
Bundle: Chemistry: The Molecular Science, 5th, Loose-Leaf + OWLv2 with Quick Prep 24-Months Printed Access Card
5th Edition
ISBN: 9781305367487
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 3, Problem 135QRT
Interpretation Introduction
Interpretation:
When preparing
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Using the bond energy values, calculate the energy that must be supplied or is released upon the polymerization of 755 monomers. If energy must be supplied, provide a positive number; if energy is released, provide a negative number. Hint: Avogadro’s number is 6.02 × 1023.
-AG|F=2E|V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
Acidic solution
-0.93
+0.38
-0.51 -0.06
H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3
-0.28
-0.50
→
-0.50
Basic solution
3-1.12
-1.57
-2.05 -0.89
PO HPO →→H2PO2 P PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5 PH,
0.0
-0.5-
2 3 9 3
-1.5
-2.0
Pa
H,PO
H,PO
H,PO
-3
-1 0
2
4
Oxidation state, N
2
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…
These two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?
Chapter 3 Solutions
Bundle: Chemistry: The Molecular Science, 5th, Loose-Leaf + OWLv2 with Quick Prep 24-Months Printed Access Card
Ch. 3.1 - When washing soda, Na2CO3, reacts with sulfuric...Ch. 3.2 - When sprayed into the flame of a torch, powdered...Ch. 3.2 - Prob. 3.1PSPCh. 3.2 - Prob. 3.2PSPCh. 3.3 - Prob. 3.3PSPCh. 3.3 - Prob. 3.4PSPCh. 3.3 - Prob. 3.5PSPCh. 3.3 - Prob. 3.6PSPCh. 3.3 - Prob. 3.3CECh. 3.4 - Phosphoric acid, H3PO4, has three protons that can...
Ch. 3.4 - Prob. 3.5CECh. 3.4 - Look back through the discussion of electrolytes...Ch. 3.4 - Prob. 3.8PSPCh. 3.4 - Prob. 3.9PSPCh. 3.4 - Write a balanced equation for the reaction of...Ch. 3.4 - Prob. 3.6ECh. 3.4 - Prob. 3.7ECh. 3.4 - Prob. 3.8ECh. 3.4 - Prob. 3.9CECh. 3.4 - Prob. 3.10CECh. 3.5 - Prob. 3.11CECh. 3.5 - Prob. 3.12CECh. 3.5 - Prob. 3.13ECh. 3.5 - Prob. 3.11PSPCh. 3.5 - Prob. 3.12PSPCh. 3.5 - Prob. 3.14CECh. 3.6 - Prob. 3.15CECh. 3.6 - Prob. 3.16ECh. 3.6 - Prob. 3.13PSPCh. 3.6 - Prob. 3.17ECh. 3.6 - Prob. 3.14PSPCh. 3.7 - Prob. 3.15PSPCh. 3.7 - Using the same reaction, calculate the mass of...Ch. 3.7 - At high temperatures, silicon dioxide reacts with...Ch. 3.7 - Urea is used as a fertilizer because it can react...Ch. 3.8 - Assume the methanol synthesis has an 85.0% yield...Ch. 3.8 - Prob. 3.19PSPCh. 3.8 - Prob. 3.19ECh. 3.8 - Prob. 3.20ECh. 3.9 - Phenol is a compound of carbon, hydrogen, and...Ch. 3.9 - Calcium carbonate forms carbon dioxide and calcium...Ch. 3.10 - Prob. 3.20PSPCh. 3.10 - Prob. 3.23ECh. 3.10 - Prob. 3.24ECh. 3.10 - Prob. 3.25CECh. 3.10 - Describe how you would prepare each solution.
