(a) Interpretation: A skeletal structure of the anabolic steroid 4 -androstene- 3 , 17 -dione, also called “andro,” from the given description is to be drawn. Concept introduction: Steroids, a group of tetracyclic lipids composed of one five-membered ring and three six-membered rings. These rings are lettered by A , B , C , and D . Most of the steroids contain two angular methyl groups. These methyl groups are numbered as C18 and C19 respectively.

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Answer 1

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Chapter 29.8, Problem 15P

Interpretation Introduction

(a)

Interpretation: A skeletal structure of the anabolic steroid 4-androstene-3,17-dione, also called “andro,” from the given description is to be drawn.

Concept introduction: Steroids, a group of tetracyclic lipids composed of one five-membered ring and three six-membered rings. These rings are lettered by A, B, C, and D. Most of the steroids contain two angular methyl groups. These methyl groups are numbered as C18 and C19 respectively.

Interpretation Introduction

(b)

Interpretation: The addition of all wedges and dashed wedges for all stereogenic centers to steroid 4-androstene-3,17-dione with the given information are to be stated.

Concept introduction: Steroids, a group of tetracyclic lipids composed of one five-membered ring and three six-membered rings. These rings are lettered by A, B, C, and D. Most of the steroids contain two angular methyl groups. These methyl groups are numbered as C18 and C19 respectively.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.

Part V. Draw the structure of compound tecla using the IR spectrum Cobtained from the compound in KBr pellet) and the mass spectrum as shown below. The mass spectrum of compound Tesla showed strong mt peak at 71. TRANSMITTANCE LOD Relative Intensity 100 MS-NW-1539 40 20 80 T 44 55 10 15 20 25 30 35 40 45 50 55 60 65 70 75 m/z D 4000 3000 2000 1500 1000 500 HAVENUMBERI-11

Answer 2

Question

Chapter 29.8, Problem 15P

Interpretation Introduction

(a)

Interpretation: A skeletal structure of the anabolic steroid 4-androstene-3,17-dione, also called “andro,” from the given description is to be drawn.

Concept introduction: Steroids, a group of tetracyclic lipids composed of one five-membered ring and three six-membered rings. These rings are lettered by A, B, C, and D. Most of the steroids contain two angular methyl groups. These methyl groups are numbered as C18 and C19 respectively.

Interpretation Introduction

(b)

Interpretation: The addition of all wedges and dashed wedges for all stereogenic centers to steroid 4-androstene-3,17-dione with the given information are to be stated.

Concept introduction: Steroids, a group of tetracyclic lipids composed of one five-membered ring and three six-membered rings. These rings are lettered by A, B, C, and D. Most of the steroids contain two angular methyl groups. These methyl groups are numbered as C18 and C19 respectively.

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Answer 3

Question

Chapter 29.8, Problem 15P

Interpretation Introduction

(a)

Interpretation: A skeletal structure of the anabolic steroid 4-androstene-3,17-dione, also called “andro,” from the given description is to be drawn.

Concept introduction: Steroids, a group of tetracyclic lipids composed of one five-membered ring and three six-membered rings. These rings are lettered by A, B, C, and D. Most of the steroids contain two angular methyl groups. These methyl groups are numbered as C18 and C19 respectively.

Interpretation Introduction

(b)

Interpretation: The addition of all wedges and dashed wedges for all stereogenic centers to steroid 4-androstene-3,17-dione with the given information are to be stated.

Concept introduction: Steroids, a group of tetracyclic lipids composed of one five-membered ring and three six-membered rings. These rings are lettered by A, B, C, and D. Most of the steroids contain two angular methyl groups. These methyl groups are numbered as C18 and C19 respectively.

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Answer 4

Question

Chapter 29.8, Problem 15P

Interpretation Introduction

(a)

Interpretation: A skeletal structure of the anabolic steroid 4-androstene-3,17-dione, also called “andro,” from the given description is to be drawn.

Concept introduction: Steroids, a group of tetracyclic lipids composed of one five-membered ring and three six-membered rings. These rings are lettered by A, B, C, and D. Most of the steroids contain two angular methyl groups. These methyl groups are numbered as C18 and C19 respectively.

