Organic Chemistry, Loose-leaf Version
Organic Chemistry, Loose-leaf Version
8th Edition
ISBN: 9781305865549
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 25.2, Problem 25.3P
Interpretation Introduction

Interpretation:

The chair conformations of α-D-mannopyranose and β-D-mannopyranose has to be given and their anomeric carbons has to be identified.

Concept Introduction:

In pyranoses, as the molecule contains six carbon atoms, the stable conformation is of chair conformation.

Anomeric carbons:

In Haworth projections, the newly formed chiral centre in the cyclic structure is said to be the Anomeric carbon.

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a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression: AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T A. Calculate the value of AS for the process. B. Next, use the Gibbs-Helmholtz equation: (a(AG/T)) ΔΗ - T2 to calculate the value of AH for the process.
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