Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
15th Edition
ISBN: 9781269935678
Author: Nivaldo J. Tro
Publisher: Pearson Education
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Chapter 3, Problem 25E
What is a
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Propose syntheses of the following compounds starting with benzene or toluene. Assume ortho and
isomers can be separated.
a.
b.
O₂N-
Cl
COOH
para
0. Propose syntheses to carry out each of the following conversions. Assume ortho and para isomers can
be separated
a.
Br
b.
COOH
CH3
NH₂
PABA
(active ingredient in some sunscreens)
H3C
H
C=C
CH3
H
m-chloroperoxybenzoic acid
CH2Cl2, rt
C-C--.
H3CH2CC
H
H3C CH3
Cl₂
H₂O
NaOH
H₂O
D.
S-
E.
CH3
H₂O₂, H₂O
It
CH₂O Na
+
CHI
F.
HI, H₂O
heat
G.
4
OH
CH3CHCH3 + ICH2CH3
1. NaH
(CH3)3COH
(CH3)3 COCHCH2CH3
2.
CH3
5. Show how the ether below could be prepared from toluene and any other necessary reagents. Show all
reagents and all intermediate structures.
H3C-
H3C-
CI
OCH2CH3
Chapter 3 Solutions
Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
Ch. 3 - Which wavelength of light has the highest...Ch. 3 - Which kind of electromagnetic radiation contains...Ch. 3 - How much energy (in J ) is contained in 1.00 mole...Ch. 3 - Light from three different lasers (A, B, and C),...Ch. 3 - Calculate the wavelength of an electron traveling...Ch. 3 - Which set of three quantum numbers does not...Ch. 3 - Calculate the wavelength of light emitted when an...Ch. 3 - Which electron transition produces light of the...Ch. 3 - How much time (in seconds) does it take light to...Ch. 3 - Which figure represents a d orbital? None of the...
Ch. 3 - Why is the quantum-mechanical model of the atom...Ch. 3 - What is light? How fast does it travel in a...Ch. 3 - Define the wavelength and amplitude of a wave.Ch. 3 - Define the frequency of electromagnetic radiation....Ch. 3 - What determines the color of light? Describe the...Ch. 3 - What determines the color of a colored object?...Ch. 3 - Give an approximate range of wavelengths for each...Ch. 3 - Explain the wave behavior known as interference....Ch. 3 - Explain the wave behavior known as diffraction....Ch. 3 - Describe the photoelectric effect. How did...Ch. 3 - How did the photoelectric effect lead Einstein to...Ch. 3 - What is a photon? How is the energy of a photon...Ch. 3 - What is an emission spectrum? How does an emission...Ch. 3 - Describe the Bohr model for the atom. How did the...Ch. 3 - Explain electron diffraction.Ch. 3 - What is the de Broglie wavelength of an electron?...Ch. 3 - What are complementary properties? How does...Ch. 3 - Explain Heisenberg’s uncertainty principle. What...Ch. 3 - What is a trajectory? What kind of information do...Ch. 3 - Why does the uncertainty principle make it...Ch. 3 - Newton’s laws of motion are deterministic. Explain...Ch. 3 - An electron behaves in ways that are at least...Ch. 3 - What is a probability distribution map?Ch. 3 - For each solution to the Schrödinger equation,...Ch. 3 - What is a quantum-mechanical orbital?Ch. 3 - What is the Schrödinger equation? What is a wave...Ch. 3 - What are the possible values of the principal...Ch. 3 - What are the possible values of the angular...Ch. 3 - What are the possible values of the magnetic...Ch. 3 - Explain the difference between a plot showing the...Ch. 3 - Sketch the general shapes of the s, p, and d...Ch. 3 - List the four different sublevels. Given that only...Ch. 3 - Why are atoms usually portrayed as spheres when...Ch. 3 - The distance from the sun to Earth is 1.496108 km....Ch. 3 - The nearest star to our sun is Proxima Centauri,...Ch. 3 - List these types of electromagnetic radiation in...Ch. 3 - List these types of electromagnetic radiation in...Ch. 3 - Calculate the frequency of each wavelength of...Ch. 3 - Calculate the wavelength of each frequency of...Ch. 3 - Calculate the energy of a photon of...Ch. 3 - Calculate the energy of a photon of...Ch. 3 - A laser pulse with wavelength 532 nm contains 3.85...Ch. 3 - A heat lamp produces 32.8 watts of power at a...Ch. 3 - Determine the energy of 1 mol of photons for each...Ch. 3 - How much energy is contained in 1 mol of each?...Ch. 3 - Sketch the interference pattern that results from...Ch. 3 - What happens to the interference pattern described...Ch. 3 - The resolution limit of a microscope is roughly...Ch. 3 - The smallest atoms can themselves exhibit...Ch. 3 - What is the de Broglie wavelength of an electron...Ch. 