ORGANIC CHEMISTRY (LL)-PACKAGE
ORGANIC CHEMISTRY (LL)-PACKAGE
8th Edition
ISBN: 9781319316389
Author: VOLLHARDT
Publisher: MAC HIGHER
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Chapter 3, Problem 43P

(a)

Interpretation Introduction

Interpretation: The heat of combustion per gram needs to be determined for the mentioned hydrocarbons.

Concept Introduction: The heat of combustion is calculated generally in unit kcal/mol. To convert it into kcal/g, the value needs to be divided with the mass of substance in its 1 mol.

(b)

Interpretation Introduction

Interpretation: The same calculations as in part (a) needs to be done for ethanol.

Concept Introduction: The heat of combustion is calculated generally in unit kcal/mol. To convert it into kcal/g, the value needs to be divided with the mass of substance in its 1 mol.

(c)

Interpretation Introduction

Interpretation: Whether the fuel capability of hydrocarbon is more or less than ethanol needs to be determined.

Concept Introduction: The heat of combustion is calculated generally in unit kcal/mol. To convert it into kcal/g, the value needs to be divided with the mass of substance in its 1 mol.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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