From the given data, compound with highest ionic character, ion with least ionic radius, atom with greatest ionization energy and oxide having high acidic character has to be identified. Concept introduction: Ionic character: Higher the electronegativity difference between the two atoms will results the bond is more polar (ionic). To identify: The compound having highest ionic character

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Answer 1

Question

Chapter 25, Problem 25.91QP

(a)

Interpretation Introduction

Interpretation:

From the given data, compound with highest ionic character, ion with least ionic radius, atom with greatest ionization energy and oxide having high acidic character has to be identified.

Concept introduction:

Ionic character: Higher the electronegativity difference between the two atoms will results the bond is more polar (ionic).

To identify: The compound having highest ionic character

(b)

Interpretation Introduction

Concept introduction:

Ionic radius: The radius of an ion is known as its ionic radius. It may be a cation or an anion.

To identify: The ion having least ionic radius

(c)

Interpretation Introduction

Concept introduction:

Ionization energy: In gas phase, the smallest amount of energy required to remove an electron from an atom is known as ionization energy.

To identify: The atom having highest ionization energy

(d)

Interpretation Introduction

Concept introduction:

Acidic oxides: these are the oxides which forms acid with water and forms salt with base.

To identify: The most acidic oxide from the given set of oxides

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Q2. Consider the hydrogenation of ethylene C2H4 + H2 = C2H6 The heats of combustion and molar entropies for the three gases at 298 K are given by: C2H4 C2H6 H2 AH comb/kJ mol‍¹ -1395 -1550 -243 Sº / J K¹ mol-1 220.7 230.4 131.1 The average heat capacity change, ACP, for the reaction over the temperature range 298-1000 K is 10.9 J K¹ mol¹. Using these data, determine: (a) the standard enthalpy change at 800 K (b) the standard entropy change at 800 K (c) the equilibrium constant at 800 K.

Answer 2

Question

Chapter 25, Problem 25.91QP

(a)

Interpretation Introduction

Interpretation:

From the given data, compound with highest ionic character, ion with least ionic radius, atom with greatest ionization energy and oxide having high acidic character has to be identified.

Concept introduction:

Ionic character: Higher the electronegativity difference between the two atoms will results the bond is more polar (ionic).

To identify: The compound having highest ionic character

(b)

Interpretation Introduction

Concept introduction:

Ionic radius: The radius of an ion is known as its ionic radius. It may be a cation or an anion.

To identify: The ion having least ionic radius

(c)

Interpretation Introduction

Concept introduction:

Ionization energy: In gas phase, the smallest amount of energy required to remove an electron from an atom is known as ionization energy.

To identify: The atom having highest ionization energy

(d)

Interpretation Introduction

Concept introduction:

Acidic oxides: these are the oxides which forms acid with water and forms salt with base.

To identify: The most acidic oxide from the given set of oxides

Expert Solution & Answer

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Answer 3

Question

Chapter 25, Problem 25.91QP

(a)

Interpretation Introduction

Interpretation:

From the given data, compound with highest ionic character, ion with least ionic radius, atom with greatest ionization energy and oxide having high acidic character has to be identified.

Concept introduction:

Ionic character: Higher the electronegativity difference between the two atoms will results the bond is more polar (ionic).

To identify: The compound having highest ionic character

(b)

Interpretation Introduction

Concept introduction:

Ionic radius: The radius of an ion is known as its ionic radius. It may be a cation or an anion.

To identify: The ion having least ionic radius

(c)

Interpretation Introduction

Concept introduction:

Ionization energy: In gas phase, the smallest amount of energy required to remove an electron from an atom is known as ionization energy.

To identify: The atom having highest ionization energy

(d)

Interpretation Introduction

Concept introduction:

Acidic oxides: these are the oxides which forms acid with water and forms salt with base.

To identify: The most acidic oxide from the given set of oxides

Expert Solution & Answer

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Answer 4

Question

Chapter 25, Problem 25.91QP

(a)

Interpretation Introduction

Interpretation:

From the given data, compound with highest ionic character, ion with least ionic radius, atom with greatest ionization energy and oxide having high acidic character has to be identified.

Concept introduction:

Ionic character: Higher the electronegativity difference between the two atoms will results the bond is more polar (ionic).

To identify: The compound having highest ionic character

(b)

Interpretation Introduction

Concept introduction:

Ionic radius: The radius of an ion is known as its ionic radius. It may be a cation or an anion.

To identify: The ion having least ionic radius

(c)

Interpretation Introduction

Concept introduction:

Ionization energy: In gas phase, the smallest amount of energy required to remove an electron from an atom is known as ionization energy.

To identify: The atom having highest ionization energy

(d)

Interpretation Introduction

Concept introduction:

Acidic oxides: these are the oxides which forms acid with water and forms salt with base.

To identify: The most acidic oxide from the given set of oxides

Expert Solution & Answer

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Answer 5

Chapter 25, Problem 25.91QP

(a)

Interpretation Introduction

Interpretation:

From the given data, compound with highest ionic character, ion with least ionic radius, atom with greatest ionization energy and oxide having high acidic character has to be identified.

