The given compound has to be identified as cis or trans isomer. Concept introduction: Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers. Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in ( cis ) and ( trans ) configurations know as geometric isomerism. Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to ( 109 .5 0 ) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Question

Want to see the full answer?

Answer 1

Question

Chapter 3, Problem 60P

(a)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(b)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(c)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.

(III) adsorbent (b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous solution was examined. The adsorption was modelled using a modified Langmuir isotherm, yielding the following values of Kat pH = 6.5: (ii) T/K 10-10 K 280 2.505 295 1.819 310 1.364 325 1.050 Determine the enthalpy of adsorption, AadsHⓇ. If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above conditions, determine Aads Gº.

with full details solution please

Answer 2

Question

Chapter 3, Problem 60P

(a)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(b)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(c)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 3, Problem 60P

(a)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(b)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(c)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 3, Problem 60P

(a)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(b)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(c)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 3, Problem 60P

(a)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(b)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(c)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Answer 6

Chapter 3, Problem 60P

(a)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Answer 7

Chapter 3, Problem 60P

(a)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 3.1 - Name each of the following:Ch. 3.1 - Draw the structures and name the four...Ch. 3.1 - Draw the structure for each of the following...Ch. 3.1 - Name the following compounds:Ch. 3.1 - Prob. 7P Ch. 3.2 - What is each compounds systematic name?Ch. 3.2 - Prob. 11P Ch. 3.3 - Prob. 12P Ch. 3.3 - Convert the following condensed structures into...Ch. 3.3 - The molecular formula for ethyl alcohol (CH3CH2OH)...

Solution Summary: The author explains that the given compound has to be identified as cis or trans isomer.

Concept explainers

Want to see the full answer?

Chapter 3 Solutions