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Concept explainers
(a)
Interpretation:
The hybridization of carbon atom, total C-C σ bonds and π bonds with 1â—¦,2â—¦,3â—¦ and 4â—¦ carbon atoms should be determined.
Concept introduction:
Hybridization is the process of mixing of atomic orbitals to form same energy and same shape hybrid orbitals which form covalent bond with overlapping of atomic orbitals of other atoms. The number of
1â—¦ orPrimary C atom = C atom which is bonded with one another C atom
2â—¦ orSecondary C atom= C atom which is bonded with two other C atoms
3â—¦ orTertiary C atom= C atom which is bonded with three other C atoms
4â—¦ or Quaternary C atom= C atom which is bonded with four other C atoms
(b)
Interpretation:
The hybridization of carbon atom, total C-C σ bonds and π bonds with 1â—¦, 2â—¦,3â—¦ and 4â—¦ carbon atoms should be determined.
Concept introduction:
Hybridization is the process of mixing of atomic orbitals to form same energy and same shape hybrid orbitals which form covalent bond with overlapping of atomic orbitals of other atoms. The number of chemical bonds formed by the atom always determine type of hybridization. Sigma bonds could only form by hybrid orbitals whereas pi bonds are always formed by overlapping of un-hybrid orbitals hence hybridization is not part of pi bond formation.
1â—¦ or Primary C atom = C atom which is bonded with one another C atom
2â—¦ or Secondary C atom= C atom which is bonded with two other C atoms
3â—¦ or Tertiary C atom= C atom which is bonded with three other C atoms
4â—¦ or Quaternary C atom= C atom which is bonded with four other C atoms
(c)
Interpretation:
The hybridization of carbon atom, total C-C σ bonds and π bonds with 1â—¦, 2â—¦,3â—¦ and 4â—¦ carbon atoms should be determined.
Concept introduction:
Hybridization is the process of mixing of atomic orbitals to form same energy and same shape hybrid orbitals which form covalent bond with overlapping of atomic orbitals of other atoms. The number of chemical bonds formed by the atom always determine type of hybridization. Sigma bonds could only form by hybrid orbitals whereas pi bonds are always formed by overlapping of un-hybrid orbitals hence hybridization is not part of pi bond formation.
1â—¦ or Primary C atom = C atom which is bonded with one another C atom
2â—¦ or Secondary C atom= C atom which is bonded with two other C atoms
3â—¦ or Tertiary C atom= C atom which is bonded with three other C atoms
4â—¦ or Quaternary C atom= C atom which is bonded with four other C atoms
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Chapter 26 Solutions
GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
- 1 2 3 4 I(aq) +OCl(aq) → IO¯¯(aq) + Cl¯(aq) Experiment [I-] M 0.005 [OCI-] 0.005 Initial Rate M/min 0.000275 0.0025 0.005 0.000138 0.0025 0.0025 Calculate the overall order of this reaction using the table data. 0.0025 0.000069 0.0025 0.000140arrow_forwardH2O2(aq) +3 I¯(aq) +2 H+(aq) → 13(aq) +2 H₂O(l)· ••• Experiment [H2 O2]o (M) [I]o (M) [H+]。 (M) Initial rate (M/s) 1 0.15 0.15 0.05 0.00012 234 0.15 0.3 0.05 0.00024 0.3 0.15 0.05 0.00024 0.15 0.15 0.1 0.00048 Calculate the overall order of this reaction using the table data.arrow_forwardThe U. S. Environmental Protection Agency (EPA) sets limits on healthful levels of air pollutants. The maximum level that the EPA considers safe for lead air pollution is 1.5 μg/m³ Part A If your lungs were filled with air containing this level of lead, how many lead atoms would be in your lungs? (Assume a total lung volume of 5.40 L.) ΜΕ ΑΣΦ = 2.35 1013 ? atoms ! Check your rounding. Your final answer should be rounded to 2 significant figures in the last step. No credit lost. Try again.arrow_forward
- Y= - 0.039 (14.01) + 0.7949arrow_forwardSuppose 1.76 g of magnesium acetate (Mg (CH3CO2)2) are dissolved in 140. mL of water. Find the composition of the resulting electrolyte solution. In particular, list the chemical symbols (including any charge) of each dissolved ion in the table below. List only one ion per row. mEq Then, calculate the concentration of each ion in dwrite the concentration in the second column of each row. Be sure you round your answers to the L correct number of significant digits. ion Add Row mEq L x 5arrow_forwardA pdf file of your hand drawn, stepwise mechanisms for the reactions. For each reaction in the assignment, you must write each mechanism three times (there are 10 reactions, so 30 mechanisms). (A) do the work on a tablet and save as a pdf., it is expected to write each mechanism out and NOT copy and paste the mechanism after writing it just once. Everything should be drawn out stepwise and every bond that is formed and broken in the process of the reaction, and is expected to see all relevant lone pair electrons and curved arrows.arrow_forward
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
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