Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Question
Chapter 29, Problem 29.29P
(a)
Interpretation Introduction
Interpretation:
The structure formula for comparable sections of the poly (vinyl chloride) has to be drawn.
(b)
Interpretation Introduction
Interpretation:
The structure formula for comparable sections of the Polytetrafluoroethylene has to be drawn.
(c)
Interpretation Introduction
Interpretation:
The structure formula for comparable sections of the Poly (methyl methacrylate) has to be drawn.
(d)
Interpretation Introduction
Interpretation:
The structure formula for comparable sections of the Poly (1,1-dichloroethylene) has to be drawn.
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Write the chemical reaction showing the formation of the following polymers from initial reactants: (a) nylon, (b) lexan, (c) terylene, (d) polyurethane.
Write an equation for the formation of the following polymers.(a) Polystyrene, from styrene (C6H5CH=CH2)(b) PET (polyethylene terephthalate), from ethylene glycol and terephthalic acid
1) (a) What is the difference between homopolymer and copolymer?
(b) How can you classify the polymer depending on their skeletal structure?
Chapter 29 Solutions
Organic Chemistry
Ch. 29.2 - Prob. 29.1PCh. 29.5 - Prob. 29.2PCh. 29.6 - Prob. AQCh. 29.6 - Prob. BQCh. 29.6 - Prob. CQCh. 29.6 - Prob. DQCh. 29.6 - Prob. EQCh. 29.6 - Prob. FQCh. 29.6 - Prob. 29.3PCh. 29.6 - Prob. 29.4P
Ch. 29 - Prob. 29.5PCh. 29 - Prob. 29.6PCh. 29 - Prob. 29.7PCh. 29 - Prob. 29.8PCh. 29 - Prob. 29.9PCh. 29 - Prob. 29.10PCh. 29 - Prob. 29.11PCh. 29 - Prob. 29.12PCh. 29 - Prob. 29.13PCh. 29 - Prob. 29.14PCh. 29 - Prob. 29.15PCh. 29 - Prob. 29.16PCh. 29 - Polycarbonates (Section 29.5C) are also formed by...Ch. 29 - Prob. 29.18PCh. 29 - Prob. 29.19PCh. 29 - Prob. 29.20PCh. 29 - Prob. 29.21PCh. 29 - Draw a structural formula of the polymer resulting...Ch. 29 - Prob. 29.23PCh. 29 - Prob. 29.24PCh. 29 - Prob. 29.25PCh. 29 - Select the monomer in each pair that is more...Ch. 29 - Prob. 29.27PCh. 29 - Prob. 29.28PCh. 29 - Prob. 29.29PCh. 29 - Prob. 29.30PCh. 29 - Prob. 29.31PCh. 29 - Prob. 29.32PCh. 29 - Prob. 29.33PCh. 29 - Radical polymerization of styrene gives a linear...Ch. 29 - Prob. 29.35PCh. 29 - Prob. 29.36PCh. 29 - Prob. 29.37PCh. 29 - Prob. 29.38P
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- Polyethylene (PE), polyvinylchloride (PVC), polypropylene (PP), polystyrene, an nylon are examples ofarrow_forwardBased on the representative part of the polymer chain, a) state whether it is an addition or a condensation polymer. b) draw the full structural formula of the two monomers use to synthesize this polymer.arrow_forwardSketch the repeat structure for each of the following alternating copolymers: (a) poly(ethylenepropylene) and poly(isobutylene-isoprene).arrow_forward
- (d) Propene can polymerize to form poly(propene). (i) State, with a reason, the atom economy for this reaction. (ii) Draw a section of this polymer, showing two repeat units.arrow_forwardDo you agree with the statement that if ethylene in polyethylene is derived from a biodegradable resource such as corn, does it make the polyethylene biodegradable? Explain briefly your answer?arrow_forwardDuring our lectures on polymeric materials, I used polyethylene as an example because of its very straightforward structure. (a.) Hydrogen peroxide (H2O2) is used as an initiator for the polymerization of ethylene. Draw a diagram of a dissociated hydrogen peroxide molecule which emphasizes the creation of two free radicals (unbonded electrons) that can serve as initiators or as terminators of polymerization.arrow_forward
- Shown below is the ε-caprolactone monomer where the biopolymer polycaprolactone (PCL) is synthesized from. (a) What is the functionality of the monomer? (b) What is polymerization mechanism to produce PCL? (c) Draw the repeating unit of the homopolymer given that the functional group is located at the terminal of the hydrocarbon chainarrow_forwardA polymer closely related to PET is PBT, which is made from terephthalic acid and butane-1,4-diol.(a) Propose a structure for PBT and write the condensed formula for the structure.(b) What does PBT stand for? That is, what do you expect the trivial name of PBT to be?(c) Would you expect PBT to have a higher or lower melting point than PET? Justify your answer.(d) PBT, rather than PET, is used in molding because it crystallizes faster. Explain why PBT crystallizes more quickly than PET.arrow_forwardb Explain why nylon-6 can be classified as a polyamide. c Explain why some chemists classify nylon-6 as an addition polymer and not a condensation polymer. d Suggest the product of hydrolysis of nylon-6.arrow_forward
- Polychlorinated Biphenyls (PCBs) are chemicals formed by attaching one or more chlorine atoms to a pair of connected benzene rings. (a) Summarise the adverse health effects associated with exposure to PCBs. (b) With a suitable illustration, explain the action of PCBs toxicity.arrow_forwardIs polystyrene biodegradable or compostable and why??arrow_forwardWhich of the following three compounds:- polyethylene [essentially no vapor pressure at 1 atm]- menthone [medium vapor pressure at 1 atm]- benzoic acid [low vapor pressure at 1 atm]Is most likely to be amenable to purification by sublimation? Whyarrow_forward
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