ORG CHEM W/ EBOOK & SW5 + STUDY GUIDE
2nd Edition
ISBN: 9780393666144
Author: KARTY
Publisher: NORTON
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Question
Chapter 25, Problem 25.73P
Interpretation Introduction
Interpretation:
The structures from J to U in the given synthesis scheme are to be determined.
Concept introduction:
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Please draw
-Page: 8
nsition metal ions have high-spin aqua complexes except one: [Co(HO)₁]".
What is the d-configuration, oxidation state of the metal in [Co(H:O))"? Name and draw the geometry
of [Co(H2O)]?
b)
Draw energy diagrams showing the splitting of the five d orbitals of Co for the two possible electron
configurations of [Co(H2O)]:
Knowing that A = 16 750 cm and Пl. = 21 000 cm, calculate the configuration energy (.e., balance
or ligand-field stabilization energy and pairing energy) for both low spin and high spin configurations of
[Co(H2O)]. Which configuration seems more stable at this point of the analysis? (Note that 349.76 cm = 1
kJ/mol)
Exchange energy (IT) was not taken into account in part (d), but it plays a role. Assuming exchange
an occur within t29 and within eg (but not between tz, and ea), how many exchanges are possible in the low
in configuration vs in the high spin configuration? What can you say about the importance of exchange energy
07
Draw everything please on a piece of paper explaining each step
Chapter 25 Solutions
ORG CHEM W/ EBOOK & SW5 + STUDY GUIDE
Ch. 25 - Prob. 25.1PCh. 25 - Prob. 25.2PCh. 25 - Prob. 25.3PCh. 25 - Prob. 25.4PCh. 25 - Prob. 25.5PCh. 25 - Prob. 25.6PCh. 25 - Prob. 25.7PCh. 25 - Prob. 25.8PCh. 25 - Prob. 25.9PCh. 25 - Prob. 25.10P
Ch. 25 - Prob. 25.11PCh. 25 - Prob. 25.12PCh. 25 - Prob. 25.13PCh. 25 - Prob. 25.14PCh. 25 - Prob. 25.15PCh. 25 - Prob. 25.16PCh. 25 - Prob. 25.17PCh. 25 - Prob. 25.18PCh. 25 - Prob. 25.19PCh. 25 - Prob. 25.20PCh. 25 - Prob. 25.21PCh. 25 - Prob. 25.22PCh. 25 - Prob. 25.23PCh. 25 - Prob. 25.24PCh. 25 - Prob. 25.25PCh. 25 - Prob. 25.26PCh. 25 - Prob. 25.27PCh. 25 - Prob. 25.28PCh. 25 - Prob. 25.29PCh. 25 - Prob. 25.30PCh. 25 - Prob. 25.31PCh. 25 - Prob. 25.32PCh. 25 - Prob. 25.33PCh. 25 - Prob. 25.34PCh. 25 - Prob. 25.35PCh. 25 - Prob. 25.36PCh. 25 - Prob. 25.37PCh. 25 - Prob. 25.38PCh. 25 - Prob. 25.39PCh. 25 - Prob. 25.40PCh. 25 - Prob. 25.41PCh. 25 - Prob. 25.42PCh. 25 - Prob. 25.43PCh. 25 - Prob. 25.44PCh. 25 - Prob. 25.45PCh. 25 - Prob. 25.46PCh. 25 - Prob. 25.47PCh. 25 - Prob. 25.48PCh. 25 - Prob. 25.49PCh. 25 - Prob. 25.50PCh. 25 - Prob. 25.51PCh. 25 - Prob. 25.52PCh. 25 - Prob. 25.53PCh. 25 - Prob. 25.54PCh. 25 - Prob. 25.55PCh. 25 - Prob. 25.56PCh. 25 - Prob. 25.57PCh. 25 - Prob. 25.58PCh. 25 - Prob. 25.59PCh. 25 - Prob. 25.60PCh. 25 - Prob. 25.61PCh. 25 - Prob. 25.62PCh. 25 - Prob. 25.63PCh. 25 - Prob. 25.64PCh. 25 - Prob. 25.65PCh. 25 - Prob. 25.66PCh. 25 - Prob. 25.67PCh. 25 - Prob. 25.68PCh. 25 - Prob. 25.69PCh. 25 - Prob. 25.70PCh. 25 - Prob. 25.71PCh. 25 - Prob. 25.72PCh. 25 - Prob. 25.73PCh. 25 - Prob. 25.74PCh. 25 - Prob. 25.75PCh. 25 - Prob. 25.76PCh. 25 - Prob. 25.77PCh. 25 - Prob. 25.1YTCh. 25 - Prob. 25.2YTCh. 25 - Prob. 25.3YTCh. 25 - Prob. 25.4YTCh. 25 - Prob. 25.5YTCh. 25 - Prob. 25.6YTCh. 25 - Prob. 25.7YTCh. 25 - Prob. 25.8YTCh. 25 - Prob. 25.9YTCh. 25 - Prob. 25.10YTCh. 25 - Prob. 25.11YTCh. 25 - Prob. 25.12YTCh. 25 - Prob. 25.13YTCh. 25 - Prob. 25.14YTCh. 25 - Prob. 25.15YTCh. 25 - Prob. 25.16YTCh. 25 - Prob. 25.17YTCh. 25 - Prob. 25.18YTCh. 25 - Prob. 25.19YTCh. 25 - Prob. 25.20YTCh. 25 - Prob. 25.21YTCh. 25 - Prob. 25.22YTCh. 25 - Prob. 25.23YTCh. 25 - Prob. 25.24YT
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