EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
4th Edition
ISBN: 9781119659525
Author: Klein
Publisher: WILEY CONS
Question
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Chapter 25.3, Problem 13CC

(a)

Interpretation Introduction

Interpretation:

The amino acid formed when carboxylic acid is treated with bromine and phosphorous tribromide, followed by water and the resulting α -haloacid treated with excess ammonia need to be drawn for the given set of carboxylic acid.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG, Chapter 25.3, Problem 13CC , additional homework tip  1

To identify: the amino acid formed when the given carboxylic acid is treated with bromine, phosphorous tribromide and followed by excess ammonia,

EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG, Chapter 25.3, Problem 13CC , additional homework tip  2

(b)

Interpretation Introduction

Interpretation:

The amino acid formed when carboxylic acid is treated with bromine and phosphorous tribromide, followed by water and the resulting α -haloacid treated with excess ammonia need to be drawn for the given set of carboxylic acid.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG, Chapter 25.3, Problem 13CC , additional homework tip  3

To identify: the amino acid formed when the given carboxylic acid is treated with bromine, phosphorous tribromide and followed by excess ammonia,

EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG, Chapter 25.3, Problem 13CC , additional homework tip  4

(c)

Interpretation Introduction

Interpretation:

The amino acid formed when carboxylic acid is treated with bromine and phosphorous tribromide, followed by water and the resulting α -haloacid treated with excess ammonia need to be drawn for the given set of carboxylic acid.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG, Chapter 25.3, Problem 13CC , additional homework tip  5

To identify: the amino acid formed when the given carboxylic acid is treated with bromine, phosphorous tribromide and followed by excess ammonia,

EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG, Chapter 25.3, Problem 13CC , additional homework tip  6

(d)

Interpretation Introduction

Interpretation:

The amino acid formed when carboxylic acid is treated with bromine and phosphorous tribromide, followed by water and the resulting α -haloacid treated with excess ammonia need to be drawn for the given set of carboxylic acid.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG, Chapter 25.3, Problem 13CC , additional homework tip  7

To identify: the amino acid formed when the given carboxylic acid is treated with bromine, phosphorous tribromide and followed by excess ammonia,

EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG, Chapter 25.3, Problem 13CC , additional homework tip  8

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