Chemistry: Atoms First
Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Chapter 25, Problem 25.23QP
Interpretation Introduction

Interpretation:

Differences between carbon monoxide (CO) and carbon dioxide (CO2) has to be explained by its two chemical properties.

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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15% glycerin by weight. If the original charge is 500 kg, evaluate; e. The ratio of sucrose to water in the original charge (wt/wt). f. Moles of CO2 evolved. g. Maximum possible amount of ethanol that could be formed. h. Conversion efficiency. i. Per cent excess of excess reactant. Reactions: Inversion reaction: C12H22O11 + H2O →2C6H12O6 Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2 Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. cleavage Bond A •CH3 + 26.← Cleavage 2°C. + Bond C +3°C• CH3 2C Cleavage E 2°C. 26. weakest bond Intact molecule Strongest 3°C 20. Gund Largest argest a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. C Weakest bond A Produces Most Bond Strongest Bond Strongest Gund produces least stable radicals Weakest Stable radical b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 13°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. • CH3 methyl radical Formed in Gund A Cleavage c.…

Chapter 25 Solutions

Chemistry: Atoms First

Ch. 25 - Prob. 25.11QPCh. 25 - Prob. 25.12QPCh. 25 - Elements 17 and 20 form compounds with hydrogen....Ch. 25 - Prob. 25.14QPCh. 25 - Prob. 25.15QPCh. 25 - Prob. 25.16QPCh. 25 - Prob. 25.17QPCh. 25 - Prob. 25.18QPCh. 25 - Prob. 25.19QPCh. 25 - Prob. 25.20QPCh. 25 - Prob. 25.21QPCh. 25 - Prob. 25.22QPCh. 25 - Prob. 25.23QPCh. 25 - Prob. 25.24QPCh. 25 - Prob. 25.25QPCh. 25 - Prob. 25.26QPCh. 25 - Prob. 25.27QPCh. 25 - Prob. 25.28QPCh. 25 - Prob. 25.29QPCh. 25 - Prob. 25.30QPCh. 25 - Prob. 25.31QPCh. 25 - Prob. 25.32QPCh. 25 - Prob. 25.33QPCh. 25 - Prob. 25.34QPCh. 25 - Prob. 25.35QPCh. 25 - Prob. 25.36QPCh. 25 - Prob. 25.37QPCh. 25 - Prob. 25.38QPCh. 25 - Prob. 25.39QPCh. 25 - Prob. 25.40QPCh. 25 - Prob. 25.41QPCh. 25 - At 620 K, the vapor density of ammonium chloride...Ch. 25 - Prob. 25.43QPCh. 25 - Prob. 25.44QPCh. 25 - Prob. 25.45QPCh. 25 - Prob. 25.46QPCh. 25 - Prob. 25.47QPCh. 25 - Prob. 25.48QPCh. 25 - Prob. 25.49QPCh. 25 - Prob. 25.50QPCh. 25 - Prob. 25.51QPCh. 25 - Prob. 25.52QPCh. 25 - Prob. 25.53QPCh. 25 - Prob. 25.54QPCh. 25 - Prob. 25.55QPCh. 25 - Prob. 25.56QPCh. 25 - Prob. 25.57QPCh. 25 - Prob. 25.58QPCh. 25 - Prob. 25.59QPCh. 25 - Prob. 25.60QPCh. 25 - Prob. 25.61QPCh. 25 - Prob. 25.62QPCh. 25 - Prob. 25.63QPCh. 25 - Prob. 25.64QPCh. 25 - Prob. 25.65QPCh. 25 - Prob. 25.66QPCh. 25 - Prob. 25.67QPCh. 25 - Prob. 25.68QPCh. 25 - Prob. 25.69QPCh. 25 - Prob. 25.70QPCh. 25 - Prob. 25.71QPCh. 25 - Prob. 25.72QPCh. 25 - What are the oxidation numbers of O and F in HFO?Ch. 25 - Prob. 25.74QPCh. 25 - Prob. 25.75QPCh. 25 - Prob. 25.76QPCh. 25 - Prob. 25.77QPCh. 25 - Prob. 25.78QPCh. 25 - Prob. 25.79QPCh. 25 - Prob. 25.80QPCh. 25 - Prob. 25.81QPCh. 25 - Prob. 25.82QPCh. 25 - Prob. 25.83QPCh. 25 - Prob. 25.84QPCh. 25 - Iodine pentoxide (I2O5) is sometimes used to...Ch. 25 - Prob. 25.86QPCh. 25 - Prob. 25.87QPCh. 25 - Prob. 25.88QPCh. 25 - Prob. 25.89QPCh. 25 - Prob. 25.90QPCh. 25 - Prob. 25.91QPCh. 25 - Prob. 25.92QPCh. 25 - Prob. 25.93QPCh. 25 - Prob. 25.94QPCh. 25 - Prob. 25.95QPCh. 25 - Prob. 25.96QPCh. 25 - Prob. 25.97QPCh. 25 - Prob. 25.98QPCh. 25 - Prob. 25.99QPCh. 25 - Prob. 25.100QPCh. 25 - Prob. 25.101QPCh. 25 - Prob. 25.102QPCh. 25 - Prob. 25.103QPCh. 25 - Prob. 25.104QP
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