Organic Chemistry-Package(Custom)
Organic Chemistry-Package(Custom)
4th Edition
ISBN: 9781259141089
Author: SMITH
Publisher: MCG
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Chapter 27, Problem 27.23P
Interpretation Introduction

(a)

Interpretation: The product formed from Claisen rearrangement of given starting material is to be predicted.

Concept introduction: Claisen rearrangement is a thermal [3,3] sigmatropic rearrangement. This rearrangement takes place in allyl vinyl ether to form γ,δ-carbonyl compound.

Sigmatropic rearrangements are pericyclic reactions which takes place by concerted mechanism. In these rearrangements migration of sigma bond takes place.

Interpretation Introduction

(b)

Interpretation: The product formed from Claisen rearrangement of given starting material is to be predicted.

Concept introduction: Claisen rearrangement is a thermal [3,3] sigmatropic rearrangement. This rearrangement takes place in allyl vinyl ether to form γ,δ-carbonyl compound.

Sigmatropic rearrangements are pericyclic reactions which takes place by concerted mechanism. In these rearrangements migration of sigma bond takes place.

Interpretation Introduction

(c)

Interpretation: The product formed from Claisen rearrangement of given starting material is to be predicted.

Concept introduction: Claisen rearrangement is a thermal [3,3] sigmatropic rearrangement. This rearrangement takes place in allyl vinyl ether to form γ,δ-carbonyl compound.

Sigmatropic rearrangements are pericyclic reactions which takes place by concerted mechanism. In these rearrangements migration of sigma bond takes place.

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Chapter 27 Solutions

Organic Chemistry-Package(Custom)

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