General Chemistry - Standalone book (MindTap Course List)
11th Edition
ISBN: 9781305580343
Author: Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher: Cengage Learning
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Question
Chapter 2.8, Problem 2.10E
Interpretation Introduction
Interpretation:
The name and formula of the anion corresponding to perbromic acid has to be given.
Concept Introduction:
When an acid is deprotonated, anion is formed. The naming of the formed anion is done by replacing “-ic” in the acid name with “-ate”.
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The complex anion in Ba₂[Cr(CN)6] is a tetragonally distorted octahedral complex (Dan). Baz[Cr(CN)6] is
paramagnetic at room temperature with S = 1. Assume that the complex is a low-spin complex.
a) Identify if the [Cr(CN)6] anionic complex has 4 long and
2 short bonds (left side of figure) or if the complex has 4
short and 2 long bonds (right side of figure) with respect
to Oh symmetry. Use crystal field theory to answer this
question. Explain/rationalize your decision. Can the
provided information decide on the order of orbital
energies?
Dah
Tetragonal Distortion
ய
Dab
z-compression
z-elongation
x and y elongation
O symmetry
x and y compression
E
eg d² dx²-y²
t2g
dxy dxz dyz
Question 4 a) continued:
Provide your explanations in the space below.
b) At low temperatures Ba₂[Cr(CN)6] is ferromagnetically ordered with a phase transition to a paramagnetic
phase at Tc = 150K. Sketch the magnetic susceptibility vs. temperature in the diagram below. Indicate Tc
as well as the paramagnetic and…
Chapter 2 Solutions
General Chemistry - Standalone book (MindTap Course List)
Ch. 2.1 - Like Dalton, chemists continue to model atoms...Ch. 2.2 - Prob. 2.2CCCh. 2.3 - A nucleus consists of 17 protons and 18 neutrons....Ch. 2.4 - Chlorine consists of the following isotopes:...Ch. 2.5 - By referring to the periodic table (Figure 2.15 or...Ch. 2.5 - Consider the elements He, Ne, and Ar. Can you come...Ch. 2.6 - Prob. 2.4ECh. 2.6 - Classify each of the following as either an ionic...Ch. 2.8 - Prob. 2.5CCCh. 2.8 - Prob. 2.5E
Ch. 2.8 - Prob. 2.6ECh. 2.8 - Prob. 2.6CCCh. 2.8 - Prob. 2.7ECh. 2.8 - Prob. 2.8ECh. 2.8 - Prob. 2.9ECh. 2.8 - Prob. 2.10ECh. 2.8 - Washing soda has the formula Na2CO310H2O. What is...Ch. 2.8 - Prob. 2.12ECh. 2.8 - Prob. 2.7CCCh. 2.10 - Prob. 2.13ECh. 2 - Describe atomic theory and discuss how it explains...Ch. 2 - Two compounds of iron and chlorine, A and B,...Ch. 2 - Explain the operation of a cathode-ray tube....Ch. 2 - Prob. 2.4QPCh. 2 - Prob. 2.5QPCh. 2 - What are the different kinds of particles in the...Ch. 2 - Describe how protons and neutrons were discovered...Ch. 2 - Oxygen consists of three different _____, each...Ch. 2 - Describe how Dalton obtained relative atomic...Ch. 2 - Briefly explain how a mass spectrometer works....Ch. 2 - Define the term atomic weight. Why might the...Ch. 2 - What is the name of the element in Group 4A and...Ch. 2 - Prob. 2.13QPCh. 2 - Prob. 2.14QPCh. 2 - Prob. 2.15QPCh. 2 - What is the fundamental difference between an...Ch. 2 - Prob. 2.17QPCh. 2 - Which of the following models represent a(n): a...Ch. 2 - Prob. 2.19QPCh. 2 - Prob. 2.20QPCh. 2 - How many protons, neutrons, and electrons are in...Ch. 2 - The atomic weight of Ga is 69.72 amu. There are...Ch. 2 - Prob. 2.23QPCh. 2 - A chunk of an unidentified element (lets call it...Ch. 2 - Average Atomic Weight Part 1: Consider the four...Ch. 2 - Model of the Atom Consider the following...Ch. 2 - One of the early models of the atom proposed that...Ch. 2 - A friend is trying to balance the following...Ch. 2 - Given that the periodic table is an organizational...Ch. 2 - Prob. 2.30QPCh. 2 - Prob. 2.31QPCh. 2 - Match the molecular model with the correct...Ch. 2 - Consider a hypothetical case in which the charge...Ch. 2 - Prob. 2.34QPCh. 2 - Prob. 2.35QPCh. 2 - You perform a chemical reaction using the...Ch. 2 - Prob. 2.37QPCh. 2 - Prob. 2.38QPCh. 2 - Prob. 2.39QPCh. 2 - Prob. 2.40QPCh. 2 - A student has determined the mass-to-charge ratio...Ch. 2 - The mass-to-charge ratio for the positive ion F+...Ch. 2 - The following table gives the number of protons...Ch. 2 - The following table gives the number of protons...Ch. 2 - Naturally occurring chlorine is a mixture of the...Ch. 2 - Naturally occurring nitrogen is a mixture of 14N...Ch. 2 - What is the nuclide symbol for the nucleus that...Ch. 2 - An atom contains 34 protons and 45 