...Ch. 3 - Anhydrous sodium sulfate, Na2SO4 absorbs water...Ch. 3 - A certain hydrate is found to have the composition...Ch. 3 - An 8.129 g sample of MgSO4H2O is heated until all...Ch. 3 - Prob. 75ECh. 3 - Prob. 76ECh. 3 - Prob. 77ECh. 3 - Prob. 78ECh. 3 - Prob. 79ECh. 3 - Prob. 80ECh. 3 - Prob. 81ECh. 3 - Prob. 82ECh. 3 - The mineral spodumene has the empirical formula...Ch. 3 - Prob. 84IAECh. 3 - Prob. 85IAECh. 3 - The important natural sources of boron compounds...Ch. 3 - Prob. 87IAECh. 3 - By analysis, a compound was found to contain 26.58...Ch. 3 - Prob. 89IAECh. 3 - What is the molecular formula of a hydrocarbon...Ch. 3 - A hydrocarbon mixture consists of 601% by mass of...Ch. 3 - A 0.732 g mature of methane, CH4 and ethane, C2H5...Ch. 3 - The density of a mixture of H2SO4 and water is...Ch. 3 - Prob. 94IAECh. 3 - Prob. 95IAECh. 3 - Prob. 96IAECh. 3 - Prob. 97IAECh. 3 - Prob. 98IAECh. 3 - The metal M forms the sulfate M2( SO4)2. A 0.738 g...Ch. 3 - Prob. 100IAECh. 3 - Prob. 101IAECh. 3 - Prob. 102IAECh. 3 - A 1.013 g sample of ZnSO4H2O is dissolved in water...Ch. 3 - The iodide ion in a 1.552 g sample of the compound...Ch. 3 - Prob. 105IAECh. 3 - The insecticide dieldrin contains carbon, oxygen,...Ch. 3 - Prob. 107IAECh. 3 - The atomic mass of Bi is to be determined by...Ch. 3 - A piece of gold (Au) foil measuring 0.25mm15mm is...Ch. 3 - Prob. 110IAECh. 3 - Prob. 111IAECh. 3 - All-purpose fertilizers contain the essential...Ch. 3 - A hydrate of copper(II) sulfate, when heated, goes...Ch. 3 - Prob. 114FPCh. 3 - Prob. 115SAECh. 3 - Prob. 116SAECh. 3 - Prob. 117SAECh. 3 - Prob. 118SAECh. 3 - Prob. 119SAECh. 3 - Three of the following formulas might be ether an...Ch. 3 - Prob. 121SAECh. 3 - Prob. 122SAECh. 3 - Iron is present red blood and acts to carry oxygen...Ch. 3 - Prob. 124SAECh. 3 - Prob. 125SAECh. 3 - Prob. 126SAECh. 3 - Prob. 127SAECh. 3 - Prob. 128SAECh. 3 - Prob. 129SAECh. 3 - Which compound has a molar mass of...Ch. 3 - Prob. 131SAECh. 3 - Prob. 132SAECh. 3 - A hydrate of Na2SO2 contains almost exactly 50%...Ch. 3 - Malachite is a common copper-containing mineral...Ch. 3 - Prob. 135SAECh. 3 - Ibuprofen is a compound used in painkiller. When a...Ch. 3 - Prob. 137SAE
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