ORGANIC CHEMISTRY II LAB MANUAL>CUSTOM<

9th Edition

ISBN: 9780534261641

Author: SIMEK

Publisher: Cengage Learning

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Alkanes and Cycloalkanes

Alkanes are saturated organic compounds which are made up of C and H atoms. Alkanes have the general formula of CnH2n+2. Alkane contains sp3 hybridized carbon atoms with four sigmas (σ) bonds & every hydrogen atom is connected with one of the carbon atom…

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Textbook Question

Chapter 3, Problem 3.45SP

a. Draw the two chair conformations of cis-1,3-dimethylcyclohexane, and label all the positions as axial or equatorial.
b. Label the higher-energy conformation and the lower-energy conformation.
c. The energy difference in these two conformations has been measured to be about 23 kJ (5.4 kcal) per mole. How much of this energy difference is due to the torsional energy of gauche relationships?
d. How much energy is due to the additional steric strain of the 1,3-diaxial interaction?

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Chapter 3, Problem 3.44SP

Chapter 3, Problem 3.46SP

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Chapter 3 Solutions

ORGANIC CHEMISTRY II LAB MANUAL>CUSTOM<

Ch. 3.2 - Using the general molecular formula for alkanes:...Ch. 3.3B - Name the following alkanes and haloalkanes. When...Ch. 3.3B - Write structures for the following compounds. a....Ch. 3.3B - Provide IUPAC names for the following compounds....Ch. 3.3B - Prob. 3.5P Ch. 3.3B - Prob. 3.6P Ch. 3.3B - Prob. 3.7P Ch. 3.3B - Draw the structures of the following compounds. a....Ch. 3.3B - Without looking at the structures, give molecular...Ch. 3.4C - Prob. 3.10P

Ch. 3.7B - Prob. 3.11P Ch. 3.7C - Draw a graph similar to Figure 3-9, of the...Ch. 3.8B - Draw a graph similar to Figure 3-11, of the...Ch. 3.9 - Draw a perspective representation of the most...Ch. 3.10C - Give IUPAC names for the following compounds.Ch. 3.10C - Draw the structure and give the molecular formula...Ch. 3.11 - Which of the following cycloalkanes are capable of...Ch. 3.11 - Give IUPAC names for the following cycloalkanes.Ch. 3.12B - The heat of combustion of...Ch. 3.12C - Prob. 3.20P Ch. 3.13B - The cyclohexane chair shown in Figure 3-22 has the...Ch. 3.13B - Draw 1,2,3,4,5,6-hexamethylcyclohexane with all...Ch. 3.14 - Prob. 3.23P Ch. 3.14 - Prob. 3.24P Ch. 3.14 - Draw the most stable conformation of a....Ch. 3.15 - Prob. 3.26P Ch. 3.15 - a. Draw both chair conformations of cis-1...Ch. 3.15 - Prob. 3.28P Ch. 3.15A - Draw the two chair conformations of each of the...Ch. 3.15B - Draw the most stable conformation of a....Ch. 3.16A - Name the following compounds.Ch. 3.16B - Prob. 3.32P Ch. 3 - Prob. 3.33SP Ch. 3 - Prob. 3.34SP Ch. 3 - 3-35 a. Draw and name the five cycloalkane...Ch. 3 - Draw the structure that corresponds with each...Ch. 3 - Each of the following descriptions applies to more...Ch. 3 - Write structures for a homologous series of...Ch. 3 - Prob. 3.39SP Ch. 3 - Construct a graph, similar to Figure 3-11, of the...Ch. 3 - The following names are all incorrect or...Ch. 3 - In each pair of compounds, which compound has the...Ch. 3 - There are eight different five-carbon alkyl...Ch. 3 - Use a Newman projection about the indicated bond...Ch. 3 - a. Draw the two chair conformations of...Ch. 3 - Draw the two chair conformations of each compound,...Ch. 3 - Using what you know about the conformational...Ch. 3 - Prob. 3.48SP Ch. 3 - Draw Newman projections along the C3C4 bond to...Ch. 3 - Prob. 3.50SP Ch. 3 - The most stable form of the common sugar glucose...Ch. 3 - This is a Newman projection of a substituted...

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