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Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
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Textbook Question
Chapter 3, Problem 3.44P
Which of the molecules in Problem 3.42 are polar?
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Chapter 3 Solutions
Inorganic Chemistry
Ch. 3.1 - Use electron-dot diagrams and formal charges to...Ch. 3.2 - Predict the structures of the following ions....Ch. 3.2 - Prob. 3.3ECh. 3.2 - Which molecule has the smallest bond angle in each...Ch. 3.2 - Briefly account for the following observations: a....Ch. 3.2 - Does this approach work for different steric...Ch. 3 - The dimethyldithiocarbamate ion, [S2CN( CH 3 )2]-...Ch. 3 - Several resonance structures are possible for each...Ch. 3 - Draw the resonance structures for the...Ch. 3 - Three isomers having the formula N2CO are known:...
Ch. 3 - Show the possible resonance structures for nitrous...Ch. 3 - Nitric acid, which exists as HNO3 molecules in the...Ch. 3 - L. C. Allen has suggested that a more meaningful...Ch. 3 - Give Lewis dot structures and sketch the shapes of...Ch. 3 - Give Lewis dot structures and sketch the shapes of...Ch. 3 - Give Lewis dot structures and sketch the shapes of...Ch. 3 - Explain the trends in bond angles and bond lengths...Ch. 3 - Select from each set the molecule or ¡on having...Ch. 3 - a. Compare the structures of the azide ion, N3 ,...Ch. 3 - Consider the series OCl2,O( CH3)2 , and O( SiH3)2...Ch. 3 - Two ions isoelectronic with carbon suboxide, C3O2...Ch. 3 - Explain the following: a. Ethylene, C2H4 , is a...Ch. 3 - Explain the following: a. PCI5 is a stable...Ch. 3 - X-ray crystal structures of ClOF3 and BrOF3 have...Ch. 3 - Make the following comparisons about the molecules...Ch. 3 - Prob. 3.20PCh. 3 - A solution containing the lO2F2 ion reacts slowly...Ch. 3 - The XeOF3 anion has been reported recently (D. S....Ch. 3 - Predict the structure of l(CF3)Cl2 . Do you expect...Ch. 3 - a. Which has the longer axial PF distance, PF2(...Ch. 3 - Prob. 3.25PCh. 3 - SeCl62,TeCl62 , and CIF6 are all octahedral, but...Ch. 3 - Prob. 3.27PCh. 3 - The thiazyldichloride ion, NSCl2- , is...Ch. 3 - Sketch the most likely structure of PCl3Br2 and...Ch. 3 - a. Are the CF3 groups in PCl3( CF3)2 more likely...Ch. 3 - Of the molecules C1SO2CH3,C1SO2CF3 , and ClSO2CCl3...Ch. 3 - Prob. 3.32PCh. 3 - Prob. 3.33PCh. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Although the CF distances and the FCF bond angles...Ch. 3 - The Cl...Cl distance in CCl4 is 289 pm, and the...Ch. 3 - The FCF angle in F2CO , shown here, is 109.5°; the...Ch. 3 - Compounds in which hydrogen is the outer atom can...Ch. 3 - For each of the following bonds, indicate which...Ch. 3 - Give Lewis dot structures and shapes for the...Ch. 3 - Give Lewis dot structures and sketch the shapes...Ch. 3 - Which of the molecules in Problem 3.41 are polar?Ch. 3 - Which of the molecules in Problem 3.42 are polar?Ch. 3 - Prob. 3.45PCh. 3 - Prob. 3.46P
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- Determine whether the following molecules are polar or nonpolar (i) CO2 (ii) NH3arrow_forward1. For each molecular geometry, give the number of total electron pairs, the number of bonding pairs and the number of lone pairs on the central atom. (a) (b) (c) 2. For the following species provide the Lewis structure and make a 3D sketch showing estimated bond angles. Determine the polarity of each molecular and draw the dipole. a) SF4 b) KrF4 3. Determine the 3D structure of the molecule of formula C2H4O (H3CCHO). Indicate the geometry around each "central" atom and estimate bond angles. Representing Molecular Geometries on Paper X-A-X XX Linear Trigonal planar Bent Tetrahedral Trigonal pyramidal Trigonal bipyramidal Seesaw Octahedral Square planararrow_forward10arrow_forward
- Which of the following is a polar molecule? (A) All of them are (B) SO2 (C) PCl3 (D) CH3Cl (E) O3arrow_forwardThe molecules CH4 and CH3Cl both have tetrahedral shapes. Why is CH4 nonpolar whereas CH3Cl is polar?arrow_forwardWhy is NH3 a polar molecule but BCl3 is not? Explain your answerarrow_forward
- V. Place the following molecules in order of increasing CN bond strength: HCN, NHCH2, NHCH3arrow_forwardIf the dipole moment of CH3F is 1.847 D and the dipole moment of CD3F is 1.858 D, which is more electronegative: hydrogen or deuterium?arrow_forwardQ3. Ammonia reacts with aluminium chloride as shown by the equation: NH3 + AICI3 → H3NAICI3 (a) Draw diagrams to illustrate the shapes of NH3 molecules and of AICI3 molecules. Page 4 of 12 Include in your diagrams any lone pairs of electrons that influence the shape. Indicate the values of the bond angles. (b) Name the type of bond formed between N and Al in H3NAICI3 and explain how this bond is formed. Type of bond Explanation (c) Explain how the value of the CI-AI-CI bond angle in AICI3 changes, if at all, on formation of the compound H3NAICI3arrow_forward
- 3 (a) Explain why BrF4 is square planar, whereas BF is tetrahe dral. (b) How would you expect the H-X-H bond angle to vary in the series H20, H2S, H2SE? Explain. (Hint: The size of an electron pair domain depends in part on the electronega- tivity of the central atom.) (30arrow_forward10. Each ball-and-stick model below shows the electron-pair and molecular geometry of a generic molecule. Explain what is wrong with each molecular geometry and provide the correct molecular geometry based on the number of lone and bonding pairs around the central atom. (a) (b) (c) 11. Draw the Lewis structure for acetamide (CH3CONH2) and determine the geometry about each interior atom. Experiments show that the geometry about the N atom in acetamide is nearly planar. Draw a resonance structure that can account for the planar geometry about the N atom.arrow_forward84. Predict the electron pair geometry and the molecular structure of each of the following ions: (a) H3O+ (b) PCl4− (c) SnCl3− (d) BrCl4− (e) ICl3 (f) XeF4 (g) SF2arrow_forward
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