Physical Chemistry
2nd Edition
ISBN: 9781285969770
Author: Ball
Publisher: Cengage
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Textbook Question
Chapter 3, Problem 3.16E
What is the entropy change for the melting of
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In the video, we looked at the absorbance of a certain substance and how it varies
depending on what wavelength of light we are looking at. Below is a similar scan of a
different substance. What color BEST describes how this substance will appear?
Absorbance (AU)
Violet
Blue
Green
Orange
1.2
1.0-
0.8-
0.6-
0.4-
0.2
0.0
450
500
550
600
650
700
Wavelength (nm)
violet
indigo
blue
green
yellow orange
red
Red
O Cannot tell from this information
In the above graph, what causes -450 nm wavelength of light to have a higher
absorbance than light with a -550 nm wavelength? Check all that are true.
The distance the light travels is different
The different data points are for different substances
The concentration is different at different times in the experiment
Epsilon (molar absortivity) is different at different wavelengths
5. a. Data were collected for Trial 1 to determine the molar mass of a nonvolatile solid solute when dissolved in cyclo-
hexane. Complete the table for the analysis (See Report Sheet). Record calculated values with the correct number
of significant figures.
B. Freezing Point of Cyclohexane plus
Calculation Zone
Unknown Solute
2. Mass of cyclohexane (g)
10.14
Part C.4
3. Mass of added solute (g)
0.255
C. Calculations
1. k; for cyclohexane (°C⚫ kg/mol)
20.0
2. Freezing point change, AT, (°C)
3.04
Part C.6
3. Mass of cyclohexane in solution (kg)
4. Moles of solute, total (mol)
Show calculation.
5. Mass of solute in solution, total (g)
6. Molar mass of solute (g/mol)
Show calculation.
Chapter 3 Solutions
Physical Chemistry
Ch. 3 - Decide whether the following processes will be...Ch. 3 - Try to find one additional example of a...Ch. 3 - Consider the following quantities for a...Ch. 3 - Consider the following quantities for a four-step...Ch. 3 - What is the temperature of the low-temperature...Ch. 3 - What is the temperature of the high - temperature...Ch. 3 - Prob. 3.7ECh. 3 - Explain why the high-temperature reservoir of a...Ch. 3 - Superheated steam is steam with a temperature...Ch. 3 - Prob. 3.10E
Ch. 3 - The Carnot cycle is defined as having a certain...Ch. 3 - In thermodynamics, the pathway in a...Ch. 3 - A refrigerator is the reverse of an engine: Work...Ch. 3 - Efficiency is given by equations 3.5, 3.6, and...Ch. 3 - What is the entropy change for an ideal Carnot...Ch. 3 - What is the entropy change for the melting of...Ch. 3 - What is the entropy change for the solidification...Ch. 3 - Explain why the statement No process is 100...Ch. 3 - What is the change in entropy of 1.00mole of water...Ch. 3 - Prob. 3.20ECh. 3 - One mole of He warms up irreversibly at constant...Ch. 3 - Consider a monatomic ideal gas in a piston...Ch. 3 - A 0.500-mol sample of an ideal gas has an initial...Ch. 3 - SO2 in a piston chamber kept in a...Ch. 3 - A normal breath has a volume of about 1L. The...Ch. 3 - An automobile tire contains 15.6L of air at...Ch. 3 - An automobile tire contains 15.6L of air at...Ch. 3 - A sample of ideal gas from a compressed gas...Ch. 3 - Prob. 3.29ECh. 3 - In Example 3.5, a heat capacity of 20.78J/molK was...Ch. 3 - Prob. 3.31ECh. 3 - 4.00L of Ar and 2.50L of He, each at 298K and...Ch. 3 - Dentists might use a mixture of 40N2O and 60O2 as...Ch. 3 - A 5.33-g piece of Cu metal is heated to 99.7C in...Ch. 3 - A sample of 1.00mol of silver at 150C is placed in...Ch. 3 - Prob. 3.36ECh. 3 - What is the change in entropy when 2.22mol of...Ch. 3 - Estimate the entropy change of an 800-lb engine...Ch. 3 - Calculate the molar entropy change of the gas that...Ch. 3 - A normal breath is about 1L in volume. Assume you...Ch. 3 - The first law of thermodynamics is sometimes...Ch. 3 - Troutons rule states that the entropy of boiling...Ch. 3 - Prob. 3.43ECh. 3 - Argue from Boltzmanns definition for entropy that...Ch. 3 - Prob. 3.45ECh. 3 - Which system has the higher entropy? a A clean...Ch. 3 - Which system has the higher entropy? a 1g of solid...Ch. 3 - The absolute entropy of He at 298.15K is...Ch. 3 - The absolute entropy of Kr at 298.15K is...Ch. 3 - The element helium is thought to remain a liquid...Ch. 3 - Order the following substances in order of...Ch. 3 - The molar entropy change for a process is...Ch. 3 - What is the entropy change of a process if ...Ch. 3 - One mole of ideal gas expands isothermally and...Ch. 3 - Why isnt the entropy of elements in their standard...Ch. 3 - Determine the entropy of formation, fS, of the...Ch. 3 - The thermite reaction has solid aluminum powder...Ch. 3 - Prob. 3.58ECh. 3 - Determine the differences in the rxnS under...Ch. 3 - Calcium carbonate has two crystalline forms,...Ch. 3 - The chemical formula for gasoline can be...Ch. 3 - Prob. 3.62ECh. 3 - Prob. 3.63ECh. 3 - Plants take in CO2(g) and H2O(l) and make glucose,...Ch. 3 - Prob. 3.65ECh. 3 - Prob. 3.66ECh. 3 - Plots of Cp/T versus T are used to determine the...
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