Organic Chemistry
3rd Edition
ISBN: 9781119338352
Author: Klein
Publisher: WILEY
expand_more
expand_more
format_list_bulleted
Question
Chapter 3, Problem 55IP
Interpretation Introduction
Interpretation:
More acidic nature of salicylic acid than its constitutional isomers is needed to be explained.
Concept introduction:
Constitutional isomers:
- Constitutional isomers are isomers which have the same molecular formula and different bond connectivity between the atoms in the molecule.
Acidic strength of the molecule depends on the stability of the Conjugate anion.
- If the conjugate anion is more resonance stabilized, the acid considered as strong acid and the anion is weak base.
- If more sterically hindered the group, acidic nature is less. That means bulkiness decreases the acidic strength of the molecule.
To give: the explanation for the acidity of salicylic acid than para-hydroxybenzoic acid.
Expert Solution & Answer

Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Where are the chiral centers in this molecule? Also is this compound meso yes or no?
PLEASE HELP! URGENT!
Where are the chiral centers in this molecule? Also is this compound meso yes or no?
Chapter 3 Solutions
Organic Chemistry
Ch. 3.2 - Prob. 1LTSCh. 3.2 - All of the following acid-base reactions are...Ch. 3.2 - Prob. 2PTSCh. 3.2 - Prob. 3ATSCh. 3.3 - Prob. 2LTSCh. 3.3 - Prob. 4PTSCh. 3.3 - Prob. 5ATSCh. 3.3 - Prob. 6ATSCh. 3.3 - Prob. 3LTSCh. 3.3 - Prob. 7PTS
Ch. 3.3 - Prob. 8ATSCh. 3.3 - Prob. 9ATSCh. 3.3 - Prob. 4LTSCh. 3.3 - Prob. 10PTSCh. 3.3 - Prob. 11ATSCh. 3.3 - Prob. 12CCCh. 3.4 - Prob. 5LTSCh. 3.4 - Prob. 13PTSCh. 3.4 - Prob. 14ATSCh. 3.4 - Prob. 6LTSCh. 3.4 - Prob. 15PTSCh. 3.4 - Prob. 16ATSCh. 3.4 - Prob. 17ATSCh. 3.4 - Prob. 7LTSCh. 3.4 - Prob. 18PTSCh. 3.4 - Prob. 19PTSCh. 3.4 - Prob. 20ATSCh. 3.4 - Prob. 8LTSCh. 3.4 - Prob. 21PTSCh. 3.4 - Prob. 22ATSCh. 3.4 - Prob. 9LTSCh. 3.4 - Prob. 23PTSCh. 3.4 - Prob. 24PTSCh. 3.4 - Prob. 25ATSCh. 3.4 - Prob. 26ATSCh. 3.5 - Prob. 10LTSCh. 3.5 - Prob. 27PTSCh. 3.5 - The development of chemical sensors that can...Ch. 3.5 - Determine whether H2O would be a suitable reagent...Ch. 3.5 - Prob. 29PTSCh. 3.5 - Prob. 30ATSCh. 3.7 - Prob. 31CCCh. 3.9 - Prob. 12LTSCh. 3.9 - Prob. 32PTSCh. 3.9 - Prob. 33ATSCh. 3 - Prob. 34PPCh. 3 - Prob. 35PPCh. 3 - Prob. 36PPCh. 3 - Prob. 37PPCh. 3 - Prob. 38PPCh. 3 - Prob. 39PPCh. 3 - Prob. 40PPCh. 3 - Prob. 41PPCh. 3 - Prob. 42PPCh. 3 - Prob. 43PPCh. 3 - Prob. 44PPCh. 3 - Prob. 45PPCh. 3 - Prob. 46PPCh. 3 - Prob. 47PPCh. 3 - Prob. 48PPCh. 3 - Prob. 49IPCh. 3 - Prob. 50IPCh. 3 - Prob. 51IPCh. 3 - Prob. 52IPCh. 3 - Prob. 53IPCh. 3 - Prob. 54IPCh. 3 - Prob. 55IPCh. 3 - Prob. 56IPCh. 3 - Prob. 57IPCh. 3 - Prob. 58IPCh. 3 - Prob. 59IPCh. 3 - Prob. 60IPCh. 3 - Prob. 61IPCh. 3 - Prob. 62IPCh. 3 - Prob. 63IPCh. 3 - Prob. 64IPCh. 3 - The bengamides are a series of natural products...Ch. 3 - Prob. 66IPCh. 3 - Prob. 67IPCh. 3 - Prob. 68IPCh. 3 - Prob. 69IPCh. 3 - Prob. 70CPCh. 3 - Prob. 71CPCh. 3 - Prob. 72CPCh. 3 - Prob. 73CP
Knowledge Booster
Similar questions
- A mixture of C7H12O2, C9H9OCl, biphenyl and acetone was put together in a gas chromatography tube. Please decide from the GC resutls which correspond to the peak for C7,C9 and biphenyl and explain the reasoning based on GC results. Eliminate unnecessary peaks from Gas Chromatography results.arrow_forwardIs the molecule chiral, meso, or achiral? CI .CH3 H₂C CIarrow_forwardPLEASE HELP ! URGENT!arrow_forward
- Identify priority of the substituents: CH3arrow_forwardHow many chiral carbons are in the molecule? OH F CI Brarrow_forwardA mixture of three compounds Phen-A, Acet-B and Rin-C was analyzed using TLC with 1:9 ethanol: hexane as the mobile phase. The TLC plate showed three spots of R, 0.1 and 0.2 and 0.3. Which of the three compounds (Phen-A; Acet-B or Rin-C) would have the highest (Blank 1), middle (Blank 2) and lowest (Blank 3) spot respectively? 0 CH: 0 CH, 0 H.C OH H.CN OH Acet-B Rin-C phen-A A A <arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY

Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning

Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning

Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning

Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY