Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 28.2, Problem 4P
Draw the mechanism for the radical
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Lactams (cyclic amides) can undergo anionic ring-opening polymerization when treated with a small amount of a strong base such as NaH, as shown here. Draw the mechanism for the initiation and first two propagationsteps for this polymerization, and draw the repeating unit of the resulting polymer.
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Chapter 28 Solutions
Organic Chemistry (6th Edition)
Ch. 28.1 - Prob. 1PCh. 28.2 - Prob. 2PCh. 28.2 - Prob. 3PCh. 28.2 - Draw the mechanism for the radical polymerization...Ch. 28.2 - Prob. 8PCh. 28.2 - Prob. 9PCh. 28.2 - Prob. 10PCh. 28.3 - Problem 30.12
What polymer is formed by anionic...Ch. 28.5 - Prob. 12PCh. 28.5 - Prob. 13P
Ch. 28.6 - Problem 30.15
What polyamide is formed from each...Ch. 28.6 - Prob. 19PCh. 28.7 - Prob. 20PCh. 28.8 - Prob. 21PCh. 28.9 - Prob. 22PCh. 28.9 - Prob. 23PCh. 28 - Prob. 24PCh. 28 - Prob. 25PCh. 28 - 30.30 Draw each polymer in Problem 30.29 using the...Ch. 28 - Prob. 44PCh. 28 - 30.49 Draw the products of each reaction.
a. e....Ch. 28 - Prob. 56PCh. 28 - 30.56 Compound A is a novel poly (ester amide)...Ch. 28 - 30.57 Researchers at Rutgers University have...Ch. 28 - 30.58 Melmac, a thermosetting polymer formed from...Ch. 28 - 30.59 Although chain branching in radical...Ch. 28 - Prob. 61P
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- The product of the polymerization of CH3 CH3 T bv) (-CH₂-CH-CH₂-CH-)n. ds) (-CH₂-CH = CH-CH₂-CH = CH-)n CH₂=CH-CH3 is: CH3 CH3 no) ( — CH= C -CH=C-) bc) (-CH=CH-CH₂-CH=CH-CH₂-)narrow_forwardReaction (blank) Choose your answer here in the radical polymerization of styrene would afford the more stable radical intermediate. A) 1 B) 2 C) 1 or 2arrow_forwardPolymerization of 1 3 -hexadiene can yield in either cis (Z) or trans (E) polymer.on the other hand the polymerization of 1 4 -hexadiene will not have any isomer.Why?arrow_forward
- 3. Which of the following could be polymerized by cationic or anionic chain polymerization(or both or neither)? CN Ph он co,CH, Doarrow_forwardDraw the mechanism for ziegler-natta-catalyzed polymerization of a subdtitude ethylene.arrow_forwardReaction (blank) Choose your answer here in the radical polymerization of styrene would afford the more stable radical intermediate. A) 1 B) 2 C) 1 or 2arrow_forward
- Draw the organic product of the following reaction. CH3 m-CICgH,CO;H • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If the reaction produces a racemic mixture, just draw one stereoisomer. • If more than one product is possible, only draw the major product. opy astearrow_forwardQ 1(e) [10 Marks] Draw the structure of the monomer from which polystyrene (P) originates; illustrate the radical reaction that occurs to provide polystyrene (P). (CH2-CH) Parrow_forwardComplete this isobutylene reactionarrow_forward
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