Organic Chemistry, Loose-leaf Version
Organic Chemistry, Loose-leaf Version
8th Edition
ISBN: 9781305865549
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 25, Problem 25.43P

(a)

Interpretation Introduction

Interpretation:

The structural formula for Alginic acid, which is a polymer of D-mannuronic acid in the pyranose form linked by β-1,4-glycosidic bonds has to be given.

(b)

Interpretation Introduction

Interpretation:

The structural formula for Pectic acid, which is a polymer of D-galacturonic acid in the pyranose ring form linked by α-1,4-glycosidic bonds has to be given.

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1. Give stereochemical (Fischer projection) formulas for all (but no extras) the stereoisomers that could theoretically form during the reduction of a. the carbonyl group of 2-methyl-3--pentanone b. both carbonyl groups of 2,4-pentanedione (careful!) 2. Predict the products of the reduction of O=CCH2CH2CH2C=O with a. LiAlH4 b. NaBH4 CH3 OH
Which of the following compounds can be synthesized using one reaction from any alkene, as a major product? If it can be synthesized, propose a route, and you may use any other starting materials, reagents and solvents as needed. If you do not think that it can be synthesized as a major product from an alkene, explain in detail why.
Draw the stepwise mechanism (with arrow pushing)
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