1.00...Ch. 3.10 - Prob. 3.26ECh. 3.10 - Prob. 3.22PSPCh. 3.10 - Prob. 3.27CECh. 3.11 - Prob. 3.23PSPCh. 3.11 - Prob. 3.24PSPCh. 3.11 - Sodium chloride is used in intravenous solutions...Ch. 3.12 - Show that the reaction of KMnO4 with H2O2 is a...Ch. 3.12 - Prob. 3.25PSPCh. 3 - Aqueous solutions of ammonium sulfide and...Ch. 3 - In a blast furnace at high temperature, iron(III)...Ch. 3 - What information does a balanced chemical equation...Ch. 3 - Prob. 2QRTCh. 3 - Prob. 3QRTCh. 3 - Prob. 4QRTCh. 3 - Prob. 5QRTCh. 3 - Prob. 6QRTCh. 3 - When asked, “What is the limiting reactant?” you...Ch. 3 - Prob. 8QRTCh. 3 - Prob. 9QRTCh. 3 - For this reaction, fill in the table with the...Ch. 3 - Prob. 11QRTCh. 3 - Prob. 12QRTCh. 3 - This diagram shows A (blue spheres) reacting with...Ch. 3 - Prob. 14QRTCh. 3 - Prob. 15QRTCh. 3 - Prob. 16QRTCh. 3 - Prob. 17QRTCh. 3 - Prob. 18QRTCh. 3 - Prob. 19QRTCh. 3 - Balance these equations. (a) UO2(s) + HF() UF4(s)...Ch. 3 - Prob. 21QRTCh. 3 - Prob. 22QRTCh. 3 - Prob. 23QRTCh. 3 - Balance these combustion reactions. (a) C6H12O6 +...Ch. 3 - Prob. 25QRTCh. 3 - Prob. 26QRTCh. 3 - Prob. 27QRTCh. 3 - Which substance conducts electricity when...Ch. 3 - Prob. 29QRTCh. 3 - Predict whether each compound is soluble in water....Ch. 3 - Prob. 31QRTCh. 3 - Which drawing is the best nanoscale representation...Ch. 3 - If aqueous solutions of potassium carbonate and...Ch. 3 - If aqueous solutions of potassium sulfide and...Ch. 3 - Prob. 35QRTCh. 3 - Prob. 36QRTCh. 3 - Prob. 37QRTCh. 3 - Prob. 38QRTCh. 3 - Prob. 39QRTCh. 3 - Prob. 40QRTCh. 3 - Prob. 41QRTCh. 3 - Prob. 42QRTCh. 3 - Prob. 43QRTCh. 3 - Prob. 44QRTCh. 3 - Prob. 45QRTCh. 3 - Prob. 46QRTCh. 3 - Prob. 47QRTCh. 3 - Prob. 48QRTCh. 3 - Prob. 49QRTCh. 3 - Prob. 50QRTCh. 3 - Prob. 51QRTCh. 3 - Prob. 52QRTCh. 3 - Prob. 53QRTCh. 3 - Prob. 54QRTCh. 3 - Prob. 55QRTCh. 3 - Prob. 56QRTCh. 3 - Prob. 57QRTCh. 3 - Prob. 58QRTCh. 3 - Nitrogen monoxide is oxidized in air to give brown...Ch. 3 - Prob. 60QRTCh. 3 - The final step in the manufacture of platinum...Ch. 3 - Disulfur dichloride, S2Cl2, is used to vulcanize...Ch. 3 - Prob. 63QRTCh. 3 - Prob. 64QRTCh. 3 - Prob. 65QRTCh. 3 - Prob. 66QRTCh. 3 - Prob. 67QRTCh. 3 - Cisplatin, Pt(NH3)2Cl2, a drug used in the...Ch. 3 - Aluminum chloride, Al2Cl6, is an inexpensive...Ch. 3 - Prob. 70QRTCh. 3 - Prob. 71QRTCh. 3 - Prob. 72QRTCh. 3 - Prob. 73QRTCh. 3 - Quicklime, CaO, is formed when calcium hydroxide...Ch. 3 - Prob. 75QRTCh. 3 - Disulfur dichloride, which has a revolting smell,...Ch. 3 - Prob. 77QRTCh. 3 - Prob. 78QRTCh. 3 - Quinone, which is used in the dye industry and in...Ch. 3 - l-Dopa is a drug used for the treatment of...Ch. 3 - Write the balanced chemical equation for the...Ch. 3 - Prob. 82QRTCh. 3 - Prob. 83QRTCh. 3 - Prob. 84QRTCh. 3 - Prob. 85QRTCh. 3 - Prob. 86QRTCh. 3 - You need 300. mL of 0.500-M K2Cr2O7. Which method...Ch. 3 - You need to make a 0.300-M solution of NiSO4(aq)....Ch. 3 - You wish to make a 0.200-M solution of CuSO4(aq)....Ch. 3 - Prob. 90QRTCh. 3 - Prob. 91QRTCh. 3 - You mix 25.0 mL of 0.234-M FeCl3 solution with...Ch. 3 - A soft drink contains an unknown mass of citric...Ch. 3 - Prob. 94QRTCh. 3 - Prob. 95QRTCh. 3 - Potassium hydrogen phthalate, KHC8H4O4, is used to...Ch. 3 - Prob. 97QRTCh. 3 - Prob. 98QRTCh. 3 - Prob. 99QRTCh. 3 - Prob. 100QRTCh. 3 - Boron forms an extensive series of compounds with...Ch. 3 - Prob. 102QRTCh. 3 - Prob. 103QRTCh. 3 - Prob. 104QRTCh. 3 - Prob. 105QRTCh. 3 - Azurite is a copper-containing mineral that often...Ch. 3 - Prob. 107QRTCh. 3 - Prob. 108QRTCh. 3 - Vitamin C is ascorbic acid, HC6H7O6, which can be...Ch. 3 - Prob. 110QRTCh. 3 - Prob. 111QRTCh. 3 - Prob. 112QRTCh. 3 - Prob. 113QRTCh. 3 - Prob. 114QRTCh. 3 - Prob. 115QRTCh. 3 - Prob. 116QRTCh. 3 - Prob. 117QRTCh. 3 - Prob. 118QRTCh. 3 - Prob. 119QRTCh. 3 - Prob. 120QRTCh. 3 - Ammonia can be formed by a direct reaction of...Ch. 3 - Carbon monoxide burns readily in oxygen to form...Ch. 3 - Prob. 123QRTCh. 