neutrons. What...Ch. 2 - Ammonia is a gas with a characteristic pungent...Ch. 2 - Hydrogen sulfide is a gas with the odor of rotten...Ch. 2 - Calculate the atomic weight of an element with two...Ch. 2 - An element has two naturally occurring isotopes...Ch. 2 - An element has three naturally occurring isotopes...Ch. 2 - An element has three naturally occurring isotopes...Ch. 2 - While traveling to a distant universe, you...Ch. 2 - While roaming a parallel universe, you discover...Ch. 2 - Identify the group and period for each of the...Ch. 2 - Prob. 2.58QPCh. 2 - Prob. 2.59QPCh. 2 - Prob. 2.60QPCh. 2 - Prob. 2.61QPCh. 2 - Prob. 2.62QPCh. 2 - The normal form of the element sulfur is a...Ch. 2 - White phosphorus is available in sticks, which...Ch. 2 - A 4.19-g sample of nitrous oxide (an anesthetic,...Ch. 2 - Nitric acid is composed of HNO3 molecules. A...Ch. 2 - A sample of ammonia, NH3, contains 1.2 1023...Ch. 2 - A sample of ethanol (ethyl alcohol), C2H3OH,...Ch. 2 - Prob. 2.69QPCh. 2 - What molecular formula corresponds to each of the...Ch. 2 - Prob. 2.71QPCh. 2 - Prob. 2.72QPCh. 2 - Prob. 2.73QPCh. 2 - Ammonium phosphate, (NH4)3PO4, has how many oxygen...Ch. 2 - Prob. 2.75QPCh. 2 - Prob. 2.76QPCh. 2 - Name the following compounds. a Na2SO4 b Na3N c...Ch. 2 - Name the following compounds. a CaO b Mn2O3 c...Ch. 2 - Prob. 2.79QPCh. 2 - Prob. 2.80QPCh. 2 - Prob. 2.81QPCh. 2 - For each of the following binary compounds, decide...Ch. 2 - Give systematic names to the following binary...Ch. 2 - Prob. 2.84QPCh. 2 - Prob. 2.85QPCh. 2 - Prob. 2.86QPCh. 2 - Prob. 2.87QPCh. 2 - Prob. 2.88QPCh. 2 - Prob. 2.89QPCh. 2 - Give the name and formula of the acid...Ch. 2 - Prob. 2.91QPCh. 2 - Prob. 2.92QPCh. 2 - Prob. 2.93QPCh. 2 - Prob. 2.94QPCh. 2 - For the balanced chemical equation Ca(NO3)2 +...Ch. 2 - In the equation 2PbS + O2 2PbO + 2SO2, how many...Ch. 2 - Balance the following equations. a Sn + NaOH ...Ch. 2 - Balance the following equations. a Ca3(PO4)2 +...Ch. 2 - Prob. 2.99QPCh. 2 - Solid sodium metal reacts with water, giving a...Ch. 2 - Prob. 2.101QPCh. 2 - Prob. 2.102QPCh. 2 - Two samples of different compounds of nitrogen and...Ch. 2 - Two samples of different compounds of sulfur and...Ch. 2 - In a series of oil-drop experiments, the charges...Ch. 2 - In a hypothetical universe, an oil-drop experiment...Ch. 2 - Compounds of europium. Eu, are used to make color...Ch. 2 - Cesium, Cs, is used in photoelectric cells...Ch. 2 - Prob. 2.109QPCh. 2 - One isotope of a metallic element has mass number...Ch. 2 - Obtain the fractional abundances for the two...Ch. 2 - Silver has two naturally occurring isotopes, one...Ch. 2 - Prob. 2.113QPCh. 2 - Prob. 2.114QPCh. 2 - Prob. 2.115QPCh. 2 - Prob. 2.116QPCh. 2 - Prob. 2.117QPCh. 2 - Prob. 2.118QPCh. 2 - Name the following compounds. a Sn3(PO4)2 b NH4NO2...Ch. 2 - Name the following compounds. a Cu(NO2)3 b (NH4)3P...Ch. 2 - Prob. 2.121QPCh. 2 - Prob. 2.122QPCh. 2 - Prob. 2.123QPCh. 2 - Name the following molecular compounds a ClF4 b...Ch. 2 - Prob. 2.125QPCh. 2 - Balance the following equations. a NaOH + H2CO3 ...Ch. 2 - A monatomic ion has a charge of +4. The nucleus of...Ch. 2 - A monatomic ion has a charge of +1. The nucleus of...Ch. 2 - Natural carbon, which has an atomic weight of...Ch. 2 - A sample of natural chlorine, has an atomic weight...Ch. 2 - Prob. 2.131QPCh. 2 - Prob. 2.132QPCh. 2 - Prob. 2.133QPCh. 2 - Prob. 2.134QPCh. 2 - Prob. 2.135QPCh. 2 - Ammonia gas reacts with molecular oxygen gas to...Ch. 2 - A hypothetical element X is found to have an...Ch. 2 - A monotomic ion has a charge of +3. The nucleus of...Ch. 2 - A small crystal of CaCl2 that weighs 0.12 g...Ch. 2 - Prob. 2.140QPCh. 2 - Prob. 2.141QPCh. 2 - The IO3, anion is called iodate. There are three...Ch. 2 - Prob. 2.143QPCh. 2 - From the following written description, write the...Ch. 2 - Prob. 2.145QPCh. 2 - Name the following compounds: a HCl(g) b HBr(aq) c...Ch. 2 - During nuclear decay a 238U atom can break apart...Ch. 2 - Prob. 2.148QPCh. 2 - There are 2.619 1022 atoms in 1.000 g of sodium....Ch. 2 - There are 1.699 1022 atoms in 1.000 g of...Ch. 2 - A sample of green crystals of nickel(II) sulfate...Ch. 2 - Cobalt(II) sulfate heptahydrate has pink-colored...Ch. 2 - A sample of metallic element X, weighing 3.177 g,...Ch. 2 - A sample of metallic element X, weighing 4.315 g,...Ch. 2 - Prob. 2.156QPCh. 2 - The element europium exists in nature as two...
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