Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357119303
Author: Bettelheim, Frederick A., Brown, William H., Campbell, Mary K., FARRELL, Shawn O., Torres, Omar
Publisher: Cengage Learning
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Chapter 26, Problem 63P
Interpretation Introduction
Interpretation: Whether oligomycin can be used as an antibacterial drug for people or not should be determined.
Concept Introduction: In the aerobic respiration, there are two steps mainly. Glycolysis is the first step that forms pyruvate. In the presence of oxygen means aerobic respiration, this pyruvate enters in the Krebs cycle and extracts energy in the form of electrons transfer.
The products of citric acid cycles act as precursors for electron transport chains and produces ATP as energy coins.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 26 Solutions
Introduction to General, Organic and Biochemistry
Ch. 26.1 - Prob. 26.1QCCh. 26.2 - Prob. 26.2QCCh. 26.3 - Prob. 26.3QCCh. 26.4 - Prob. 26.4QCCh. 26.5 - Prob. 26.5QCCh. 26.6 - Prob. 26.6QCCh. 26.7 - Prob. 26.7QCCh. 26.8 - Prob. 26.8QCCh. 26 - Prob. 1PCh. 26 - Prob. 2P
Ch. 26 - Prob. 3PCh. 26 - Prob. 4PCh. 26 - Prob. 5PCh. 26 - Prob. 6PCh. 26 - (a) How many membranes do mitochondria have? (b)...Ch. 26 - Prob. 8PCh. 26 - Prob. 9PCh. 26 - Prob. 10PCh. 26 - Prob. 11PCh. 26 - Prob. 12PCh. 26 - Prob. 13PCh. 26 - Prob. 14PCh. 26 - What kind of chemical bond exists between the...Ch. 26 - Prob. 16PCh. 26 - Which atoms in the flavin portion of FAD are...Ch. 26 - NAD+ has two ribose units in its structure; FAD...Ch. 26 - Prob. 19PCh. 26 - The ribitol in FAD is bound to phosphate. What is...Ch. 26 - What kind Of chemical bond exists between the...Ch. 26 - Prob. 22PCh. 26 - Prob. 23PCh. 26 - Prob. 24PCh. 26 - Prob. 25PCh. 26 - Prob. 26PCh. 26 - Prob. 27PCh. 26 - Prob. 28PCh. 26 - Prob. 29PCh. 26 - Prob. 30PCh. 26 - Prob. 31PCh. 26 - Prob. 32PCh. 26 - Prob. 33PCh. 26 - Prob. 34PCh. 26 - Prob. 35PCh. 26 - Prob. 36PCh. 26 - Prob. 37PCh. 26 - Prob. 38PCh. 26 - Prob. 39PCh. 26 - Prob. 40PCh. 26 - Prob. 41PCh. 26 - Prob. 42PCh. 26 - Prob. 43PCh. 26 - Prob. 44PCh. 26 - Prob. 45PCh. 26 - Prob. 46PCh. 26 - Prob. 47PCh. 26 - Prob. 48PCh. 26 - Prob. 49PCh. 26 - Prob. 50PCh. 26 - Prob. 51PCh. 26 - Prob. 52PCh. 26 - Prob. 53PCh. 26 - A hexose (C6) enters the common metabolic pathway...Ch. 26 - Prob. 55PCh. 26 - Prob. 56PCh. 26 - Prob. 57PCh. 26 - Prob. 58PCh. 26 - Prob. 59PCh. 26 - Prob. 60PCh. 26 - Prob. 61PCh. 26 - Prob. 62PCh. 26 - Prob. 63PCh. 26 - Prob. 64PCh. 26 - Prob. 65PCh. 26 - Prob. 66PCh. 26 - Prob. 67PCh. 26 - Prob. 68PCh. 26 - Prob. 69PCh. 26 - What is the basic difference in the functional...Ch. 26 - Prob. 71PCh. 26 - Prob. 72PCh. 26 - Prob. 73PCh. 26 - Prob. 74PCh. 26 - Prob. 75PCh. 26 - Prob. 76PCh. 26 - Prob. 77PCh. 26 - Prob. 78PCh. 26 - Prob. 79PCh. 26 - Prob. 80PCh. 26 - Prob. 81PCh. 26 - Prob. 82PCh. 26 - Prob. 83PCh. 26 - Prob. 84PCh. 26 - Prob. 85PCh. 26 - Prob. 86PCh. 26 - Some soft drinks contain citric acid as flavoring....Ch. 26 - Prob. 88PCh. 26 - Prob. 89PCh. 26 - Prob. 90PCh. 26 - Prob. 91PCh. 26 - Prob. 92PCh. 26 - Prob. 93PCh. 26 - Prob. 94PCh. 26 - Prob. 95PCh. 26 - Prob. 96PCh. 26 - Prob. 97PCh. 26 - Why is it somewhat misleading to study biochemi-...Ch. 26 - Prob. 99PCh. 26 - Prob. 100PCh. 26 - Prob. 101PCh. 26 - Prob. 102PCh. 26 - Prob. 103PCh. 26 - Prob. 104PCh. 26 - Prob. 105PCh. 26 - Prob. 106PCh. 26 - Prob. 107PCh. 26 - Prob. 108PCh. 26 - Prob. 109PCh. 26 - Prob. 110PCh. 26 - Prob. 111PCh. 26 - Prob. 112P
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