Interpretation Introduction

(b)

Interpretation: The addition of all wedges and dashed wedges for all stereogenic centers to steroid 4-androstene-3,17-dione with the given information are to be stated.

Concept introduction: Steroids, a group of tetracyclic lipids composed of one five-membered ring and three six-membered rings. These rings are lettered by A, B, C, and D. Most of the steroids contain two angular methyl groups. These methyl groups are numbered as C18 and C19 respectively.

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Answer 5

Chapter 29.8, Problem 15P

Interpretation Introduction

(a)

Interpretation: A skeletal structure of the anabolic steroid 4-androstene-3,17-dione, also called “andro,” from the given description is to be drawn.

Concept introduction: Steroids, a group of tetracyclic lipids composed of one five-membered ring and three six-membered rings. These rings are lettered by A, B, C, and D. Most of the steroids contain two angular methyl groups. These methyl groups are numbered as C18 and C19 respectively.

Interpretation Introduction

(b)

Interpretation: The addition of all wedges and dashed wedges for all stereogenic centers to steroid 4-androstene-3,17-dione with the given information are to be stated.

Concept introduction: Steroids, a group of tetracyclic lipids composed of one five-membered ring and three six-membered rings. These rings are lettered by A, B, C, and D. Most of the steroids contain two angular methyl groups. These methyl groups are numbered as C18 and C19 respectively.

Answer 6

Chapter 29.8, Problem 15P

Interpretation Introduction

(a)

Interpretation: A skeletal structure of the anabolic steroid 4-androstene-3,17-dione, also called “andro,” from the given description is to be drawn.

Concept introduction: Steroids, a group of tetracyclic lipids composed of one five-membered ring and three six-membered rings. These rings are lettered by A, B, C, and D. Most of the steroids contain two angular methyl groups. These methyl groups are numbered as C18 and C19 respectively.

Answer 7

Chapter 29.8, Problem 15P

Interpretation Introduction

(a)

Interpretation: A skeletal structure of the anabolic steroid 4-androstene-3,17-dione, also called “andro,” from the given description is to be drawn.

Concept introduction: Steroids, a group of tetracyclic lipids composed of one five-membered ring and three six-membered rings. These rings are lettered by A, B, C, and D. Most of the steroids contain two angular methyl groups. These methyl groups are numbered as C18 and C19 respectively.

Answer 8

Interpretation Introduction

(b)

Interpretation: The addition of all wedges and dashed wedges for all stereogenic centers to steroid 4-androstene-3,17-dione with the given information are to be stated.

Concept introduction: Steroids, a group of tetracyclic lipids composed of one five-membered ring and three six-membered rings. These rings are lettered by A, B, C, and D. Most of the steroids contain two angular methyl groups. These methyl groups are numbered as C18 and C19 respectively.

Answer 9

Interpretation Introduction

(b)

Interpretation: The addition of all wedges and dashed wedges for all stereogenic centers to steroid 4-androstene-3,17-dione with the given information are to be stated.

Concept introduction: Steroids, a group of tetracyclic lipids composed of one five-membered ring and three six-membered rings. These rings are lettered by A, B, C, and D. Most of the steroids contain two angular methyl groups. These methyl groups are numbered as C18 and C19 respectively.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 29.2 - Problem 31.1 One component of jojoba oil is a wax...Ch. 29.3 - Problem 31.2 How would you expect the melting...Ch. 29.3 - Problem 31.3 Draw the products formed when...Ch. 29.3 - Problem 31.4 The main fatty acid component of the...Ch. 29.3 - Prob. 5P Ch. 29.7 - Problem 31.10 Locate the isoprene units in each...Ch. 29.7 - Problem 31.11 Locate the isoprene units in...Ch. 29.7 - Problem 31.12 Write a stepwise mechanism for the...Ch. 29.7 - Prob. 14P Ch. 29.8 - Prob. 15P

Solution Summary: The author explains the skeletal structure of the anabolic steroid 4 -androstene- 3,17-dione, also called "andro."

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Chapter 29 Solutions