The given ionic compound has to be named. Concept Introduction: An ionic compound is named in a way that the cation name follows the anion. The stem name of the ionic compound is the name of the anion present in it. Metals form cation and it is named with the oxidation state and the name of the metal. The anionic part is named as per the element present in it and the charge on the anion. When both cation and anion are considered as monoatomic ions, then the charge on the ion is derived for anion by subtracting 8 from the group number in which the element is present. Cations are named by using roman letter next to the name of the metal, where the roman letter denotes the oxidation state of the metal.

Question

Shown below are five NMR spectra for five different C6H10O2 compounds. For each spectrum, draw the structure of the compound, and assign the spectrum by labeling H's in your structure (or in a second drawing of the structure) with the chemical shifts of the corresponding signals (which can be estimated to nearest 0.1 ppm). IR information is also provided. As a reminder, a peak near 1700 cm-1 is consistent with the presence of a carbonyl (C=O), and a peak near 3300 cm-1 is consistent with the presence of an O–H. Extra information: For C6H10O2 , there must be either 2 double bonds, or 1 triple bond, or two rings to account for the unsaturation. There is no two rings for this problem. A strong band was observed in the IR at 1717 cm-1

Answer 1

Question

Chapter 2.8, Problem 2.5E

(a)

Interpretation Introduction

Interpretation:

The given ionic compound has to be named.

Concept Introduction:

An ionic compound is named in a way that the cation name follows the anion. The stem name of the ionic compound is the name of the anion present in it. Metals form cation and it is named with the oxidation state and the name of the metal. The anionic part is named as per the element present in it and the charge on the anion. When both cation and anion are considered as monoatomic ions, then the charge on the ion is derived for anion by subtracting 8 from the group number in which the element is present. Cations are named by using roman letter next to the name of the metal, where the roman letter denotes the oxidation state of the metal.

(b)

Interpretation Introduction

Interpretation:

The given ionic compound has to be named.

Concept Introduction:

An ionic compound is named in a way that the cation name follows the anion. The stem name of the ionic compound is the name of the anion present in it. Metals form cation and it is named with the oxidation state and the name of the metal. The anionic part is named as per the element present in it and the charge on the anion. When both cation and anion are considered as monoatomic ions, then the charge on the ion is derived for anion by subtracting 8 from the group number in which the element is present. Cations are named by using roman letter next to the name of the metal, where the roman letter denotes the oxidation state of the metal.

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