General Chemistry: Principles And Modern Applications Plus Mastering Chemistry With Pearson Etext -- Access Card Package (11th Edition)
11th Edition
ISBN: 9780134097329
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Question
Chapter 26, Problem 25E
Interpretation Introduction
Interpretation:
The isomers of C5H10O2 that are carboxylic acids need to be depicted.
Concept introduction:
- Isomers are two or more compounds which have the same formula but different structures and properties.
- Constitutional isomers are structural isomers which have the same molecular formula but different connectivity of the constituent atoms.
- Stereoisomers are spatial isomers which have the same formula and connectivity but differ in the orientation of the constituent atoms in space.
- Carboxylic acids are organic
functional groups where a carbon atom is linked to oxygen via a double bond and a hydroxyl group via a single bond i.e. −COOH group. - The degree of unsaturation i.e. the presence of multiple bonds or rings in a compound based on its molecular formula can be determine using the following equation:
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 26 Solutions
General Chemistry: Principles And Modern Applications Plus Mastering Chemistry With Pearson Etext -- Access Card Package (11th Edition)
Ch. 26 - Prob. 1ECh. 26 - Draw a structural formula for each of the...Ch. 26 - Prob. 3ECh. 26 - Write structural formulas corresponding to these...Ch. 26 - Prob. 5ECh. 26 - Prob. 6ECh. 26 - Prob. 7ECh. 26 - Prob. 8ECh. 26 - What is the relationship, if any, between the...Ch. 26 - Prob. 10E
Ch. 26 - Prob. 11ECh. 26 - Prob. 12ECh. 26 - Identify the chiral carbon atoms, ¡f any, in the...Ch. 26 - Prob. 14ECh. 26 - Identify the chiral carbon atoms, ¡f any, in the...Ch. 26 - Prob. 16ECh. 26 - Prob. 17ECh. 26 - Prob. 18ECh. 26 - Prob. 19ECh. 26 - By name or formula, give one example of each of...Ch. 26 - Prob. 21ECh. 26 - Prob. 22ECh. 26 - Prob. 23ECh. 26 - Prob. 24ECh. 26 - Prob. 25ECh. 26 - Prob. 26ECh. 26 - Prob. 27ECh. 26 - Prob. 28ECh. 26 - Prob. 29ECh. 26 - Prob. 30ECh. 26 - Prob. 31ECh. 26 - Prob. 32ECh. 26 - Prob. 33ECh. 26 - Prob. 34ECh. 26 - Does each of the following names convey sufficient...Ch. 26 - Prob. 36ECh. 26 - Prob. 37ECh. 26 - Supply condensed structural formulas for the...Ch. 26 - Prob. 39ECh. 26 - Prob. 40ECh. 26 - Classify the carbon atoms in, a. methylbutane, and...Ch. 26 - Classity the carbon atoms in a....Ch. 26 - Prob. 43ECh. 26 - Draw Newman projections for the staggered and...Ch. 26 - Draw the most stable conformation for the molecule...Ch. 26 - Prob. 46ECh. 26 - Prob. 47ECh. 26 - Prob. 48ECh. 26 - Prob. 49ECh. 26 - Prob. 50ECh. 26 - Prob. 51ECh. 26 - Prob. 52ECh. 26 - Prob. 53ECh. 26 - Prob. 54ECh. 26 - Prob. 55ECh. 26 - Prob. 56ECh. 26 - Draw suitable structural formulas to show that...Ch. 26 - Which of the following pairs of molecules are...Ch. 26 - Prob. 59ECh. 26 - Prob. 60ECh. 26 - Name the following molecules with the appropriate...Ch. 26 - Name the following molecules with the appropriate...Ch. 26 - Name the following molecules with the appropriate...Ch. 26 - Prob. 64ECh. 26 - Draw the structure for each of the following. a....Ch. 26 - Prob. 66ECh. 26 - Prob. 67ECh. 26 - Prob. 68ECh. 26 - Prob. 69ECh. 26 - Prob. 70ECh. 26 - Prob. 71ECh. 26 - Prob. 72ECh. 26 - Prob. 73ECh. 26 - Prob. 74ECh. 26 - Supply condensed or structural formulas for the...Ch. 26 - Prob. 76IAECh. 26 - Prob. 77IAECh. 26 - Prob. 78IAECh. 26 - Prob. 79IAECh. 26 - Prob. 80IAECh. 26 - Combustion of a 0.1908 g sample of a compound gave...Ch. 26 - Prob. 82IAECh. 26 - In the monochiorination of hydrocarbons, a...Ch. 26 - A particular colorless organic liquid is known to...Ch. 26 - Prob. 85IAECh. 26 - Give the systematic names, including any...Ch. 26 - Prob. 87IAECh. 26 - Prob. 88IAECh. 26 - Levomethadyl acetate (shown below) is used in the...Ch. 26 - Thiamphenicol (shown below) is an antibacterial...Ch. 26 - Prob. 91IAECh. 26 - Prob. 92IAECh. 26 - Prob. 93IAECh. 26 - Prob. 94IAECh. 26 - Prob. 95IAECh. 26 - For each of the following molecules (a) draw the...Ch. 26 - Prob. 97FPCh. 26 - Prob. 98SAECh. 26 - Explain the important distinctions between each...Ch. 26 - Describe the characteristics of each of the...Ch. 26 - The compound isoheptane is best represented by the...Ch. 26 - Prob. 102SAECh. 26 - Prob. 103SAECh. 26 - Prob. 104SAECh. 26 - Assign configurations, R or S, to the chiral...Ch. 26 - Consider the following pairs of structures In each...Ch. 26 - Prob. 107SAECh. 26 - Prob. 108SAECh. 26 - Prob. 109SAECh. 26 - Prob. 110SAECh. 26 - Prob. 111SAE
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