EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
4th Edition
ISBN: 9781119192107
Author: BULLARD
Publisher: JOHN WILEY+SONS,INC.-CONSIGNMENT
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Chapter 3, Problem 3.16P

Chapter 3, Problem 3.16P, 3.16. In April 2010, the worst oil spill ever recorded occurred when an explosion and tire on the

3.16. In April 2010, the worst oil spill ever recorded occurred when an explosion and tire on the Deepwater

Horizon offshore oil-drilling rig left 11 workers dead and began releasing oil into the Gulf of Mexico. One of the attempts to contain the spill involved pumping drilling mud into the well to balance the pressure of escaping oil against a column of fluid (the mud) having a density significantly higher than those of seawater and oil. In the following problems, you may assume that seawater has a specific gravity of 1.03 and that the subsea wellhead was 5053 ft below the surface of the Gulf.

  1. Estimate the gauge pressure (psig) in the Gulf at a depth of 5053 ft.
  2. Measurements indicate that the pressure inside the wellhead is 4400 psig. Suppose a pipe between the surface of the Gulf and the wellhead is filled with drilling mud and balances that pressure. Estimate the specific gravity of the drilling mud.
  3. The drilling mud is a stable slurry of seawater and barite (SG = 4.37). What is the mass fraction of barite in the slurry?
  4. What would you expect to happen if the barite weight fraction were significantly less than that estimated in Part (c)? Explain your reasoning.

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#2 The isothermal gas-phase degradation reaction is given below. Pure ethane enters a flow reactor at 6 atm and 1100 K, with the pressure drop can be negligible. This reaction follows an elementary rate law. C2H6 → C2H4 + H2 a) Express the concentration of each species solely as a function of conversion. b) Write the reaction rate (the unit is mol/L-s) solely as a function of conversion (*rate constant k will be used in this mathematical expression). What is the unit of k. c) If this reaction is carried out in a constant volume batch reactor now, how to express the concentration of each species solely as a function of conversion?
#1 For the following liquid phase reaction, ethylene oxide reacts with water to form ethylene glycol in a CSTR. The entering concentrations of ethylene oxide and water are 16.13 mol/L and 55.5 mol/L, respectively. The reaction rate constant k = 0.1 L/mol·s at 300 K. This reaction follows an elementary rate law. Taking ethylene oxide as the limiting species (i.e., basis of the calculation). ན CH₂-OH | H2SO4 CH2-CH₂+H₂O CH₂-OH a) Express the concentration of each species solely as a function of conversion. b) Write the reaction rate solely as a function of conversion at 300 K.
#4 The gas phase reaction, as given below is carried out isothermally in a PFR with no pressure drop. The feed is equal molar in A and B, and the entering concentration of A is 0.1 mol/L. 2A + B → C a) What is the entering concentration of B? b) What are the concentrations of A, B, and C at 25% conversion of A? c) If at a particular conversion, the rate of formation of C is 2 mol/L-min, what is the rate of consumption of A at the same conversion?

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EBK ELEMENTARY PRINCIPLES OF CHEMICAL P

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