Which system has the higher entropy? (a) 1 g of solid Au at 1064 K or 1 g of liquid Au at 1064 K ? (b) 1 mole of CO at STP or 1 mole of CO 2 at STP? (c) 1 mole of Ar at a pressure of 1 atm or 1 mole of Ar at a pressure of 0 .01 atm ?
Which system has the higher entropy? (a) 1 g of solid Au at 1064 K or 1 g of liquid Au at 1064 K ? (b) 1 mole of CO at STP or 1 mole of CO 2 at STP? (c) 1 mole of Ar at a pressure of 1 atm or 1 mole of Ar at a pressure of 0 .01 atm ?
Solution Summary: The author explains that the randomness present in the system is called its entropy, which is an extensive property.
Which system has the higher entropy? (a)
1
g
of solid
Au
at
1064
K
or
1
g
of liquid
Au
at
1064
K
? (b)
1
mole of
CO
at STP or
1
mole of
CO
2
at STP? (c)
1
mole of
Ar
at a pressure of
1
atm
or
1
mole of
Ar
at a pressure of
0
.01
atm
?
a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression:
AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T
A. Calculate the value of AS for the process.
B. Next, use the Gibbs-Helmholtz equation:
(a(AG/T))
ΔΗ
-
T2
to calculate the value of AH for the process.
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