ELEMENTS OF CHEM. REACTION ENGR
5th Edition
ISBN: 9780135486498
Author: Fogler
Publisher: INTER PEAR
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 3, Problem 3.15P
Solar Chemical Energy Storage. The major ways to utilize, capture, or store the sun’s energy are solar thermal (see P8-16B), solar voltaic, biomass conversion, solar water splitting (P10-13B), and solar chemical. Solar chemical refers to processes that harness and store solar energy by adsorbing light in a reversible chemical reaction; see http://en.wikipedia.org/wiki/Solar_chemical. For example, the photodimerization of anthracene absorbs and stores solar energy that can be released when the reverse reaction takes place.
Figure P3-15.1 Anthracene dimerization.
Another reaction of interest is the Norbornadiene–Quadricyclane (NQ) couple, where solar energy is adsorbed and stored in one direction and released in the other.
Figure P3-15.2 The Norbornadiene–Quadricyclane (NQ) couple is of potential interest for sunlight energy storage.
- (a) Suggest a rate law for the reversible photodimerization of anthracene.
- (b) Suggest a rate law for the reversible storage of energy by the NQ couple.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Problem 1
Marks: 60
Section: 1a): 30 marks, Section 1b):30 marks
A laboratory scale fluidized bed is considered for studying a catalytic ozone decomposition.
a) It is requested to derive model equations under the following assumptions:
■ Operation of the catalytic reactor under steady state conditions,
There is no influence of thermal ozone decomposition reactions.
The fluidized bed includes bubbles and dense phase.
□ The dense phase can be simulated using a CSTR
The fluidized bed bubbles contain catalyst particles and can be simulated as a DSTR (batch).
□ The jets contain particles and can be simulated with a PFR.
The influence of the freeboard has to be considered using a PFR model.
The available catalytic reaction rate model is r (moles/gcat.s)= -k CA
b) Same than on a) under unsteady state conditions, using an absorbable and reactive tracer.
Note: A step-by step derivation of the model equations is required here. A quick answer will not do.
Problem 2 Marks: 40
Section 2a: 30 marks,…
Penicillin process
Penicillium chrysogenum is used to produce penicillin in a 90,000-litre fermenter. The volumetric rate of oxygen uptake by the cells ranges from 0.45 to 0.85 mmol l^−1 min^−1 depending on time during the culture. Power input by stirring is 2.9 W l^−1. Estimate the cooling requirements.
Production of bakers’ yeast
Bakers’ yeast is produced in a 50,000-litre fermenter under aerobic conditions. The carbon substrate is sucrose; ammonia is provided as the nitrogen source. The average biomass composition is CH_1.83O_0.55N_0.17 with 5% ash. Under conditions supporting efficient growth, biomass is the only major product and the biomass yield from sucrose is 0.5 g g^−1. If the specific growth rate is 0.45 h^−1, estimate the rate of heat removal required to maintain constant temperature in the fermenter when the yeast concentration is 10 g l^−1.
Chapter 3 Solutions
ELEMENTS OF CHEM. REACTION ENGR
Ch. 3 - (a) Example 3-1. Make a plot of k versus T and ln...Ch. 3 - Prob. 3.2PCh. 3 - Use Equation (3-20) to make a plot of f(E,T) as a...Ch. 3 - Prob. 3.5PCh. 3 - Prob. 3.7PCh. 3 - Inspector Sgt. Ambercromby of Scotland Yard. It is...Ch. 3 - Prob. 3.9PCh. 3 - Prob. 3.10PCh. 3 - Determine the rate law for the reaction described...Ch. 3 - (a)Write the rate law for the following reactions...
Additional Engineering Textbook Solutions
Find more solutions based on key concepts
The following C++ program will not compile because the lines have been mixed up. cout Success\n; cout Success...
Starting Out with C++ from Control Structures to Objects (9th Edition)
How is the hydrodynamic entry length defined for flow in a pipe? Is the entry length longer in laminar or turbu...
Fluid Mechanics: Fundamentals and Applications
Why is the study of database technology important?
Database Concepts (8th Edition)
Assume a telephone signal travels through a cable at two-thirds the speed of light. How long does it take the s...
Electric Circuits. (11th Edition)
17–1C A high-speed aircraft is cruising in still air. How does the temperature of air at the nose of the aircra...
Thermodynamics: An Engineering Approach
The solid steel shaft AC has a diameter of 25 mm and is supported by smooth bearings at D and E. It is coupled ...
