ORGANIC CHEMISTRY-ACCESS
6th Edition
ISBN: 9781260475586
Author: SMITH
Publisher: MCG
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Chapter 26.3, Problem 7P
Interpretation Introduction
Interpretation: The number of different aldoheptoses and the number of D-sugars are to be predicted. All D-aldoheptoses that have R-configuration at
Concept introduction: A monosaccharide in which
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Chapter 26 Solutions
ORGANIC CHEMISTRY-ACCESS
Ch. 26.2 - Prob. 1PCh. 26.2 - Prob. 2PCh. 26.2 - Label each stereogenic center as R or S. a. b. c....Ch. 26.2 - Convert the ball-and-stick model to a Fischer...Ch. 26.2 - Prob. 5PCh. 26.2 - Prob. 6PCh. 26.3 - Prob. 7PCh. 26.3 - Prob. 8PCh. 26.4 - Prob. 9PCh. 26.4 - Prob. 10P
Ch. 26.6 - Prob. 11PCh. 26.6 - Prob. 12PCh. 26.6 - Prob. 13PCh. 26.6 - Prob. 14PCh. 26.6 - Prob. 15PCh. 26.7 - Prob. 16PCh. 26.7 - Draw a stepwise mechanism for the following...Ch. 26.7 - Prob. 18PCh. 26.8 - Prob. 19PCh. 26.9 - Prob. 20PCh. 26.9 - Prob. 21PCh. 26.9 - Draw the products formed when D-arabinose is...Ch. 26.9 - Prob. 23PCh. 26.10 - Prob. 24PCh. 26.10 - Prob. 25PCh. 26.10 - Prob. 26PCh. 26.10 - Prob. 27PCh. 26.11 - Prob. 28PCh. 26.11 - Prob. 29PCh. 26.12 - Prob. 30PCh. 26.12 - Prob. 31PCh. 26.13 - Prob. 32PCh. 26.13 - Prob. 33PCh. 26.13 - Problem-28.35
Draw the structures of the...Ch. 26.13 - Prob. 35PCh. 26 - 28.37 Convert each ball-and-stick model to a...Ch. 26 - Prob. 37PCh. 26 - Prob. 38PCh. 26 - 28.40 Convert each compound to a Fischer...Ch. 26 - Prob. 40PCh. 26 - Prob. 41PCh. 26 - 28.43 Draw a Haworth projection for each compound...Ch. 26 - Prob. 43PCh. 26 - 28.45 Draw both pyranose anomers of each...Ch. 26 - Prob. 45PCh. 26 - 28.50 Draw the products formed when D-altrose is...Ch. 26 - 28.58 Draw a stepwise mechanism for the following...Ch. 26 - Prob. 62PCh. 26 - Prob. 63PCh. 26 - Prob. 64PCh. 26 - Prob. 65PCh. 26 - Prob. 66PCh. 26 - Prob. 67PCh. 26 - Prob. 68PCh. 26 - Prob. 69PCh. 26 - Prob. 70P
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- 1. Which of the following is not true to the monosaccharide below? H. ОН но- -H- но ОН ĆH2OH O It is the Fischer Projection of D-glucose. It is an aldohexose having 4 chiral centers and 24 stereoisomers. It is has a D-glucose because OH- group bonded to the highest numbered chiral C is pointing to the right. It is a polyhydroxy ketone having 8 enantiomeric pair.arrow_forwardConsider only the top monosaccharide chair conformation. How would I draw the Fischer projection of the aldohexose from which this chair conformation is derived? And is the diaccharide shown reducing, non-reducing, or can that not be determined?arrow_forwardA Fischer projection of a monosaccharide is shown below: Classify this monosaccharide (e.g., aldotriose) Does it have the D or L configuration? Which carbon and oxygen become bonded in the furanose ring form of this monosaccharide (e.g., C2O6, where O6 means the oxygen on carbon 6, or "not formed")? Which carbon and oxygen become bonded in the pyranose ring form of this monosaccharide e.g., C2O6 or "not formed"?arrow_forward
- Draw the structures (using chair conformations of pyranoses) of the following disaccharides. a-d-fructofuranosyl-b-d-mannopyranoside(arrow_forwardTrehalose and isomaltose are both dimers of glucose. However, they have considerablydifferent reactivities. Concisely explain why these differences are observed.arrow_forwardi need an answer pleaseeeearrow_forward
- A disaccharide is shown below. For part (a), circle the anomeric carbon atoms. For part (b), explain whether it is a reducing sugar or non-reducing sugar.arrow_forwardWhich one is b-D glucose and which one is a-L glucose ? 2. Which one is b-fructose and which a-L fructose?arrow_forwardI) Draw a proper Fischer projection for the following molecule. Assign each stereogenic carbon as either (R) or (S) and determine if the molecule is either a (D) or (L)-sugar, is this aldose or ketose? ОН он он ОНarrow_forward
- Are digitoxin / digoxin composed of one type or more than one type of monosaccharide? How are the monosaccharide derivatives of digitoxin / digoxin classified (alcohol sugar, deoxy sugar, amino sugar, carboxylic acid sugar)? Are the monosaccharides furanose or pyranose rings?arrow_forwarda) Which of the following monosaccharides will react with Tollens' reagent? Circle all that apply. СООН CH2OH CH2OH OCH3 но- H- O: OH но H- но—н OH ČH2OH ČH2OH ÓH II III IV V b) Which of the following carbohydrates is sucrose? OH OH OH но OH HO, O. OH "OH HO OH Он HO OH II I HO, HO. Он HO, HO. HO, OH Но Он но. OH HO,, HO, OH HOl HO OH но он III Он HO IV HO ноarrow_forwardCan you please solve this question for me?arrow_forward
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