Organic Chemistry
Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 29.6, Problem FQ
Interpretation Introduction

Interpretation:

Among the given conditions, the condition that lowers the length of the polymers in the curing of superglue has to be identified.

Concept Introduction:

Anionic Polymerizations:  It can be initiated by addition of a nucleophile to an activated

Alkene.  The most common nucleophiles used for this purpose are metal alkyls such as methyl- and sec-butyllithium. The newly formed carbanion then acts as a nucleophile and adds to another monomer unit, and the propagation continues.

Organic Chemistry, Chapter 29.6, Problem FQ

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?
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