EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
4th Edition
ISBN: 9781119659525
Author: Klein
Publisher: WILEY CONS
Question
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Chapter 25.4, Problem 29CC

(a)

Interpretation Introduction

Interpretation:

In Bacitracin A, the amino acid residues and the configuration of the same along with non-amino acid residue need to be identified.

Concept introduction:

The amino acid residue is in a given compound is identified by finding the peptide bond.  Then assigning the side chain for the corresponding amino acid residue.  If the configuration of the amino acid residue is “L-amino acid” means it is naturally occurring and if it is a “D-amino acid” it is enantiomer of “L-amino acid”

To identify: the amino acid residue in Bacitracin A that are naturally occurring.

(b)

Interpretation Introduction

Interpretation:

In Bacitracin A, the amino acid residues and the configuration of the same along with non-amino acid residue need to be identified.

Concept introduction:

The amino acid residue is in a given compound is identified by finding the peptide bond.  Then assigning the side chain for the corresponding amino acid residue.  If the configuration of the amino acid residue is “L-amino acid” means it is naturally occurring and if it is a “D-amino acid” it is enantiomer of “L-amino acid”

To identify: the amino acid residue in Bacitracin A that are D-amino acids.

(c)

Interpretation Introduction

Interpretation:

In Bacitracin A, the amino acid residues and the configuration of the same along with non-amino acid residue need to be identified.

Concept introduction:

The amino acid residue is in a given compound is identified by finding the peptide bond.  Then assigning the side chain for the corresponding amino acid residue.  If the configuration of the amino acid residue is “L-amino acid” means it is naturally occurring and if it is a “D-amino acid” it is enantiomer of “L-amino acid”

To identify: the amino acid residue in Bacitracin A that are not naturally occurring and its enantiomer also.

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