The Fischer projection formula of (S)-proline is to be given. Concept introduction: In Fischer projection formula, the amino acid molecule is represented by placing the COO- group on the top of the chiral carbon. The configuration in which the NH 3 + group is placed on right is said to be D configuration while that which has NH 3 + group on the left is called to have L configuration. Based on sequence rules, the four groups attached to the chiral carbon are arranged in the order of priorities. While viewing the molecule from the side far away from the group of lowest priority, if the arrangement of first highest priority, second highest priority and third highest priority is clockwise the molecule is said to have R configuration and if the arrangement is anti-clockwise the molecule is said to have S configuration. To draw: The Fischer projection formula of (S)-proline.

Question

Given the first-order reaction: aA → products. State its kinetic equation.

Answer 1

Question

Chapter 26.SE, Problem 31AP

Interpretation Introduction

Interpretation:

The Fischer projection formula of (S)-proline is to be given.

Concept introduction:

In Fischer projection formula, the amino acid molecule is represented by placing the COO- group on the top of the chiral carbon. The configuration in which the NH₃⁺ group is placed on right is said to be D configuration while that which has NH₃⁺ group on the left is called to have L configuration.

Based on sequence rules, the four groups attached to the chiral carbon are arranged in the order of priorities. While viewing the molecule from the side far away from the group of lowest priority, if the arrangement of first highest priority, second highest priority and third highest priority is clockwise the molecule is said to have R configuration and if the arrangement is anti-clockwise the molecule is said to have S configuration.

To draw:

The Fischer projection formula of (S)-proline.

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Answer 2

Question

Chapter 26.SE, Problem 31AP

Interpretation Introduction

Interpretation:

The Fischer projection formula of (S)-proline is to be given.

Concept introduction:

In Fischer projection formula, the amino acid molecule is represented by placing the COO- group on the top of the chiral carbon. The configuration in which the NH₃⁺ group is placed on right is said to be D configuration while that which has NH₃⁺ group on the left is called to have L configuration.

Based on sequence rules, the four groups attached to the chiral carbon are arranged in the order of priorities. While viewing the molecule from the side far away from the group of lowest priority, if the arrangement of first highest priority, second highest priority and third highest priority is clockwise the molecule is said to have R configuration and if the arrangement is anti-clockwise the molecule is said to have S configuration.

To draw:

The Fischer projection formula of (S)-proline.

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Answer 3

Question

Chapter 26.SE, Problem 31AP

Interpretation Introduction

Interpretation:

The Fischer projection formula of (S)-proline is to be given.

Concept introduction:

In Fischer projection formula, the amino acid molecule is represented by placing the COO- group on the top of the chiral carbon. The configuration in which the NH₃⁺ group is placed on right is said to be D configuration while that which has NH₃⁺ group on the left is called to have L configuration.

Based on sequence rules, the four groups attached to the chiral carbon are arranged in the order of priorities. While viewing the molecule from the side far away from the group of lowest priority, if the arrangement of first highest priority, second highest priority and third highest priority is clockwise the molecule is said to have R configuration and if the arrangement is anti-clockwise the molecule is said to have S configuration.

To draw:

The Fischer projection formula of (S)-proline.

Expert Solution & Answer

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Answer 4

Question

Chapter 26.SE, Problem 31AP

Interpretation Introduction

Interpretation:

The Fischer projection formula of (S)-proline is to be given.

Concept introduction:

In Fischer projection formula, the amino acid molecule is represented by placing the COO- group on the top of the chiral carbon. The configuration in which the NH₃⁺ group is placed on right is said to be D configuration while that which has NH₃⁺ group on the left is called to have L configuration.

Based on sequence rules, the four groups attached to the chiral carbon are arranged in the order of priorities. While viewing the molecule from the side far away from the group of lowest priority, if the arrangement of first highest priority, second highest priority and third highest priority is clockwise the molecule is said to have R configuration and if the arrangement is anti-clockwise the molecule is said to have S configuration.

To draw:

The Fischer projection formula of (S)-proline.

Expert Solution & Answer

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Answer 5

Chapter 26.SE, Problem 31AP

Interpretation Introduction

Interpretation:

The Fischer projection formula of (S)-proline is to be given.

Concept introduction:

In Fischer projection formula, the amino acid molecule is represented by placing the COO- group on the top of the chiral carbon. The configuration in which the NH₃⁺ group is placed on right is said to be D configuration while that which has NH₃⁺ group on the left is called to have L configuration.

Based on sequence rules, the four groups attached to the chiral carbon are arranged in the order of priorities. While viewing the molecule from the side far away from the group of lowest priority, if the arrangement of first highest priority, second highest priority and third highest priority is clockwise the molecule is said to have R configuration and if the arrangement is anti-clockwise the molecule is said to have S configuration.

To draw:

The Fischer projection formula of (S)-proline.

Answer 6

Chapter 26.SE, Problem 31AP

Interpretation Introduction

Interpretation:

The Fischer projection formula of (S)-proline is to be given.

Concept introduction:

In Fischer projection formula, the amino acid molecule is represented by placing the COO- group on the top of the chiral carbon. The configuration in which the NH₃⁺ group is placed on right is said to be D configuration while that which has NH₃⁺ group on the left is called to have L configuration.

Based on sequence rules, the four groups attached to the chiral carbon are arranged in the order of priorities. While viewing the molecule from the side far away from the group of lowest priority, if the arrangement of first highest priority, second highest priority and third highest priority is clockwise the molecule is said to have R configuration and if the arrangement is anti-clockwise the molecule is said to have S configuration.

To draw:

The Fischer projection formula of (S)-proline.

Answer 7

Chapter 26.SE, Problem 31AP

Interpretation Introduction

Interpretation:

The Fischer projection formula of (S)-proline is to be given.

Concept introduction:

In Fischer projection formula, the amino acid molecule is represented by placing the COO- group on the top of the chiral carbon. The configuration in which the NH₃⁺ group is placed on right is said to be D configuration while that which has NH₃⁺ group on the left is called to have L configuration.

Based on sequence rules, the four groups attached to the chiral carbon are arranged in the order of priorities. While viewing the molecule from the side far away from the group of lowest priority, if the arrangement of first highest priority, second highest priority and third highest priority is clockwise the molecule is said to have R configuration and if the arrangement is anti-clockwise the molecule is said to have S configuration.

To draw:

The Fischer projection formula of (S)-proline.

Answer 8

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Ch. 26.1 - How many of the -amino acids shown in Table 26-1...Ch. 26.1 - Prob. 2P Ch. 26.1 - Prob. 3P Ch. 26.2 - Hemoglobin has pI=6.8. Does hemoglobin have a net...Ch. 26.3 - Show how you could prepare the following -amino...Ch. 26.3 - What alkyl halides would you use to prepare the...Ch. 26.3 - Prob. 7P Ch. 26.4 - There are six isomeric tripeptides that contain...Ch. 26.4 - Draw the structure of M-P-V-G, and indicate its...Ch. 26.5 - Prob. 10P

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Chapter 26 Solutions