(a) Interpretation: The following reaction is to be balanced using the half reaction method- C 6 H 5 N O 2 + F e + H + → C 6 H 5 N H 3 + + F e 3 + + H 2 O Concept introduction: Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously. Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

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Answer 1

Question

Chapter 26, Problem 79IAE

Interpretation Introduction

(a)

Interpretation:

The following reaction is to be balanced using the half reaction method-

C6H5NO2+Fe+H+→C6H5NH3++Fe3++H2O

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

Interpretation Introduction

(b)

Interpretation:

The following reaction is to be balanced using the half reaction method-

C6H5CH2OH+Cr2O72−+H+→C6H5CO2H+Cr3++H2O

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

Interpretation Introduction

(c)

Interpretation:

The following reaction is to be balanced using the half reaction method-

CH3CH=CH2+MnO4−+H2O→CH3CHOHCH2OH+MnO2+OH−

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.

Part V. Draw the structure of compound tecla using the IR spectrum Cobtained from the compound in KBr pellet) and the mass spectrum as shown below. The mass spectrum of compound Tesla showed strong mt peak at 71. TRANSMITTANCE LOD Relative Intensity 100 MS-NW-1539 40 20 80 T 44 55 10 15 20 25 30 35 40 45 50 55 60 65 70 75 m/z D 4000 3000 2000 1500 1000 500 HAVENUMBERI-11

Answer 2

Question

Chapter 26, Problem 79IAE

Interpretation Introduction

(a)

Interpretation:

The following reaction is to be balanced using the half reaction method-

C6H5NO2+Fe+H+→C6H5NH3++Fe3++H2O

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

Interpretation Introduction

(b)

Interpretation:

The following reaction is to be balanced using the half reaction method-

C6H5CH2OH+Cr2O72−+H+→C6H5CO2H+Cr3++H2O

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

Interpretation Introduction

(c)

Interpretation:

The following reaction is to be balanced using the half reaction method-

CH3CH=CH2+MnO4−+H2O→CH3CHOHCH2OH+MnO2+OH−

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

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Answer 3

Question

Chapter 26, Problem 79IAE

Interpretation Introduction

(a)

Interpretation:

The following reaction is to be balanced using the half reaction method-

C6H5NO2+Fe+H+→C6H5NH3++Fe3++H2O

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

Interpretation Introduction

(b)

Interpretation:

The following reaction is to be balanced using the half reaction method-

C6H5CH2OH+Cr2O72−+H+→C6H5CO2H+Cr3++H2O

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

Interpretation Introduction

(c)

Interpretation:

The following reaction is to be balanced using the half reaction method-

CH3CH=CH2+MnO4−+H2O→CH3CHOHCH2OH+MnO2+OH−

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

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Answer 4

Question

Chapter 26, Problem 79IAE

Interpretation Introduction

(a)

Interpretation:

The following reaction is to be balanced using the half reaction method-

C6H5NO2+Fe+H+→C6H5NH3++Fe3++H2O

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

Interpretation Introduction

(b)

Interpretation:

The following reaction is to be balanced using the half reaction method-

C6H5CH2OH+Cr2O72−+H+→C6H5CO2H+Cr3++H2O

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

Interpretation Introduction

(c)

Interpretation:

The following reaction is to be balanced using the half reaction method-

CH3CH=CH2+MnO4−+H2O→CH3CHOHCH2OH+MnO2+OH−

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

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Answer 5

Chapter 26, Problem 79IAE

Interpretation Introduction

(a)

Interpretation:

The following reaction is to be balanced using the half reaction method-

C6H5NO2+Fe+H+→C6H5NH3++Fe3++H2O

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

Interpretation Introduction

(b)

Interpretation:

The following reaction is to be balanced using the half reaction method-

C6H5CH2OH+Cr2O72−+H+→C6H5CO2H+Cr3++H2O

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

Interpretation Introduction

(c)

Interpretation:

The following reaction is to be balanced using the half reaction method-

CH3CH=CH2+MnO4−+H2O→CH3CHOHCH2OH+MnO2+OH−

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

Answer 6

Chapter 26, Problem 79IAE

Interpretation Introduction

(a)

Interpretation:

The following reaction is to be balanced using the half reaction method-

C6H5NO2+Fe+H+→C6H5NH3++Fe3++H2O

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

Answer 7

Chapter 26, Problem 79IAE

Interpretation Introduction

(a)

Interpretation:

The following reaction is to be balanced using the half reaction method-

C6H5NO2+Fe+H+→C6H5NH3++Fe3++H2O

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The following reaction is to be balanced using the half reaction method-

C6H5CH2OH+Cr2O72−+H+→C6H5CO2H+Cr3++H2O

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The following reaction is to be balanced using the half reaction method-

C6H5CH2OH+Cr2O72−+H+→C6H5CO2H+Cr3++H2O

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The following reaction is to be balanced using the half reaction method-

CH3CH=CH2+MnO4−+H2O→CH3CHOHCH2OH+MnO2+OH−

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The following reaction is to be balanced using the half reaction method-

CH3CH=CH2+MnO4−+H2O→CH3CHOHCH2OH+MnO2+OH−

Concept introduction:

Redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

Balancing of redox reaction can be done via half reaction method- in which the reaction is divided into two halves- Oxidation half and the reduction half. Both the half reactions are balanced separately and then after balancing, combined together such that electron lost is equal to electrons gained.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 26 - Prob. 1E Ch. 26 - Draw a structural formula for each of the...Ch. 26 - Prob. 3E Ch. 26 - Write structural formulas corresponding to these...Ch. 26 - Prob. 5E Ch. 26 - Prob. 6E Ch. 26 - Prob. 7E Ch. 26 - Prob. 8E Ch. 26 - What is the relationship, if any, between the...Ch. 26 - Prob. 10E

Solution Summary: The author explains that redox reactions are those in which one of the species is oxidized and the other is reduced simultaneously.

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Chapter 26 Solutions