3 - A proton in a linear accelerator has a de Broglie...Ch. 3 - Prob. 53ECh. 3 - A 0.22-caliber handgun fires a 27-g bullet at a...Ch. 3 - An electron has an uncertainty in its position of...Ch. 3 - An electron traveling at [1.35 \times {10^5}\] m/s...Ch. 3 - Which electron is, on average, closer to the...Ch. 3 - Which electron is, on average, further from the...Ch. 3 - What are the possible values of I for each given...Ch. 3 - What are the possible values of m1 for each given...Ch. 3 - Which set of quantum numbers cannot occur together...Ch. 3 - Which combinations of n and I represent real...Ch. 3 - Prob. 63ECh. 3 - Sketch the 3d orbitals. How do the 4d orbitals...Ch. 3 - An electron in a hydrogen atom is excited with...Ch. 3 - Determine whether each transition in the hydrogen...Ch. 3 - According to the quantum-mechanical model for the...Ch. 3 - According to the quantum-mechanical model for the...Ch. 3 - Calculate the wavelength of the light emitted when...Ch. 3 - Calculate the frequency of the light emitted when...Ch. 3 - Prob. 71ECh. 3 - An electron in a hydrogen atom relaxes to the [n =...Ch. 3 - Ultraviolet radiation and radiation of shorter...Ch. 3 - The human eye contains a molecule called...Ch. 3 - An argon ion laser puts out 5.0 W of continuous...Ch. 3 - A green leaf has a surface area of 2.50 cm2. If...Ch. 3 - Prob. 77ECh. 3 - An X-ray photon of wavelength 0.989 nm strikes a...Ch. 3 - Prob. 79ECh. 3 - The energy required to ionize sodium is 496...Ch. 3 - Prob. 81ECh. 3 - Suppose that, in an alternate universe, the...Ch. 3 - Prob. 83ECh. 3 - Prob. 84ECh. 3 - The binding energy of electrons in a metal is 193...Ch. 3 - In order for a thermonuclear fusion reaction of...Ch. 3 - Prob. 87ECh. 3 - Prob. 88ECh. 3 - The iodine molecule can be photodissociated...Ch. 3 - A sample of naphthalene in hexane contains 5.00104...Ch. 3 - Prob. 91ECh. 3 - Prob. 92ECh. 3 - Prob. 93ECh. 3 - The energy of a vibrating molecule is quantized...Ch. 3 - The wave functions for the 1s and 2s orbitals are...Ch. 3 - Before quantum mechanics was developed, Johannes...Ch. 3 - Find the velocity of an electron emitted by a...Ch. 3 - Water is exposed to infrared radiation of...Ch. 3 - Prob. 99ECh. 3 - A metal with a threshold frequency of 6.711014s1...Ch. 3 - Find the longest wavelength of a wave that can...Ch. 3 - The amount of heat to melt ice is 0.333 kJ/g. Find...Ch. 3 - Explain the difference between the Bohr model for...Ch. 3 - The light emitted from one of the following...Ch. 3 - Determine whether an interference pattern is...Ch. 3 - Which transition in the hydrogen atom results in...
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- Given the major organic product(s) of each of the following reactions. If none is predicted, write "N.R." [answer 61 a. b. H3C C. NO₂ CH3CH2CH2Cl AICI 3 1) NaOH CI 2) H3O+ NO₂ 1. SnCl2, H3O+ 2. NaOH 3arrow_forwardPlease correct answer and don't used hand raitingarrow_forwardTo answer the following questions, consider the reaction below: CH3 . CH3 OH a. The best reagents for accomplishing the above transformation are.... a. 1. OsO4, pyridine 2. NaHSO3, H₂O b. 1. Hg(OAc)2, H₂O 1. C. 2. NaBH4 RCO₂H, CH2Cl₂ 2. H₂O* d. 1. BH3, THF 2. H₂O₂, OH b. The alcohol product is classified as a: a. 1° alcohol b. 2° alcohol C. 3° alcohol d. 4° alcohol c. The conversion of an alcohol into an alkyl chloride by reaction with SOCI2 is an example of: a. b. ن نخنه C. d. an El process an Syl process an E2 process an Sy2 processarrow_forward
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- Propose a synthesis for the following compound using benzene or toluene and any other reagents necessary. Show all major intermediate compounds that would probably be isolated during the course of your synthesis. on. Harrow_forwardProvide correct IUPAC names for each of the following compounds. NOT a. b. C. 2003 H,N- CH3 NH2 CHarrow_forward. Consider the reaction below to answer the following questions. OH 1. NaH 2. CH3I, ether O-CH3 A. Write the complete stepwise mechanism for the reaction. Show all intermediate structures and all electron flow with arrows. B. Mechanistically, the Williamson ether synthesis outlined above is: ن نخنه a. an El process b. an SN1 process C. an E2 process d. an SN2 process C. Alternatively, cyclopentyl methyl ether may be synthesized from cyclopentene. synthesis of cyclopentyl methyl ether from cyclopentene. Outline aarrow_forward
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