Mechanics of Materials (10th Edition)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemical-engineering and related others by exploring similar questions and additional content below.Similar questions
- Sensible energy change Calculate the enthalpy change associated with the following processes:(a) m-Cresol is heated from 25°C to 100°C(b) Ethylene glycol is cooled from 20°C to 10°C(c) Succinic acid is heated from 15°C to 120°C(d) Air is cooled from 150°C to 65°Carrow_forward▼ Enzyme conversion An immobilised enzyme process is used in an ice-cream factory to hydrolyse lactose (C12H22O11) to glucose (C6H12O6) and galactose (C6H1206): C12H22O11 + H2O →→ C6H12O + C6H12O6 Gel beads containing ß-galactosidase are packed into a column reactor; 2500 kg of lactose enters the reactor per day as a 10% solution in water at 25°C. The reactor operates at steady state and 32°C; all of the lactose is converted. Because the heat of reaction for enzyme conversions is not as great as for cell culture, sensible heat changes and heats of mixing cannot be ignored. Lactose Water Ah (kJ gmol¹) C, (cal g¹ ºC-¹) Ahm (kcal gmol¹) 3.7 -5652.5 0.30 1.0 Glucose -2805.0 0.30 5.6 Galactose -2805.7 0.30 5.6 (a) What is the standard heat of reaction for this enzyme conversion? (b) Estimate the heating or cooling requirements for this process. State explicitly whether heating or cooling is needed.arrow_forwardBacterial production of alginate Azotobacter vinelandii is investigated for production of alginate from sucrose. In a continuous fermenter at 28°C with ammonia as nitrogen source, the yield of alginate was found to be 4 g g^−1 oxygen consumed. It is planned to produce alginate at a rate of 5 kg h^−1. Since the viscosity of alginate in aqueous solution is considerable, energy input due to mixing the broth cannot be neglected. The fermenter is equipped with a flat-blade disc turbine; at a satisfactory mixing speed and air flow rate, the power requirements are estimated at 1.5 kW. Calculate the cooling requirements.arrow_forward
- Preheating nutrient medium Steam is used to heat nutrient medium in a continuous-flow process. Saturated steam at 150°C enters a coil on the outside of the heating vessel and is completely condensed. Liquid medium enters the vessel at 15°C and leaves at 44°C. Heat losses from the jacket to the surroundings are estimated as 0.22 kW. If the flow rate of medium is 3250 kg h^−1 and its heat capacity is 0.9 cal g^−1 °C^−1, how much steam is required?arrow_forwardQ3] Determine the optimal operating conditions (XA, t, and CR) in a mixed flow reactor to maximize the concentration of R (CR) in the effluent, where an aqueous feed A with an initial concentration of CA0-40 mol/m³ enters the reactor, undergoes decomposition, and exits as a mixture containing A, R, and S. K₁ AR, FR = k₁C, k₁ = 0.4 m³/(mol min) SA AS, rs = k₂CA, k₂ = 2(min), CA0 = 40 mol/m³arrow_forwardConsider the parallel decomposition of A of different orders with FR = 1, rs = 2CA and IT = C. Determine the maximum concentration of desired product obtainable in mixed flow reactor and plug flow reactor. (1) R is desired product and CA0 = 2. (2) S is desired product and CA0 = 4. R S Tarrow_forward
- 1. Copper is known to be toxic to fish, and in particular, the free ion Cu²+ species typically shows greatest toxicity. a. Calculate the speciation of Cu(II) for freshwater at a pH value of 8.3 as the hardness increases from 20 (soft) to 100 (moderately hard) to 200 (very hard) mg/L as CaCO3. Assume that the total divalent Cu(II) concentration is 10 µg/L. b. Based on your findings in part (a), do you think it is appropriate to set a single regulatory limit or should it depend on variables such as pH and hardness? Explain your answer.arrow_forwardMaterial Sciencearrow_forwardElectronic devices found in integrated circuits are composed of very high purity silicon to which has been added small and very controlled concentrations of elements found in Groups IIIA and VA of the periodic table. For Si that has had added 9.1 × 1021 atoms per cubic meter of antimony compute (a) the weight percent and (b) the atom percent of Sb present. (Hint: use Equation 100 C₁ = 1 + NAP2 N1A₁ P2 P1 (a) 0.00636 %wt (b) i 0.0182 %atarrow_forward
- Use the binary diagram, 45 line above and material balance to solve the One thousand kg/h of a (50-50 wt%) acetone-in-water solution is to be extracted at 25C in a continuous, countercurrent system with pure 1,1,2-trichloroethane to obtain a raffinate containing 10 wt% acetone. Using the following equilibrium data, determine with an equilateral-triangle diagram: a the minimum flow rate of solvent; b. the number of stages required for a solvent rate equal to 1.5 times minimum, and composition of each streamleaving each stage. Repeat the calculation of (a) and (b) if the solvent used has purity 93wt% (4wr% acetone, 3wt% water impurities) acetone 0.6 water 0.13 1,1,2-trichloroethane 0.27 Raffinate. Weight Fraction Acetone Extract. Weight Fraction Acetone 0.5 0.04 0.46 0.44 0.56 0.4 0.03 0.57 0.29 0.40 0.3 0.02 0.681 0.12 0.18 0.2 0.015 0.785 0.0 0.0 0.1 0.01 0.89 0.55 0.35 0.1 0.5 0.43 0.07 0.4 0.57 0.03 0.3 0.68 0.02 0.2 0.79 0.01 0.1 0.895 0.005arrow_forwardMaterial Sciencearrow_forwardMaterial Sciencearrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami...Chemical EngineeringISBN:9781259696527Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark SwihartPublisher:McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind...Chemical EngineeringISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Elements of Chemical Reaction Engineering (5th Ed...Chemical EngineeringISBN:9780133887518Author:H. Scott FoglerPublisher:Prentice Hall
Industrial Plastics: Theory and ApplicationsChemical EngineeringISBN:9781285061238Author:Lokensgard, ErikPublisher:Delmar Cengage Learning
Unit Operations of Chemical EngineeringChemical EngineeringISBN:9780072848236Author:Warren McCabe, Julian C. Smith, Peter HarriottPublisher:McGraw-Hill Companies, The
Introduction to Chemical Engineering Thermodynami...
Chemical Engineering
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind...
Chemical Engineering
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY
Elements of Chemical Reaction Engineering (5th Ed...
Chemical Engineering
ISBN:9780133887518
Author:H. Scott Fogler
Publisher:Prentice Hall
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:9781285061238
Author:Lokensgard, Erik
Publisher:Delmar Cengage Learning
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:9780072848236
Author:Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:McGraw-Hill Companies, The
Kinetics: Initial Rates and Integrated Rate Laws; Author: Professor Dave Explains;https://www.youtube.com/watch?v=wYqQCojggyM;License: Standard YouTube License, CC-BY