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Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
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Textbook Question
Chapter 3, Problem 3.11P
Explain the trends in bond angles and bond lengths of the following ions:
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Arrange the following in decreasing order of bond length and bond angle with explanation C2H6, C2H4, C2H2
The VSEPR model was developed before any xenon com-pounds had been prepared. Thus, these compounds provided anexcellent test of the model’s predictive power. What would youhave predicted for the shapes of XeF₂, XeF₄, and XeF₆?
Chapter 3 Solutions
Inorganic Chemistry
Ch. 3.1 - Use electron-dot diagrams and formal charges to...Ch. 3.2 - Predict the structures of the following ions....Ch. 3.2 - Prob. 3.3ECh. 3.2 - Which molecule has the smallest bond angle in each...Ch. 3.2 - Briefly account for the following observations: a....Ch. 3.2 - Does this approach work for different steric...Ch. 3 - The dimethyldithiocarbamate ion, [S2CN( CH 3 )2]-...Ch. 3 - Several resonance structures are possible for each...Ch. 3 - Draw the resonance structures for the...Ch. 3 - Three isomers having the formula N2CO are known:...
Ch. 3 - Show the possible resonance structures for nitrous...Ch. 3 - Nitric acid, which exists as HNO3 molecules in the...Ch. 3 - L. C. Allen has suggested that a more meaningful...Ch. 3 - Give Lewis dot structures and sketch the shapes of...Ch. 3 - Give Lewis dot structures and sketch the shapes of...Ch. 3 - Give Lewis dot structures and sketch the shapes of...Ch. 3 - Explain the trends in bond angles and bond lengths...Ch. 3 - Select from each set the molecule or ¡on having...Ch. 3 - a. Compare the structures of the azide ion, N3 ,...Ch. 3 - Consider the series OCl2,O( CH3)2 , and O( SiH3)2...Ch. 3 - Two ions isoelectronic with carbon suboxide, C3O2...Ch. 3 - Explain the following: a. Ethylene, C2H4 , is a...Ch. 3 - Explain the following: a. PCI5 is a stable...Ch. 3 - X-ray crystal structures of ClOF3 and BrOF3 have...Ch. 3 - Make the following comparisons about the molecules...Ch. 3 - Prob. 3.20PCh. 3 - A solution containing the lO2F2 ion reacts slowly...Ch. 3 - The XeOF3 anion has been reported recently (D. S....Ch. 3 - Predict the structure of l(CF3)Cl2 . Do you expect...Ch. 3 - a. Which has the longer axial PF distance, PF2(...Ch. 3 - Prob. 3.25PCh. 3 - SeCl62,TeCl62 , and CIF6 are all octahedral, but...Ch. 3 - Prob. 3.27PCh. 3 - The thiazyldichloride ion, NSCl2- , is...Ch. 3 - Sketch the most likely structure of PCl3Br2 and...Ch. 3 - a. Are the CF3 groups in PCl3( CF3)2 more likely...Ch. 3 - Of the molecules C1SO2CH3,C1SO2CF3 , and ClSO2CCl3...Ch. 3 - Prob. 3.32PCh. 3 - Prob. 3.33PCh. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Although the CF distances and the FCF bond angles...Ch. 3 - The Cl...Cl distance in CCl4 is 289 pm, and the...Ch. 3 - The FCF angle in F2CO , shown here, is 109.5°; the...Ch. 3 - Compounds in which hydrogen is the outer atom can...Ch. 3 - For each of the following bonds, indicate which...Ch. 3 - Give Lewis dot structures and shapes for the...Ch. 3 - Give Lewis dot structures and sketch the shapes...Ch. 3 - Which of the molecules in Problem 3.41 are polar?Ch. 3 - Which of the molecules in Problem 3.42 are polar?Ch. 3 - Prob. 3.45PCh. 3 - Prob. 3.46P
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- In each of the following molecules, a central atom is surrounded by a total of three atoms or unshared electron pairs: SnCl2, BCl3, SO2. In which of these molecules would you expect the bond angle to be less than 120? Explain your reasoning.arrow_forward• identify sigma and pi bonds in a molecule and explain the difference between them.arrow_forwardYour assigneed ion is : AlCl4- please give a brief description that includes: (f) actual bond angles (may use > or< symbols where appropriate). Please note that your individual assignment may be for an ion (don't forget about charges) or a neutral atom.arrow_forward
- What would you expect to be the electron-group arrangement around atom A in the following case? Give the ideal bond angle. Y X A- -X Electron-group arrangement: trigonal planar trigonal bipyramidal square planar Ideal bond angle:arrow_forwardNitrogen is capable of forming single, double, or triple bonds, and the figure that follows shows the potential energy as a function of internuclear distance for each of these types of bonds. Match the three curves in the figure (A, B and C) to the three types of bonds. Explain your reasoning.arrow_forwardUsing hybridization and the long method for determining the Lewis Structures, show the most feasible representation of the following compounds: AsCl4+ OClF4- (Cl is the central atom) O3BrF (Br is the central atom)arrow_forward
- Consider the Lewis Structure for the molecule, SeF4. On your own, make a sketch of the VSEPR shape, and use that to answer the following questions: :F: F-Se-F: :F: Part A What is the electronic geometry of this molecule? O trigonal bipyramidal O t-shaped O trigonal pyramidal O tetrahedral O square planar see-saw O octahedral O O Oarrow_forwardWrite the Lewis structure for each molecule or ion. Include resonance structures ifnecessary. Then assign the electron geometry, molecular geometry, and bond angles CN-arrow_forwardWhich theory have been given to explain shapes of the molecules. On the basis of its various postulates explain: (i) From the given examples of SF4, BF4', XeF4, IC14', the number of species having two lone pairs of electrons (ii) The bond distances and angles in SO2C12 and S2C12arrow_forward
- The SeF6 molecule displays which bond angles (in degrees)about the central Se? VSEPR theory predicts which molecular structure (arrangement of bonded atoms about the central Se atom) for SeF6?arrow_forward“Inert” xenon actually forms several compounds, especially with the highly electronegative elements oxygen and fluorine. The simple fluorides XeF2, XeF4, and XeF6 are all formed by direct reaction of the elements. As you might expect from the size of the xenon atom, the Xe¬F bond is not a strong one. Calculate the Xe¬F bond energy in XeF6, given that the enthalpy of formation is -402 kJ/mol.arrow_forwardEstimate the percent ionic character of the bond in cach of the following diatomic molecules, based on the dipole moment. Bond Length (À) Dipole Moment (D) CIO 1.573 1.239 KI 3.051 10.82 TICI 2.488 4.543 Incl 2.404 3.79arrow_forward
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