Concept introduction:

Ionic character: Higher the electronegativity difference between the two atoms will results the bond is more polar (ionic).

To identify: The compound having highest ionic character

(b)

Interpretation Introduction

Concept introduction:

Ionic radius: The radius of an ion is known as its ionic radius. It may be a cation or an anion.

To identify: The ion having least ionic radius

(c)

Interpretation Introduction

Concept introduction:

Ionization energy: In gas phase, the smallest amount of energy required to remove an electron from an atom is known as ionization energy.

To identify: The atom having highest ionization energy

(d)

Interpretation Introduction

Concept introduction:

Acidic oxides: these are the oxides which forms acid with water and forms salt with base.

To identify: The most acidic oxide from the given set of oxides

Answer 6

Chapter 25, Problem 25.91QP

(a)

Interpretation Introduction

Interpretation:

From the given data, compound with highest ionic character, ion with least ionic radius, atom with greatest ionization energy and oxide having high acidic character has to be identified.

Concept introduction:

Ionic character: Higher the electronegativity difference between the two atoms will results the bond is more polar (ionic).

To identify: The compound having highest ionic character

Answer 7

Chapter 25, Problem 25.91QP

(a)

Interpretation Introduction

Interpretation:

From the given data, compound with highest ionic character, ion with least ionic radius, atom with greatest ionization energy and oxide having high acidic character has to be identified.

Concept introduction:

Ionic character: Higher the electronegativity difference between the two atoms will results the bond is more polar (ionic).

To identify: The compound having highest ionic character

Answer 8

(b)

Interpretation Introduction

Concept introduction:

Ionic radius: The radius of an ion is known as its ionic radius. It may be a cation or an anion.

To identify: The ion having least ionic radius

Answer 9

(b)

Interpretation Introduction

Concept introduction:

Ionic radius: The radius of an ion is known as its ionic radius. It may be a cation or an anion.

To identify: The ion having least ionic radius

Answer 10

(c)

Interpretation Introduction

Concept introduction:

Ionization energy: In gas phase, the smallest amount of energy required to remove an electron from an atom is known as ionization energy.

To identify: The atom having highest ionization energy

Answer 11

(c)

Interpretation Introduction

Concept introduction:

Ionization energy: In gas phase, the smallest amount of energy required to remove an electron from an atom is known as ionization energy.

To identify: The atom having highest ionization energy

Answer 12

(d)

Interpretation Introduction

Concept introduction:

Acidic oxides: these are the oxides which forms acid with water and forms salt with base.

To identify: The most acidic oxide from the given set of oxides

Answer 13

(d)

Interpretation Introduction

Concept introduction:

Acidic oxides: these are the oxides which forms acid with water and forms salt with base.

To identify: The most acidic oxide from the given set of oxides

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 25 - Prob. 25.1QP Ch. 25 - Prob. 25.2QP Ch. 25 - Prob. 25.3QP Ch. 25 - Prob. 25.4QP Ch. 25 - Prob. 25.5QP Ch. 25 - Prob. 25.6QP Ch. 25 - Prob. 25.7QP Ch. 25 - Prob. 25.8QP Ch. 25 - Prob. 25.9QP Ch. 25 - Prob. 25.10QP

Solution Summary: The author explains that the highest ionic character compound is SiCl_4 from the given set of compounds.

Concept explainers

Concept introduction:

Ionic radius: The radius of an ion is known as its ionic radius. It may be a cation or an anion.

To identify: The ion having least ionic radius

Concept introduction:

Ionization energy: In gas phase, the smallest amount of energy required to remove an electron from an atom is known as ionization energy.

To identify: The atom having highest ionization energy

Concept introduction:

Acidic oxides: these are the oxides which forms acid with water and forms salt with base.

To identify: The most acidic oxide from the given set of oxides

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Chapter 25 Solutions

Solution Summary: The author explains that the highest ionic character compound is SiCl_4 from the given set of compounds.

Concept explainers

Concept introduction: Ionic radius: The radius of an ion is known as its ionic radius. It may be a cation or an anion. To identify: The ion having least ionic radius

Concept introduction: Ionization energy: In gas phase, the smallest amount of energy required to remove an electron from an atom is known as ionization energy. To identify: The atom having highest ionization energy

Concept introduction: Acidic oxides: these are the oxides which forms acid with water and forms salt with base. To identify: The most acidic oxide from the given set of oxides

Want to see the full answer?

Chapter 25 Solutions

Concept introduction:

Ionic radius: The radius of an ion is known as its ionic radius. It may be a cation or an anion.

To identify: The ion having least ionic radius

Concept introduction:

Ionization energy: In gas phase, the smallest amount of energy required to remove an electron from an atom is known as ionization energy.

To identify: The atom having highest ionization energy

Concept introduction:

Acidic oxides: these are the oxides which forms acid with water and forms salt with base.

To identify: The most acidic oxide from the given set of oxides