Pearson eText Organic Chemistry -- Instant Access (Pearson+)
Pearson eText Organic Chemistry -- Instant Access (Pearson+)
8th Edition
ISBN: 9780135213711
Author: Paula Bruice
Publisher: PEARSON+
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Chapter 28, Problem 40P
Interpretation Introduction

Interpretation:

Product with 99% and 1% yield should be identified from the given reaction, the reaction involving the thermal opening of cis-3, 4-Dimethylcyclobutene.

Concept introduction:

Conjugated system: A system of connected p-orbitals with delocalized electrons with alternating single and multiple bonds and the compound may be cyclic, linear or mixed

Woodward –Hoffmann rules are the set of rules used to vindicate or predict certain aspects of the stereo chemical outcome and activation energy of pericyclic reactions.

Woodward – Hoffmann rules for pericyclic reactions are listed below

NumberofconjugatedΠbondsReactionconditionsAllowedmodeofringclosureEvennumberThermalConrotatoryPhotochemicalDisrotatoryOddnumberThermalDisrotatoryPhotochemicalConrotatory

Woodward – Hoffmann rules for the configuration of pericyclic reactions are,

SubstituentsinthereactantModeofringclosureConfigurationoftheproductPointinoppositedirectionsDisrotatorycisConrotatorytransPointinthesamedirectionsDisrotatorytransConrotatorycis

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