The mechanism for the given Carroll rearrangement reaction is to be drawn. Concept introduction: Carroll rearrangement is a reaction in which β − keto ester reacts with allylic alcohol in the presence of base to give unsaturated carbonyl compound. In the sigmatropic rearrangement, the rearrangement of pi bond and the breaking of sigma bond take place. This results in the generation of new sigma bond in the product. In this type of rearrangement, the number of pi bonds remains constant in the reactant as well as in the product.

Question

Want to see the full answer?

Answer 1

Question

Chapter 27, Problem 27.57P

Interpretation Introduction

Interpretation: The mechanism for the given Carroll rearrangement reaction is to be drawn.

Concept introduction: Carroll rearrangement is a reaction in which β−keto ester reacts with allylic alcohol in the presence of base to give unsaturated carbonyl compound.

In the sigmatropic rearrangement, the rearrangement of pi bond and the breaking of sigma bond take place. This results in the generation of new sigma bond in the product. In this type of rearrangement, the number of pi bonds remains constant in the reactant as well as in the product.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Retro aldol: NaOH H₂O H NaOH & d H₂O H

Draw the product of the reaction shown below. Ignore inorganic byproducts. H conc. HBr Drawing Q

Calculate the atomic packing factor of diamond knowing that the number of Si atoms per cm3 is 2.66·1022 and that the atomic radii of silicon and oxygen are, respectively, 0.038 and 0.117 nm.

Answer 2

Question

Chapter 27, Problem 27.57P

Interpretation Introduction

Interpretation: The mechanism for the given Carroll rearrangement reaction is to be drawn.

Concept introduction: Carroll rearrangement is a reaction in which β−keto ester reacts with allylic alcohol in the presence of base to give unsaturated carbonyl compound.

In the sigmatropic rearrangement, the rearrangement of pi bond and the breaking of sigma bond take place. This results in the generation of new sigma bond in the product. In this type of rearrangement, the number of pi bonds remains constant in the reactant as well as in the product.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 27, Problem 27.57P

Interpretation Introduction

Interpretation: The mechanism for the given Carroll rearrangement reaction is to be drawn.

Concept introduction: Carroll rearrangement is a reaction in which β−keto ester reacts with allylic alcohol in the presence of base to give unsaturated carbonyl compound.

In the sigmatropic rearrangement, the rearrangement of pi bond and the breaking of sigma bond take place. This results in the generation of new sigma bond in the product. In this type of rearrangement, the number of pi bonds remains constant in the reactant as well as in the product.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 27, Problem 27.57P

Interpretation Introduction

Interpretation: The mechanism for the given Carroll rearrangement reaction is to be drawn.

Concept introduction: Carroll rearrangement is a reaction in which β−keto ester reacts with allylic alcohol in the presence of base to give unsaturated carbonyl compound.

In the sigmatropic rearrangement, the rearrangement of pi bond and the breaking of sigma bond take place. This results in the generation of new sigma bond in the product. In this type of rearrangement, the number of pi bonds remains constant in the reactant as well as in the product.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 27, Problem 27.57P

Interpretation Introduction

Interpretation: The mechanism for the given Carroll rearrangement reaction is to be drawn.

Concept introduction: Carroll rearrangement is a reaction in which β−keto ester reacts with allylic alcohol in the presence of base to give unsaturated carbonyl compound.

In the sigmatropic rearrangement, the rearrangement of pi bond and the breaking of sigma bond take place. This results in the generation of new sigma bond in the product. In this type of rearrangement, the number of pi bonds remains constant in the reactant as well as in the product.

Answer 6

Chapter 27, Problem 27.57P

Interpretation Introduction

Interpretation: The mechanism for the given Carroll rearrangement reaction is to be drawn.

Concept introduction: Carroll rearrangement is a reaction in which β−keto ester reacts with allylic alcohol in the presence of base to give unsaturated carbonyl compound.

In the sigmatropic rearrangement, the rearrangement of pi bond and the breaking of sigma bond take place. This results in the generation of new sigma bond in the product. In this type of rearrangement, the number of pi bonds remains constant in the reactant as well as in the product.

Answer 7

Chapter 27, Problem 27.57P

Interpretation Introduction

Interpretation: The mechanism for the given Carroll rearrangement reaction is to be drawn.

Concept introduction: Carroll rearrangement is a reaction in which β−keto ester reacts with allylic alcohol in the presence of base to give unsaturated carbonyl compound.

In the sigmatropic rearrangement, the rearrangement of pi bond and the breaking of sigma bond take place. This results in the generation of new sigma bond in the product. In this type of rearrangement, the number of pi bonds remains constant in the reactant as well as in the product.

Answer 8

Expert Solution & Answer

Answer 9

Expert Solution & Answer

Answer 10

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 11

Ch. 27 - Prob. 27.1P Ch. 27 - Problem 27.2 For each molecular orbital in Figure...Ch. 27 - Problem 27.3 (a) Using Figure 27.2 as a guide,...Ch. 27 - Problem 27.4 (a) How many molecular orbitals are...Ch. 27 - Prob. 27.5P Ch. 27 - Prob. 27.6P Ch. 27 - Prob. 27.7P Ch. 27 - Prob. 27.8P Ch. 27 - Prob. 27.9P Ch. 27 - Prob. 27.10P

Solution Summary: The author explains that the mechanism for the given Carroll rearrangement reaction is shown in Figure 1.

Concept explainers

Want to see the full answer?

Chapter 27 Solutions