3 - Write a balanced chemical equation that represents...Ch. 3 - A student set up an experiment for six different...Ch. 3 - A weighed sample of a metal is added to liquid...Ch. 3 - Prob. 127QRTCh. 3 - Prob. 128QRTCh. 3 - Each box represents a tiny volume in an aqueous...Ch. 3 - Consider the chemical reaction 2 S + 3 O2 → 2 SO3....Ch. 3 - Prob. 131QRTCh. 3 - Prob. 132QRTCh. 3 - Prob. 133QRTCh. 3 - Prob. 134QRTCh. 3 - Prob. 135QRTCh. 3 - Prob. 136QRTCh. 3 - Prob. 137QRTCh. 3 - Prob. 138QRTCh. 3 - Prob. 139QRTCh. 3 - Prob. 140QRTCh. 3 - Prob. 141QRTCh. 3 - Prob. 142QRTCh. 3 - In a reaction, 1.2 g element A reacts with exactly...Ch. 3 - Prob. 144QRTCh. 3 - When solutions of silver nitrate and sodium...Ch. 3 - Nickel metal reacts with aqueous silver nitrate in...Ch. 3 - Prob. 147QRTCh. 3 - Prob. 148QRTCh. 3 - Prob. 149QRTCh. 3 - Prob. 150QRTCh. 3 - A mountain lake that is 4.0 km × 6.0 km with an...Ch. 3 - Prob. 152QRTCh. 3 - Prob. 153QRTCh. 3 - Prob. 154QRTCh. 3 - Prob. 155QRTCh. 3 - Ethanol, C2H5OH, is a gasoline additive that can...Ch. 3 - Prob. 157QRTCh. 3 - Prob. 3.ACPCh. 3 - Prob. 3.BCPCh. 3 - Prob. 3.DCPCh. 3 - Prob. 3.ECPCh. 3 - Prob. 3.FCPCh. 3 - Prob. 3.GCP
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- What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1. PPh3 3 1 2 2. n-BuLi • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Explanation Check Click and drag to start drawing a structure. 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Priva ×arrow_forwardPredict the products of this organic reaction: Explanation Check IN NaBH3CN H+ ? Click and drag to start drawing a structure. D 5 C +arrow_forwardPredict the products of this organic reaction: H3O+ + ? • Draw all the reasonable products in the drawing area below. If there are no products, because no reaction will occur, check the box under the drawing area. • Include both major and minor products, if some of the products will be more common than others. • Be sure to use wedge and dash bonds if you need to distinguish between enantiomers. No reaction. Click and drag to start drawing a structure. dmarrow_forward
- Iarrow_forwardDraw the anti-Markovnikov product of the hydration of this alkene. this problem. Note for advanced students: draw only one product, and don't worry about showing any stereochemistry. Drawing dash and wedge bonds has been disabled for esc esc ☐ Explanation Check F1 1 2 F2 # 3 F3 + $ 14 × 1. BH THE BH3 2. H O NaOH '2 2' Click and drag to start drawing a structure. F4 Q W E R A S D % 905 LL F5 F6 F7 © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility < & 6 7 27 8 T Y U G H I F8 F9 F10 F11 F12 9 0 J K L P + // command option Z X C V B N M H H rol option commandarrow_forwardAG/F-2° V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: -0.93 +0.38 -0.50 -0.51 -0.06 H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3 Acidic solution Basic solution -0.28 -0.50 3--1.12 -1.57 -2.05 -0.89 PO HPO H₂PO₂ →P → PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH P 0.0 -0.5 -1.0- -1.5- -2.0 H.PO, -2.3+ -3 -2 -1 1 2 3 2 H,PO, b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) H,PO 4 S Oxidation stale, Narrow_forward
- 4. For the following complexes, draw the structures and give a d-electron count of the metal: a) Tris(acetylacetonato)iron(III) b) Hexabromoplatinate(2-) c) Potassium diamminetetrabromocobaltate(III) (6 points)arrow_forward2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation constant for [Fe(CN)6] 4 is ~1032, and that: Fe3+ (aq) + e = Fe²+ (aq) E° = +0.77 V [Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V (4 points)arrow_forward5. Consider the compounds shown below as ligands in coordination chemistry and identify their denticity; comment on their ability to form chelate complexes. (6 points) N N A B N N N IN N Carrow_forward
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