
Concept explainers
(a)
Interpretation:
An explanation regarding the arrangement of the compounds in order of their decreasing
Concept introduction:
The

Answer to Problem 3.29P
The arrangement of the given compounds in decreasing order of their
Explanation of Solution
The given compounds are shown below.
Figure 1
The acidity of an atom is directly proportional to the electronegativity of an atom. The
Compound C contains
Compound A contains sulfur atom which is less electronegative than oxygen atom but it contains a chlorine atom. Chlorine atom is electronegative in nature due to which acidity of compound A increases.
Therefore, the order of acidity of the compounds is shown below.
Figure 2
The
Therefore, the order of decreasing
Figure 3
The order of decreasing
The arrangement of the given compounds in decreasing order of their
(b)
Interpretation:
An explanation regarding the arrangement of the compounds in order of their decreasing
Concept introduction:
The

Answer to Problem 3.29P
The arrangement of the order of decreasing
Explanation of Solution
The given compounds are shown below.
Figure 4
The acidity of an atom is directly proportional to the electronegativity of an atom. Compound C contains two
Compound A contains only one
Compound B contains
Therefore, the order of acidity of the compounds is shown below.
Figure 5
The
Therefore, the order of decreasing
Figure 6
The order of decreasing
The arrangement of the order of decreasing
(c)
Interpretation:
An explanation regarding the arrangement of the compounds in order of their decreasing
Concept introduction:
The

Answer to Problem 3.29P
The arrangement of the order of decreasing
Explanation of Solution
The given compounds are shown below.
Figure 7
The conjugate bases of the compounds are shown below.
Figure 8
Compound C shown in Figure 8 is more basic than compound A and B due he presence of carboxylate ion. Compound B contains one chlorine atom which is an electron-withdrawing group. Thus, due to
The order of basicity of the compounds is shown below.
Figure 9
The order of basicity is directly proportional to the
Therefore, the order of decreasing
Figure 9
The order of decreasing
The arrangement of the order of decreasing
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Chapter 3 Solutions
Organic Chemistry
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