
Concept explainers
(a)
Interpretation: To identify whether proline can or cannot be synthesized in the body in amounts adequate to meet the body’s needs.
Concept introduction: Amino acids are the main building blocks of proteins. Amino acids are classified as essential and non-essential depending upon whether they can be synthesized within the body itself or not.
Essential amino acids are those amino acids which cannot be synthesized by the body via biosynthesis and thus must be taken from the outside in form of dietary protein to meet the body’s need. Those amino acids which can be synthesized by biosynthesis within the liver are termed as non-essential amino acids.
The essential amino acids are arginine, histidine, isoleucine, leucine, lysine, methionine, phenylalanine, threonine, tryptophan, and valine.
The non-essential amino acids are alanine, asparagines, aspartic acid, cysteine, glutamic acid, glutamine, glycine, proline, serine, and tyrosine.
(b)
Interpretation: To identify whether glycine can or cannot be synthesized in the body in amounts adequate to meet the body’s needs.
Concept introduction: Amino acids are the main building blocks of proteins. Amino acids are classified as essential and non-essential depending upon whether they can be synthesized within the body itself or not.
Essential amino acids are those amino acids which cannot be synthesized by the body via biosynthesis and thus must be taken from the outside in form of dietary protein to meet the body’s need. Those amino acids which can be synthesized by biosynthesis within the liver are termed as non-essential amino acids.
The essential amino acids are arginine, histidine, isoleucine, leucine, lysine, methionine, phenylalanine, threonine, tryptophan, and valine.
The non-essential amino acids are alanine, asparagines, aspartic acid, cysteine, glutamic acid, glutamine, glycine, proline, serine, and tyrosine.
(c)
Interpretation: To identify whether valine can or cannot be synthesized in the body in amounts adequate to meet the body’s needs.
Concept introduction: Amino acids are the main building blocks of proteins. Amino acids are classified as essential and non-essential depending upon whether they can be synthesized within the body itself or not.
Essential amino acids are those amino acids which cannot be synthesized by the body via biosynthesis and thus must be taken from the outside in form of dietary protein to meet the body’s need. Those amino acids which can be synthesized by biosynthesis within the liver are termed as non-essential amino acids.
The essential amino acids are arginine, histidine, isoleucine, leucine, lysine, methionine, phenylalanine, threonine, tryptophan, and valine.
The non-essential amino acids are alanine, asparagines, aspartic acid, cysteine, glutamic acid, glutamine, glycine, proline, serine, and tyrosine.
(d)
Interpretation: To identify whether methionine can or cannot be synthesized in the body in amounts adequate to meet the body’s needs.
Concept introduction: Amino acids are the main building blocks of proteins. Amino acids are classified as essential and non-essential depending upon whether they can be synthesized within the body itself or not.
Essential amino acids are those amino acids which cannot be synthesized by the body via biosynthesis and thus must be taken from the outside in form of dietary protein to meet the body’s need. Those amino acids which can be synthesized by biosynthesis within the liver are termed as non-essential amino acids.
The essential amino acids are arginine, histidine, isoleucine, leucine, lysine, methionine, phenylalanine, threonine, tryptophan, and valine.
The non-essential amino acids are alanine, asparagines, aspartic acid, cysteine, glutamic acid, glutamine, glycine, proline, serine, and tyrosine.

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Chapter 26 Solutions
General, Organic, And Biological Chemistry, Hybrid (with Owlv2 Quick Prep For General Chemistry Printed Access Card)
- ✓ Check the box under each molecule that has a total of five ẞ hydrogens. If none of the molecules fit this description, check the box underneath the table. tab OH CI 0 Br xx Br None of these molecules have a total of five ẞ hydrogens. esc Explanation Check caps lock shift 1 fn control 02 F2 W Q A N #3 S 80 F3 E $ t 01 205 % 5 F5 & 7 © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility FT * 8 R T Y U כ F6 9 FIG F11 F D G H J K L C X V B < N M H option command P H + F12 commandarrow_forwardDraw the major product of this reaction. Ignore inorganic byproducts and the carboxylic acid side product. O 1. CHзMgBr (excess) 2. H₂O ✓ W X 人arrow_forwardIf cyclopentyl acetaldehyde reacts with NaOH, state the product (formula).arrow_forward
- Draw the major product of this reaction. Ignore inorganic byproducts. N S S HgCl2, H2SO4 く 8 W X Parrow_forwardtab esc く Drawing the After running various experiments, you determine that the mechanism for the following reaction occurs in a step-wise fashion. Br + OH + Using this information, draw the correct mechanism in the space below. 1 Explanation Check F2 F1 @2 Q W A os lock control option T S # 3 80 F3 Br $ 4 0105 % OH2 + Br Add/Remove step X C F5 F6 6 R E T Y 29 & 7 F D G H Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Ce A F7 DII F8 C Ո 8 * 9 4 F10 F C J K L C V Z X B N M H command P ge Coarrow_forwardIndicate compound A that must react with ethylbenzene to obtain 4-ethylbenzene-1-sulfonic acid. 3-bromo-4-ethylbenzene-1-sulfonic acid.arrow_forward
- Part 1 of 2 Draw the structure of A, the minor E1 product of the reaction. esc I Skip Part Check H₂O, D 2 A + Click and drag to start drawing a structure. -0- F1 F2 1 2 # 3 Q A 80 F3 W E S D F4 $ 4 % 5 F5 ㅇ F6 R T Y F G X 5 & 7 + Save 2025 McGraw Hill LLC. All Rights Reserved. DII F7 F8 H * C 80 J Z X C V B N 4 F9 6arrow_forwardFile Preview The following is a total synthesis of the pheromone of the western pine beetle. Such syntheses are interesting both because of the organic chemistry, and because of the possibility of using species specific insecticides, rather than broad band insecticides. Provide the reagents for each step. There is some chemistry from our most recent chapter in this synthesis, but other steps are review from earlier chapters. (8 points) COOEt COOEt A C COOEt COOEt COOH B OH OTS CN D E See the last homework set F for assistance on this one. H+, H₂O G OH OH The last step is just nucleophilic addition reactions, taking the ketone to an acetal, intramolecularly. But it is hard to visualize the three dimensional shape as it occurs. Frontalin, pheromone of the western pine beetlearrow_forwardFor the reaction below: 1. Draw all reasonable elimination products to the right of the arrow. 2. In the box below the reaction, redraw any product you expect to be a major product. C Major Product: Check + ◎ + X ง © Cl I F2 80 F3 I σ F4 I F5 NaOH Click and drawing F6 A 2025 McGraw Hill LLC. All Rights E F7 F8 $ # % & 2 3 4 5 6 7 8 Q W E R T Y U A S D F G H Jarrow_forward
- Can I please get help with this graph. If you can show exactly where it needs to pass through.arrow_forwardN Draw the major product of this reaction. Ignore inorganic byproducts. D 1. H₂O, pyridine 2. neutralizing work-up V P W X DE CO e C Larrow_forwardDraw the major product of this reaction. Ignore inorganic byproducts. N O' 1. H2O, pyridine 2. neutralizing work-up く 8 W aarrow_forward
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