The structures of A and B are to be predicted. Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C 2 of a product.

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Answer 1

Question

Chapter 26.10, Problem 27P

Interpretation Introduction

Interpretation: The structures of A and B are to be predicted.

Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.

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A D-aldohexose A is formed from an aldopentose B by the Kiliani-Fischer synthesis. Reduction of A with NABH4 forms an optically inactive alditol. Oxidation of B forms an optically active aldaric acid. What are the structures of A and B?

A D-aldopentose A is reduced to an optically active alditol. Upon Kiliani–Fischer synthesis, A is converted to two Daldohexoses, B and C. B is oxidized to an optically inactive aldaric acid. C is oxidized to an optically active aldaric acid. What are the structures of A–C?

Cellobiose, a disaccharide obtained by the hydrolysis of cellulose, is composed of two glucose units joined together in a 1→4-β-glycoside bond. What is the structure of cellobiose?

Answer 2

Question

Chapter 26.10, Problem 27P

Interpretation Introduction

Interpretation: The structures of A and B are to be predicted.

Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.

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Answer 3

Question

Chapter 26.10, Problem 27P

Interpretation Introduction

Interpretation: The structures of A and B are to be predicted.

Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.

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Answer 4

Question

Chapter 26.10, Problem 27P

Interpretation Introduction

Interpretation: The structures of A and B are to be predicted.

Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.

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Answer 5

Chapter 26.10, Problem 27P

Interpretation Introduction

Interpretation: The structures of A and B are to be predicted.

Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.

Answer 6

Chapter 26.10, Problem 27P

Interpretation Introduction

Interpretation: The structures of A and B are to be predicted.

Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.

Answer 7

Chapter 26.10, Problem 27P

Interpretation Introduction

Interpretation: The structures of A and B are to be predicted.

Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 26.2 - Prob. 1P Ch. 26.2 - Prob. 2P Ch. 26.2 - Label each stereogenic center as R or S. a. b. c....Ch. 26.2 - Convert the ball-and-stick model to a Fischer...Ch. 26.2 - Prob. 5P Ch. 26.2 - Prob. 6P Ch. 26.3 - Prob. 7P Ch. 26.3 - Prob. 8P Ch. 26.4 - Prob. 9P Ch. 26.4 - Prob. 10P

The structures of A and B are to be predicted. Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C 2 of a product.

Solution Summary: The author explains Kiliani–Fischer synthesis, which is used for the elongation of the carbon chain in aldoses.

Concept explainers

Interpretation: The structures of A and B are to be predicted.

Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.

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Chapter 26 Solutions

The structures of A and B are to be predicted. Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C 2 of a product.

Solution Summary: The author explains Kiliani–Fischer synthesis, which is used for the elongation of the carbon chain in aldoses.

Concept explainers

Interpretation: The structures of A and B are to be predicted. Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.

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Chapter 26 Solutions

Interpretation: The structures of A and B are to be predicted.

Concept introduction: Kiliani–Fischer synthesis is a method which is used for the elongation of the carbon chain in aldoses. In this method, the aldose chain is elongated by the formation of new stereogenic centre at C2 of a product.