EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
4th Edition
ISBN: 9781119192107
Author: BULLARD
Publisher: JOHN WILEY+SONS,INC.-CONSIGNMENT
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Textbook Question
Chapter 3, Problem 3.22P
A mixture of methanol and propyl acetate contains 25.0 wt% methanol.
- Using a single dimensional equation, determine the g-moles of methanol in 200.0 kg of the mixture.
- The flow rate of propyl acetate in the mixture is to be 100.0 lb-mole/h. What must the mixture flow rate be in lbm/h?
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Thermophysical Properties of Petroleum Fractions and Crude Ofls
67
3.4. A gas oil has the following TBP distillation data
Volume %
TBP (°C)
0
216
10
243
30
268
50
284
70
304
90
318
95
327
100
334
It also has an average boiling point of 280 °C and an average density of
0.850 g/cm³.
(a) Split this gas oil fraction into five pseudo-components. Calculate T., Pc
and w for each pseudo-component.
(b) Calculate T, Pc and w for the whole gas oil fraction.
(c) Calculate the enthalpy of this gas oil fraction at 400 °C using the Lee-
Kessler correlation with a reference state of ideal gas at 273.15 K.
3.3. Use the following crude assay data with crude API of 36 to estimate cut
vol%, critical properties and molecular weight for Light Naphtha (90-
190 °F) and Kerosene (380-520 °F). In addition, calculate the fractions
of paraffins, naphthenes and aromatics in the two cuts.
ASTM D86 (°F)
Volume % Cum vol%
SG
86
0.0
0.0
122
0.5
0.5
0.6700
167
1.2
1.7
0.6750
212
1.6
3.3
0.7220
257
2.7
6.0
0.7480
302
3.1
9.1
0.7650
347
3.9
13.0
0.7780
392
4.7
17.7
0.7890
437
5.7
23.4
0.8010
482
8.0
31.4
0.8140
527
10.7
42.1
0.8250
584
5.0
47.1
0.8450
636
10.0
57.1
0.8540
689
7.8
64.9
0.8630
742
7.0
71.9
0.8640
794
6.5
78.4
0.8890
20.8
99.2
0.9310
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QUESTIONS AND PROBLEMS
4.1. With 100,000 BPD of the following crude (API = 36), estimate the
products of the atmospheric distillation column. If the atmospheric
residue of the crude is taken at 650+ F. It enters in a vacuum distilla-
tion tower to give three products: light vacuum gas oil (650-850 °F),
heavy vacuum gas oil (850-1050 °F) and vacuum residue (1050+ °F).
Calculate the mass flow rate of these products. Then calculate the
sulphur content (lb/hr) for each product.
ASTM D86 (°F) vol%
Cum vol%
SG
86
0.0
0.0
122
0.5
0.5
0.6700
167
1.2
1.7
0.6750
212
1.6
3.3
0.7220
257
2.7
6.0
0.7480
3021
3.1
9.1
0.7650
347
3.9
13.0
0.7780
392
4.7
17.7
0.7890
437
5.7
23.4
0.8010
4821
8.0
31.41
0.8140
527
10,7
42.1
0.8250
584
5.0
47.1
0.8450
6361
10,0
57.1
0.8540
689
7,8
64.9
0.8630
7421
7.0
71.9
0.8640
794
6.5
78.4
0.8890
20.8
99.2
0.9310
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Chapter 3 Solutions
EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
Ch. 3 - Perform the following estimations without using a...Ch. 3 - Prob. 3.2PCh. 3 - Prob. 3.3PCh. 3 - Prob. 3.4PCh. 3 - Prob. 3.5PCh. 3 - Prob. 3.6PCh. 3 - Prob. 3.7PCh. 3 - Prob. 3.8PCh. 3 - Prob. 3.9PCh. 3 - A rectangular block of solid carbon (graphite)...
Ch. 3 - Prob. 3.11PCh. 3 - Prob. 3.12PCh. 3 - Prob. 3.13PCh. 3 - Prob. 3.14PCh. 3 - Prob. 3.15PCh. 3 - 3.16. In April 2010, the worst oil spill ever...Ch. 3 - Prob. 3.17PCh. 3 - The following data have been obtained for the...Ch. 3 - Prob. 3.19PCh. 3 - Prob. 3.20PCh. 3 - Prob. 3.21PCh. 3 - A mixture of methanol and propyl acetate contains...Ch. 3 - The feed to an ammonia synthesis reactor contains...Ch. 3 - Prob. 3.24PCh. 3 - A mixture is 10.0 molc% methyl alcohol, 75.0 mole%...Ch. 3 - Certain solid substances, known as hydrated...Ch. 3 - Prob. 3.27PCh. 3 - Prob. 3.28PCh. 3 - Prob. 3.29PCh. 3 - Prob. 3.30PCh. 3 - Prob. 3.31PCh. 3 - Prob. 3.32PCh. 3 - Prob. 3.33PCh. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Prob. 3.36PCh. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Prob. 3.39PCh. 3 - Prob. 3.40PCh. 3 - Prob. 3.41PCh. 3 - Prob. 3.42PCh. 3 - Prob. 3.43PCh. 3 - Prob. 3.44PCh. 3 - Prob. 3.45PCh. 3 - Prob. 3.46PCh. 3 - In the movie, Willy Wonka and the Chocolate...Ch. 3 - Prob. 3.48PCh. 3 - Prob. 3.49PCh. 3 - Prob. 3.50PCh. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - Prob. 3.53PCh. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - Prob. 3.56PCh. 3 - Prob. 3.57PCh. 3 - Prob. 3.58PCh. 3 - Prob. 3.59PCh. 3 - Prob. 3.60PCh. 3 - Prob. 3.61PCh. 3 - Prob. 3.62PCh. 3 - Convert the temperatures in Parts (a) and (b) and...Ch. 3 - Prob. 3.64PCh. 3 - Prob. 3.65PCh. 3 - Prob. 3.66PCh. 3 - Prob. 3.67PCh. 3 - Prob. 3.68PCh. 3 - Prob. 3.69P
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