
Macroscale and Microscale Organic Experiments
7th Edition
ISBN: 9781305577190
Author: Kenneth L. Williamson, Katherine M. Masters
Publisher: Brooks Cole
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Textbook Question
Chapter 3, Problem 12Q
An unknown compound is suspected to be acetanilide
What would happen to the melting point if this unknown were mixed with (a) an equal quantity of pure acetanilide? (b) An equal quantity of benzoic acid?
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Draw the acyl chloride that would give the ketone shown using the Friedel-Crafts acylation reaction.
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Chapter 3 Solutions
Macroscale and Microscale Organic Experiments
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- Order the following organic reactions by relative rate. That is, select '1' next to the reaction that will have the fastest initial rate, select '2' next to the reaction that will have the next fastest initial rate, and so on. If two reactions will have very similar initial rates, you can select the same number next to both. If a reaction will have zero or nearly zero initial rate, don't select a number and check the box in the table instead. Note: the "Nu" in these reactions means "a generic nucleophile." ملی CI :Nu 2 он 3 H Reaction Relative Rate (Choose one) ▼ Nu :CI: zero or nearly zero Nu :Nu bi (Choose one) zero or nearly zero : Nu لی Nu :H (Choose one) zero or nearly zeroarrow_forward9:12 AM Tue Mar 4 66% Problem 38 of 15 Submit Curved arrows are used to illustrate the flow of electrons. Use the reaction conditions provided and follow the arrows to draw the product formed in this reaction or mechanistic step(s). Include all lone pairs and charges as appropriate. Ignore inorganic byproducts. Br2 FeBrз H (+) Br: H : Br----FeBr3 く a SU 00 nd earrow_forwardUnder aqueous acidic conditions, nitriles will react to form a neutral organic intermediate 1 that has an N atom in it first, and then they will continue to react to form the final product 2: ☐ : P Draw the missing intermediate 1 and the final product 2 in the box below. You can draw the two structures in any arrangement you like. CN H₂O H₂O H+ H+ Click and drag to start drawing a structure. Хarrow_forward
- Organic bases have lone pairs of electrons that are capable of accepting protons. Lone pair electrons in a neutral or negatively charged species, or pi electron pairs. Explain the latter case (pi electron pairs).arrow_forwardDescribe the propyl anion.arrow_forwardIndicate the names of these compounds (if they exist). 0: HỌC—NH CH3CH2-CH2arrow_forward
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