Chapter 28, Problem 45P

Interpretation Introduction

Interpretation:

Given transformation can be carried out using only heat or light has to be determined

Concept introduction:

Woodward – Hoffmann rules for Electrocyclic reactions are listed below

$\begin{array}{ccc}\text{Number}\text{of}\text{conjugated}\text{Π}\text{bonds}& \text{Reaction}\text{conditions}& \text{Allowed}\text{mode}\text{of}\text{ring}\text{closure}\\ \text{Even}\text{number}& \text{Thermal}& \text{Conrotatory}\\ & \text{Photochemical}& \text{Disrotatory}\\ \text{Odd}\text{number}& \text{Thermal}& \text{Disrotatory}\\ & \text{Photochemical}& \text{Conrotatory}\end{array}$

A photochemical reaction takes place when a reactant absorbs light and a thermal reaction takes place without the absorption of light.

Woodward – Hoffmann rules for the configuration of electrocyclic reactions are,

$\begin{array}{ccc}\text{Substituents}\text{in}\text{the}\text{reactant}& \text{Mode}\text{of}\text{ring}\text{closure}& \text{Configuration}\text{of}\text{the}\text{product}\\ \text{Point}\text{in}\text{opposite}\text{directions}& \text{Disrotatory}& \text{cis}\\ & \text{Conrotatory}& \text{trans}\\ \text{Point}\text{in}\text{the}\text{same}\text{directions}& \text{Disrotatory}& \text{trans}\\ & \text{Conrotatory}& \text{cis}\end{array}$